Abstract The Cadia district of New South Wales contains four alkalic porphyry Au-Cu deposits (Cadia East, Ridgeway, Cadia Hill, and Cadia Quarry) and two Cu-Au-Fe skarn prospects (Big Cadia and Little Cadia), with a total of ~50 Moz Au and ~9.5 Mt Cu (reserves, resources, and past production). The ore deposits are hosted by volcaniclastic rocks of the Weemalla Formation and Forest Reefs Volcanics, which were deposited in a submarine basin on the flanks of the Macquarie Arc during the Middle to Late Ordovician. Alkalic magmatism occurred during the Benambran orogeny in the Late Ordovician to early Silurian, resulting in the emplacement of monzonite intrusive complexes and the formation of porphyry Au-Cu mineralization. Ridgeway formed synchronous with the first compressive peak of deformation and is characterized by an intrusion-centered quartz-magnetite-bornite-chalcopyrite-Au vein stockwork associated with calc-potassic alteration localized around the apex of the pencil-like Ridgeway intrusive complex. The volcanic-hosted giant Cadia East deposit and the intrusion-hosted Cadia Hill and Cadia Quarry deposits formed during a period of relaxation after the first compressive peak of the Benambran orogeny and are characterized by sheeted quartz-sulfide-carbonate vein arrays associated with subtle potassic, calc-potassic, and propylitic alteration halos.