Abstract In this chapter, we analyse the influence of the Carpathian Mountains on the variability of stable isotopes in precipitation by employing a combination of observed and model data. Overall, the mean value of the stable isotopes in precipitation over the Carpathian Mountains, based on observational data, was −9.8‰ for δ 18 O and −68.6‰ for δ 2 H. The local meteoric line, using all samples from the study sites, was δ 2 H = 7.65 × δ 18 O + 5.82. The simulated δ 18 O, based on the ECHAM5-wiso isotopes enable model, showed good agreement with the observed isotopic data. By comparing all the monthly values of the observed isotopic data from all analysed stations and the corresponding model data, a correlation coefficient of 0.76 ( n = 455, p < 0.001) was obtained. The spatial distribution of the simulated δ 18 O values in precipitation had the lowest values over the Romanian Carpathian Mountains and the highest values over the extra-Carpathian area, with the maximum in southeastern Romania. This pattern was strongly influenced by the Carpathian Mountains orography. Using the simulated δ 18 O data, we show that the spatial distribution of the δ 18 O values increases with temperature and decreases with altitude and latitude (−0.5‰ for δ 18 O per degree of latitude). The continental gradient is characterized by a polynomial trend of the second degree in the form of a large-open ‘U’ shape, and the general pattern of the δ 18 O values follows the spatial distribution of the Carpathian Mountains.

Abstract Oligocene and Lower Miocene deposits in the Paratethys are important source rocks, but reveal major stratigraphic and regional differences. As a consequence of the first Paratethys isolation, source rocks with very good oil potential accumulated during Early Oligocene time in the Central Paratethys. Coeval source rocks in the Eastern Paratethys are characterized by a lower source potential. With the exception of the Carpathian Basin and the eastern Kura Basin, the source potential of Upper Oligocene and Lower Miocene units is low. In general, this is also valid for rocks formed during the second (Kozakhurian) isolation of the Eastern Paratethys. However, upwelling along a shelf-break canyon caused deposition of prolific diatomaceous source rocks in the western Black Sea. Overall, Oligocene–Lower Miocene sediments in the Carpathian Basin (Menilite Formation) can generate up to 10 t HC m −2 . Its high petroleum potential is a consequence of the interplay of very high productivity of siliceous organisms and excellent preservation in a deep silled basin. In contrast, the petroleum potential of Oligocene–Lower Miocene (Maikopian) sediments in the Eastern Paratethys is surprisingly low (often <2 t HC m −2 ). It is, therefore, questionable whether these sediments are the only source rocks in the Eastern Paratethys.