ABSTRACT The formation of the “expansion breccia” observed in the Lower Cretaceous Maiolica limestone in the Umbria-Marches region of Italy is attributable to a fluid-assisted brecciation process that occurred during the late Miocene exhumation of the Northern Apennines. The hydrothermal fluids probably originated as brine solutions trapped in the Burano anhydrite while it was in a plastic state. The migration of the Burano from the plastic to the brittle domain during unroofing resulted in liberation and injection of over-pressured hydrothermal fluids into the overlying limestone, causing hydraulic fracturing. Mapping of breccia morphology along a 400-m transect showed structures produced by different flow regimes, with chaotic and mosaic breccia characterizing the core parts of the section and mineral-filled fractures and veins in the margins. Based on the clast size in the chaotic breccia, the estimated velocities for fluidizing the aggregates of clasts and sustaining the clasts in suspension are, respectively, 15 cm/s and 65 cm/s. Crack growth was probably the main mechanism for the fragmentation of the limestone. Explosion fracturing patterns were only sporadically observed in the breccia, indicating substantial heat loss of the over-pressured fluids during their ascent to the Earth’s surface.

ABSTRACT In total, 33 and 65 chrome-spinel (Cr-spinel) grains in the >63 and 32–63 μm size fractions, respectively, were recovered from 12 beds in two stratigraphically separated groups along the 240-m-thick Monte Acuto section of the Maiolica limestone in central Italy, spanning from the Berriasian to the early Hauterivian. The chemistry of these detrital spinels suggests they may represent windblown ophiolitic detritus, showing the evolution of an ophiolite evolving from a mid-ocean-ridge basalt setting (Bosso section) to a suprasubduction-zone setting, including a backarc and an arc setting (Monte Acuto section). The source of the Maiolica detrital minerals may have been the obducting ophiolites of the Albanides and/or the Hellenides, which show a similar evolution. In this case, it is particularly important to note how the Cr-spinel detritus in the Maiolica limestone records this evolution over a relatively short period of time, lasting ~10 m.y.

ABSTRACT The objective of this research was to determine the age relationships between Early Jurassic sedimentary units in the Umbria-Marche Apennines using strontium isotope stratigraphy. These age relations are critical for evaluating the mechanism by which the small platforms in the region formed. I present an alternative model for carbonate platform differentiation and evolution based on the strontium isotope data; this model relies primarily on growth of individual small platforms through differential sediment accumulation rather than the generally accepted model of extensive late-stage faulting. Strontium isotope stratigraphy provides a high-resolution correlation tool for the region. Because 87 Sr/ 86 Sr values steadily decrease in the Hettangian–Pliensbachian section of the Early Jurassic, they illuminate relationships in different carbonate facies very well. This is particularly valuable where physical and/or biostratigraphic correlation is difficult, such as in the Umbria-Marche carbonate platforms. Strontium isotopic ratios from measured basinal stratigraphic sections along the Burano and Bosso Rivers indicate that at least a 100 m section of the Corniola Formation was deposited while adjacent platforms continued to grow. The small Umbria-Marche platforms drowned synchronously in the late Sinemurian, based on 87 Sr/ 86 Sr values from several platforms at the end of Calcare Massiccio Formation deposition. Measured 87 Sr/ 86 Sr values for all platforms are the same within error. These stratigraphic relationships indicate that differentiation into shallow- and deep-water facies occurred in the latest Triassic/earliest Jurassic, early in the development of the margin. Current models explain the differentiation of platforms and basins by late-stage extensive normal faulting, requiring hundreds of meters of stratigraphic throw. Large-displacement faults are not consistent with the age relations determined by strontium isotope stratigraphy in the region. Minor faulting in the Late Triassic coupled with growth by differential sediment accumulation of small, shallow-water carbonate platforms continuing for several million years would produce the exposed platform/basin relationships. Inferred accumulation rates for the platform and basin sequences suggest that the observed relief of the platform escarpments was generated in less than 7 m.y., a time period consistent with the documented stratigraphy in the region.

