Abstract Since Jurassic time ( c. 200 Ma), Antarctica has had a greater diversity of volcanism than other southern continents. It includes: (1) voluminous mafic and felsic volcanism associated with the break-up of Gondwana; (2) a long-lived continental margin volcanic arc, including back-arc alkaline volcanism linked to slab rollback; (3) small-volume mafic alkaline volcanism associated with slab-window formation; and (4) one of Earth's major continental rift zones, the West Antarctic Rift System (WARS), with its numerous large alkaline central volcanoes. Several of Antarctica's volcanoes are still active. This chapter is a review of the major volcanic episodes and their principal characteristics, in their tectonic, volcanological and palaeoenvironmental contexts. Jurassic Gondwana break-up was associated with large-scale volcanism that caused global environmental changes and associated mass extinctions. The volcanic arc was a major extensional arc characterized by alternating volcanic flare-ups and lulls. The Neogene rift-related alkaline volcanism is dominated by effusive glaciovolcanic eruptions, overwhelmingly as both pāhoehoe- and ‘a‘ā-sourced lava-fed deltas. The rift is conspicuously poor in pyroclastic rocks due to the advection and removal of tephra erupted during glacial intervals. Volcanological investigations of the Neogene volcanism have also significantly increased our knowledge of the critical parameters and development of the Antarctic Ice Sheet.

Abstract Nineteen large (2348–4285 m above sea level) central polygenetic alkaline shield-like composite volcanoes and numerous smaller volcanoes in Marie Byrd Land (MBL) and western Ellsworth Land rise above the West Antarctic Ice Sheet (WAIS) and comprise the MBL Volcanic Group (MBLVG). Earliest MBLVG volcanism dates to the latest Eocene (36.6 Ma). Polygenetic volcanism began by the middle Miocene (13.4 Ma) and has continued into the Holocene without major interruptions, producing the central volcanoes with 24 large (2–10 km-diameter) summit calderas and abundant evidence for explosive eruptions in caldera-rim deposits. Rock lithofacies are dominated by basanite and trachyte/phonolite lava and breccia, deposited in both subaerial and ice-contact environments. The chronology of MBLVG volcanism is well constrained by 330 age analyses, including 52 new 40 Ar/ 39 Ar ages. A volcanic lithofacies record of glaciation provides evidence of local ice-cap glaciation at 29–27 Ma and of widespread WAIS glaciation by 9 Ma. Late Quaternary glaciovolcanic records document WAIS expansions that correlate to eustatic sea-level lowstands (MIS 16, 4 and 2): the WAIS was +500 m at 609 ka at coastal Mount Murphy, and +400 m at 64.7 ka, +400 m at 21.2 ka and +575 m at 17.5 ka at inland Mount Takahe.

Abstract In Marie Byrd Land and Ellsworth Land 19 large polygenetic volcanoes and numerous smaller centres are exposed above the West Antarctic Ice Sheet along the northern flank of the West Antarctic Rift System. The Cenozoic (36.7 Ma to active) volcanism of the Marie Byrd Land Volcanic Group (MBLVG) encompasses the full spectrum of alkaline series compositions ranging from basalt to intermediate (e.g. mugearite, benmoreite) to phonolite, peralkaline trachyte, rhyolite and rare pantellerite. Differentiation from basalt is described by progressive fractional crystallization; however, to produce silica-oversaturated compositions two mechanisms are proposed: (1) polybaric fractionation with early-stage removal of amphibole at high pressures; and (2) assimilation–fractional crystallization to explain elevated 87 Sr/ 86 Sr i ratios. Most basalts are silica-undersaturated and enriched in incompatible trace elements (e.g. La/Yb N >10), indicating small degrees of partial melting of a garnet-bearing mantle. Mildly silica-undersaturated and rare silica-saturated basalts, including tholeiites, are less enriched (La/Yb N <10), a result of higher degrees of melting. Trace elements and isotopes (Sr, Nd, Pb) reveal a regional gradient explained by mixing between two mantle components, subduction-modified lithosphere and HIMU-like plume ( 206 Pb/ 204 Pb >20) materials. Geophysical studies indicate a deep thermal anomaly beneath central Marie Byrd Land, suggesting a plume influence on volcanism and tectonism.