This paper documents the lithology and geochemistry of vitric tephra deposits from the Pliocene-Pleistocene Hadar and Busidima Formations from the early hominin site of Hadar in Ethiopia. Vitric tephras of the Hadar Formation (ca. 3.45–2.9 Ma) are limited to certain facies of the Sidi Hakoma Tuff, the Kada Hadar Tuff, and the Bouroukie Tuff 2 (BKT-2) Complex, the latter of which is discussed in detail in this study. In contrast, this systematic study identified at least 12 distinct vitric tephras preserved in the Busidima Formation at Hadar (ca. 2.7–0.81 Ma), which are represented by no less than 20 chemical modes. These analyses are used to construct the first tephrostratigraphic-based sequence for the highly complex and discontinuous Busidima Formation deposits preserved at Hadar. Busidima Formation correlations have also been established between Hadar and neighboring project areas, specifically Dikika and Gona. Artifact Site Tuff 3 (AST-3), the Inaalale Tuff, and the Ken Di Tuff are correlated between Hadar and Dikika. AST-1, AST-3, the Ken Di Tuff, the Dahuli Tuff, and several localized tuffs of the Busidima Formation are correlated between Hadar and Gona. However, tuffs associated with the earliest archaeology in the two regions, namely AST-2 from Gona and BKT-3 from Hadar, were not identified outside their respective project areas. Nonetheless, the sequence of tephra provides important information for the placement and relationship of archaeological and paleontological sites both within Hadar and between Hadar and adjacent project areas.

Sediments exposed in the Dikika Research Project area form a nearly continuous sequence spanning the period from older than 3.8 Ma to younger than 0.15 Ma. By developing a stratigraphic framework of sedimentary basins, we are able to reconstruct a regional geological history that illuminates environmental changes resulting from tectonic events in the Afar triple junction region. The sequence begins with the Basal Member of the Hadar Formation, which was deposited on a dissected and deeply weathered surface of the uppermost flow of Dahla Series Basalt (8–4 Ma). This contact signals an increase in sediment accumulation rate due to active extension along faults parallel to the Red Sea Rift system. Sediments of the Hadar Formation indicate the progressive infilling of the Hadar Basin and migration of the shoreline northward or northeastward toward the axial depocenter, with several brief transgressions southward. After 2.9 Ma, the Dikika Research Project area was uplifted, and the Hadar Formation was faulted and eroded on an angular unconformity. Subsequent to 2.7 Ma, sedimentation returned, although the character and position of the newly developed Busidima half-graben had changed. This basin was formed by the rotation of an asymmetric marginal half-graben around a border fault that paralleled the western escarpment of the Ethiopian Rift. The Busidima Formation deposited in this basin records the migration of the paleo–Awash River across its floodplain in response to a changing tectonic setting. These local paleoenvironmental changes are primarily the response to regional tectonics and are superimposed on the global and regional records of climate change.

Mapping and description of the Hadar and Busidima Formations in the northern Awash valley, Ethiopia, have been greatly aided by the use of tephrostratigraphy and tephra correlation in the Dikika, Gona, Hadar, and Ledi-Geraru paleoanthropological project areas. The Hadar Formation contains at least nine dated tuffs, many of which have been correlated across the northern Awash project areas, and all of which are easily distinguished from each other on the basis of major-element chemistry. The overlying Busidima Formation contains at least 35 distinct tuffs, many of which are firmly or approximately dated. Because of their discontinuous and compositionally similar nature, many of the Busidima Formation tuffs are not correlated across the northern Awash project areas. Trace-element compositional data or detailed stratigraphic information may be necessary for correlation or relative placement of many of the Busidima Formation tuffs. Differences in the frequency, chemistry, and extent of Hadar and Busidima Formation tuffs preserved in the northern Awash valley may ultimately be related to the tectonic evolution of the region throughout the Pliocene-Pleistocene, as well as to basin-scale geological processes. Despite a number of known issues in tephra correlation, the composite tephrostratigraphy assembled for the northern Awash valley demonstrates the effectiveness of this technique, which has played a key role in ongoing efforts to document the geological history of this unique and important region.

Deposits in the Gona Paleoanthropological Research Project (GPRP) area in east-central Ethiopia span most of the last ~6.4 m.y. and are among the longest and most complete paleoenvironmental and human fossil archives in East Africa. The 40 Ar/ 39 Ar and paleomagnetic dates and tephrostratigraphic correlations establish the time spans for the four formations present at Gona: the Adu-Asa (>6.4–5.2 Ma), Sagantole (>4.6–3.9 Ma), Hadar (3.8–2.9 Ma), and Busidima Formations (2.7 to <0.16 Ma). The volcano-sedimentary succession at Gona displays many classic tectono-sedimentary features of an evolving rift basin. The mixed volcanic and fluviolacustrine Adu-Asa Formation is the earliest expression of rifting at Gona, probably deposited in a small half-graben. The Sagantole and Hadar Formations were deposited in a much larger half-graben bounded to the E-NE by an as-yet-unidentified normal fault. The Sagantole and Hadar Formations are both fluvial and lacustrine, reflecting periodic shallow impoundment of a low-gradient paleo–Awash River, perhaps by an accommodation zone north of the Ledi-Geraru project area. Starting at 2.9–2.7 Ma, the character of sedimentation changed dramatically throughout the Awash Valley as bed load coarsened and the meandering paleo–Awash River cyclically cut and filled. Unlike the Hadar Formation, the Busidima Formation thickens westward, suggesting deposition in a half-graben of the opposite polarity compared to Sagantole/Hadar time. Sedimentation rates decreased 5-fold, from 0.25 mm/yr in the Hadar Formation to 0.05 mm/yr in the Busidima Formation, perhaps in response to slowing extension rates and/or opening of the half-graben north of Gona.