ABSTRACT In the Umbria-Marche Apennines, direct evidence of earthquakes (including data from geodetic, geophysical, historical, and paleoseismological research) is not older than 20–10 ka, but the events themselves are influenced by the whole ~250 m.y. geological history of the region. For seismic sequences that have occurred in the past few decades, seismological data of increasing quality provide detailed images of the active NNW-SSE–trending normal fault systems in the upper 10 km of the crust. Major historical earthquakes and sparse paleoseismological data are also aligned parallel to the same lineaments, which clearly define the distribution of the major seismogenic sources of the region. The close connection between active tectonics and older Quaternary faults that border a series of extensional intramountain basins is demonstrated by the fact that seismogenic and Quaternary faults are distributed along the same alignments, formed within similarly oriented stress fields, and accommodate WSW-ENE extension coherently with the active strain field. The Quaternary to present tectonics form part of a long-lived extensional process, active over 15–20 m.y., which is migrating eastward through time across the Italian peninsula, superimposed on the previous compressional phase that created the Apennines. The older Umbria-Marche geological history, recorded in the Triassic to Paleogene stratigraphic succession of the region, also influences the present-day distribution of seismicity. Specifically, the complex mechanical stratigraphy of the region determines the superposition of rocks with different rheological behaviors and overall thickness of the seismogenic layer. Almost all of the earthquakes occur within the sedimentary cover, with main shocks located close to the basal contact with the underlying Paleozoic basement.

ABSTRACT The Popigai (100 km in diameter) and the Chesapeake Bay (40–85 km diameter) impact structures formed within ~10–20 k.y. in the late Eocene during a 2 m.y. period with enhanced flux of 3 He-rich interplanetary dust to Earth. Ejecta from the Siberian Popigai impact structure have been found in late Eocene marine sediments at numerous deep-sea drilling sites around the globe and also in a few marine sections outcropped on land, like the Massignano section near Ancona in Italy. In the Massignano section, the Popigai layer is associated with an iridium anomaly, shocked quartz, and abundant clinopyroxene-bearing (cpx) spherules, altered to smectite and flattened to “pancake spherules.” The ejecta are also associated with a significant enrichment of H-chondritic chromite grains (>63 μm), likely representing unmelted fragments of the impactor. The Massignano section also contains abundant terrestrial chrome-spinel grains, making reconstructions of the micrometeorite flux very difficult. We therefore searched for an alternative section that would be more useful for these types of studies. Here, we report the discovery of such a section, and also the first discovery of the Popigai ejecta in another locality in Italy, the Monte Vaccaro section, 90 km west of Ancona. The Monte Vaccaro section biostratigraphy was established based on calcareous nannoplankton, which allowed the identification of a sequence of distinct bioevents showing a good correlation with the Massignano section. In both the Monte Vaccaro and Massignano sections, the Popigai ejecta layer occurs in calcareous nannofossil zone CNE 19. The ejecta layer in the Monte Vaccaro section contains shocked quartz, abundant pancake spherules, and an iridium anomaly of 700 ppt, which is three times higher than the peak Ir measured in the ejecta layer at Massignano. In a 105-kg-size sample from just above the ejecta layer at Monte Vaccaro, we also found an enrichment of H-chondritic chromite grains. Because of its condensed nature and low content of terrestrial spinel grains, the Monte Vaccaro section holds great potential for reconstructions of the micrometeorite flux to Earth during the late Eocene using spinels.

