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Abstract For the first time, we present a decadal-scale stable isotope record (δ 18 O, δ 13 C) of 67 speleothem calcite samples coming from an artificial tunnel network located in Graz, Austria. Stable isotope data are interpreted with the help of time series (TS) analysis of mean air temperatures (MAT) and mean annual precipitations (MAP) that have been monitored and recorded in a neighbouring meteorological station. Speleothem records have proved to be very useful in reconstructing changes of environmental conditions. For studied stalagmites, which grew between 1945 and 2018, the δ 18 O values average −18.64‰ and range from −23‰ to −17‰ (VPDB, Vienna Pee Dee Belemnite), suggesting variable climatic conditions. The δ 18 O values of calcite increase along the growth axis and are correlated with high temporal resolution MAT, MAP and weighted mean annual δ 18 O of precipitations. For the same time interval, while the temperature TS show an increasing trend, with a steeper gradient since the 1980s, the precipitation TS presents a weak decreasing tendency. Increase in the δ 13 C values of speleothems from −33‰ to −24‰ (VPDB) is correlated with increasing temperature and drought, associated CO 2 degassing and soil erosion over the tunnel system.
Raman spectroscopic quantification of tetrahedral boron in synthetic aluminum-rich tourmaline
Hooked on salt: Rethinking Alpine tectonics in Hallstatt (Eastern Alps, Austria)
ABSTRACT The Cretaceous-Paleocene (K/P) boundary intervals are rarely preserved in successions of shallow-water limestones. Here, we describe a shallow rocky shore on the active orogenic wedge of the eastern Alps (Austria) fringed by a carbonate platform that was largely cannibalized by erosion. We compared this succession with similar nearshore environments globally, as well as the deep sea, to gain a better understanding of the environmental response to the K/P boundary transition. In the eastern Alps, Cretaceous and Paleocene lithofacies across the K/P boundary transition are separated by a hardground that formed during subaerial exposure and that terminates Upper Maastrichtian limestone with planktic foraminiferal assemblages deposited at neritic depth during zone CF3 (ca. 66.500 Ma). Above the hardground, there are beachrocks with early Danian zone P1a(1) assemblages, which indicate the hardground spans about ~600 k.y. of nondeposition and/or erosion. During the early Danian, the marine transgressive fringe fluctuated between “shoreface to emersion” environments, depositing limestones rich in bryozoans, rhynchonellids, coralline algae, and rare planktic foraminifera along with abraded, bored, and/or encrusted clasts eroded from older rocks. Repeated short subaerial exposure is marked by vadose diagenesis and hardgrounds, including an ~1.5 m.y. interval between magnetochrons C29n to C28n and planktic foraminiferal zones P1b to P1c(2). Comparison with platform carbonate sequences from Croatia, Oman, Madagascar, Belize, and Guatemala, as well as nearshore siliciclastic environments of southern Tunisia, Texas, and Argentina, across the K/P boundary transition revealed surprisingly similar deposition and erosion patterns, with the latter correlative with sea-level falls and repeated subaerial exposure forming hardgrounds. Comparison with deep-sea depositional patterns revealed coeval but shorter intervals of erosion. This pattern shows a uniform response to the K/P boundary transition linked to climate and sea-level changes, whether in shallow nearshore or deep-sea environments, with climate change tied to Deccan volcanism in magnetochrons C29r-C29n.