ABSTRACT We reconstructed a record of the micrometeorite flux in the Late Cretaceous using the distribution of extraterrestrial spinel grains across an ~2 m.y. interval of elevated 3 He in the Turonian Stage (ca. 92–90 Ma). From ~30 m of the limestone succession in the Bottaccione section, Italy, a total of 979 kg of rock from levels below and within the 3 He excursion yielded 603 spinel grains (32–355 μm size). Of those, 115 represent equilibrated ordinary chondritic chromite (EC). Within the 3 He excursion, there is no change in the number of EC grains per kilogram of sediment, but H-chondritic grains dominate over L and LL grains (70%, 27%, and 3%), contrary to the interval before the excursion, where the relation between the three groups (50%, 44%, and 6%) is similar to today and to the Early Cretaceous. Intriguingly, within the 3 He anomaly, there is also a factor-of-five increase of vanadium-rich chrome spinels likely originating from achondritic and unequilibrated ordinary chondritic meteorites. The 3 He anomaly has an unusually spiky and temporal progression not readily explained by present models for delivery of extraterrestrial dust to Earth. Previous suggestions of a relation to a comet or asteroid shower possibly associated with dust-producing lunar impacts are not supported by our data. Instead, the spinel data preliminary indicate a more general disturbance of the asteroid belt, where different parent bodies or source regions of micrometeorites were affected at the same time. More spinel grains need to be recovered and more oxygen isotopic analyses of grains are required to resolve the origin of the 3 He anomaly.

ABSTRACT What causes recurrent mass extinctions of life? We find that the ages of 10 of the 11 well-documented extinction episodes of the last 260 m.y. show correlations, at very high confidence (>99.99%), with the ages of the largest impact craters or the ages of massive continental flood-basalt eruptions. The four largest craters (≥100 km diameter, impact energies ≥3 × 10 7 Mt trinitrotoluene [TNT]) can be linked with recognized extinction events at 36, 66, 145, and 215 Ma, and with stratigraphic distal impact debris correlative with the extinctions. The ages of 7 out of 11 major flood-basalt episodes can be correlated with extinction events at 66, 94, ca. 120, 183, 201, 252, and 260 Ma. All seven flood-basalt–extinction co-events have coincident volcanogenic mercury anomalies in the stratigraphic record, closely linking the extinctions to the volcanism. Furthermore, the seven major periods of widespread anoxia in the oceans of the last 260 m.y. are significantly correlated (>99.99%) with the ages of the flood-basalt–extinction events, supporting a causal connection through volcanism-induced climate warming. Over Phanerozoic time (the last 541 m.y.), the six “major” mass extinctions (≥40% extinction of marine genera) are all correlated with the ages of flood-basalt episodes, and stratigraphically with related volcanogenic mercury anomalies. In only one case, the end of the Cretaceous (66 Ma), is there an apparent coincidence of a “major” mass-extinction event with both a very large crater (Chicxulub) and a continental flood-basalt eruption (the Deccan Traps). The highly significant correlations indicate that extinction episodes are typically related to severe environmental crises produced by the largest impacts and by periods of flood-basalt volcanism. About 50% of the impacts of the past 260 m.y. seem to have occurred in clusters, supporting a picture of brief pulses of increased comet or asteroid flux. The largest craters tend to fall within these age clusters. Cross-wavelet transform analyses of the ages of impact craters and extinction events show a common, strong ~26 m.y. cycle, with the most recent phase of the cycle at ~12 Ma, correlating with a minor extinction event at 11.6 Ma. The stream of life flows so slowly that the imagination fails to grasp the immensity of time required for its passage, but like many another stream it pulses irregularly as it flows. There are times of quickening, the expression points of evolution, which are almost invariably coincident with some great geologic change, and the correspondence so exact and so frequent that the laws of chance may not be invoked by way of explanation. —Richard Swann Lull ( Organic Evolution , New York, Macmillan, 1929, p. 693)

ABSTRACT The geochemical signatures of sparry calcite-sealing expansion breccias, calcite veins, and host clasts were analyzed for their strontium ( 87 Sr/ 86 Sr) and oxygen and carbon (δ 18 O, δ 13 C) stable isotopic signatures. The breccias occur within the Lower Cretaceous Maiolica Formation. Related but different breccias are found in a few places in the Upper Cretaceous to Eocene Scaglia Rossa Formation of the Umbria-Marche Apennines fold-and-thrust belt (Italy). We propose hydraulic fracturing by fluid overpressure as a possible mechanism for generation of the breccias in these formations. Our data are compatible with the hypothesis of a hydraulically fractured breccia formed by cyclic buildup and rapid decompression of CO 2 -rich fluids, with overpressures generated by entrapment of CO 2 by structural and stratigraphic seals. Strontium and oxygen isotope ratio data suggest that the CO 2 -rich fluids may have originated from carbonate metasomatism of the mantle, resulting from subduction of carbonate-rich lithologies constituting the downgoing slab. This is consistent with previous conceptual models inferring that in the central part of the Northern Apennines, which is characterized by thick continental crust, CO 2 -rich fluids derived from mantle metasomatism would become trapped in structural seals, creating high fluid overpressures.

ABSTRACT In this study, we discuss the results from different luminescence dating methods applied to four samples of Pleistocene slack-water sediments from the Frasassi hypogenic cave system, in the northeastern Apennines of Italy. Two samples came from a well-sorted, fine sand deposit in the Grotta Grande del Vento cave (SDS site), while two others were taken from a borehole through a clayey deposit in the adjacent Caverna del Carbone cave (CDC site). Both sites are located at an elevation of ~235 m above sea level (asl), which corresponds to ~30 m above the thalweg of the Sentino River flowing through the Frasassi Gorge outside the cave. In the Frasassi multistory cave system, the elevation of 235 ± 5 m asl corresponds to the third karst level or “floor,” the minimum age of which from speleothem U-Th dating is ca. 130 ± 15 ka. The luminescence ages for the two samples from the SDS site are in good agreement with each other within error, just like the two samples from the CDC profile. Different luminescence dating protocols were used to determine the ages for each individual sample. By applying this comparative approach, and taking the luminescence characteristics of the samples into consideration (quartz optically stimulated luminescence, different feldspar luminescence signals), the ages could be based on the most robust measurement protocol. The ages presented here were all derived from measurements using the post-infrared infrared signal of potassium-rich feldspar stimulated at a temperature of 225 °C (pIRIR225). Incomplete bleaching of the luminescence signal prior to deposition, leading to age overestimation when not detected and corrected for, was not a significant factor for the samples under investigation, because ages calculated for luminescence signals with different bleachability yielded results in agreement within error. Bleaching can therefore be assumed to have been sufficient before the samples entered the cave system. The ages determined for both sites are reliable from a methodological standpoint. The pIRIR225 luminescence dates from the SDS sand range between 129 and 101 ka and are consistent with the minimum age for the third cave floor (~235 m asl) as obtained from previous U-Th dating. In contrast, the pIRIR225 luminescence dates obtained from the clay-rich CDC deposit range from 217 to 158 ka, which is consistent with the minimum age for the fifth subhorizontal cave level when measured from the modern water table, found at ~65 m above the present river thalweg. This apparent discrepancy may be due to the fact that the present entrance of the CDC cave was incised by the river on the south side of Frasassi Gorge sometime during the Eemian interglacial period (marine isotope stage [MIS] 5e), but, being part of a hypogenic karst system in an uplifting tectonic structure, the actual third floor was preexisting, thus anteceding the river incision. On the other hand, the fifth floor of the cave system, some 30 m above the third floor, was incised sometime during the interglacial MIS 7 at around 200 ka, at a time when the saturated phreatic third floor had already been formed and thus was capable of collecting the fine suspension sediment settling from muddy river water flooding the cave.

ABSTRACT In this study, we present a composite δ 18 O and δ 13 C record obtained from four speleothems from the Grotta Grande del Vento Cave, located within the Frasassi karst system, northeastern Apennines of central Italy. The ages were determined by U-series analysis, employing thermal ionization mass spectrometry (TIMS), and the composite isotopic profile covers most of the time period from ca. 95,000 yr B.P. until ca. 10,000 yr B.P., including the last part of marine isotope stage (MIS) 5, most of the last glacial (MIS 4–2), and the earliest Holocene (MIS 1), with a hiatus lasting from ca. 65,000 to ca. 55,000 yr B.P. We compared this record with other speleothem records from the Eastern Mediterranean, with caves from western Portugal, with two marine records from the Eastern Mediterranean and the Aegean Sea, and with the North Greenland Ice Core Project (NGRIP) ice-core record. The Frasassi speleothem record provides further insight for a wider regional understanding of the paleoclimate record through the discrepancies and similarities between the northeastern Apennines of central Italy and the Western, Eastern, and northeastern Mediterranean regions. The time interval between ca. 86,000 and 83,000 yr B.P. shows low δ 18 O values in the Western and Eastern Mediterranean speleothems and the marine records. This period coincides with sapropel (S3) and is associated with increased hydrological activity and warming. On the other hand, Frasassi speleothem δ 18 O data do not show a similar low trend, suggesting that increased hydrological activity either did not reach the Frasassi region and/or the region received rainfall from other sources and/or the proportion of winter-summer rainfall was different. Another interval in which different conditions prevailed in the Frasassi region is during the transition from MIS 5 to glacial MIS 4, from ca. 83,000 to 65,000 yr B.P., when Frasassi speleothem δ 18 O values decreased, whereas all other records show a clear increase in δ 18 O. Comparison with the NGRIP record suggests that Northern Hemisphere temperature changes are reflected in Frasassi speleothem δ 18 O fluctuations during this interval. A major pronounced isotopic event associated with warming and pluvial conditions during the last glacial evident in the entire Mediterranean region between ca. 54,500 and 52,500 yr B.P. is recorded also in the Frasassi speleothem isotopic profile. This event is followed by a transition from wet and warm climatic conditions to cold conditions. The end of the last glacial is associated with climate instability, evident mainly from the very large oscillations in the Frasassi δ 13 C record. The transition from the last glacial to early Holocene is characterized by a decreasing trend in δ 18 O and a sharp increase in δ 13 C values.

ABSTRACT The massive Jurassic limestone making up the core of the Frasassi-Valmontagnana blind thrust anticline hosts a large sulfidic cave complex, which, due to Pleistocene tectonic uplift, has been incised by the Sentino River, forming the deep Frasassi Gorge. The Frasassi cave complex is organized into seven horizontal levels, with the youngest and presently active one at river level, and the oldest (ca. 1.2 Ma) one some 200 m above the Sentino River. Therefore, the Frasassi cave complex records the river incision history of this still-active Apennine mountain belt. In addition to an uplift rate of ~0.55 mm/yr for the Holocene, previous radioisotopic dating and surveying of phreatic calcite deposits revealed an overall tilting of the Frasassi anticline of ~0.2° toward N60E for the past 9000 or so years. Our study adds to this history of tectonic tilting by focusing on a group of 30 tilted stalagmites found at the bottom of the Abisso Ancona of the Grotta Grande del Vento (the largest room in the Frasassi complex). These stalagmites have a fairly uniform plunge of ~81° trending toward N30W, and we interpret this to record a tilt of the cave toward S30E during the formation of the stalagmites. From U-Th dating of these paleotiltmeters, we deduce that the Frasassi anticline was tilted by ~0.3° from 32 to 7 k.y. B.P., and the tilt rate gradually increased during this period. The 60° (NE) direction of oblique-slip faults in this area and the local focal mechanisms of recent seismic activity suggest that the tilting is caused by movement along a listric oblique strike-slip zone south of the Frasassi anticline. Our findings also demonstrate that given the right conditions, stalagmites can be used as paleotiltmeters that provide insight into recent crustal deformation.