ABSTRACT Quantitative insights into the geochemistry and petrology of proximal impactites are fundamental to understand the complex processes that affected target lithologies during and after hypervelocity impact events. Traditional analytical techniques used to obtain major- and trace-element data sets focus predominantly on either destructive whole-rock analysis or laboratory-intensive phase-specific micro-analysis. Here, we present micro–X-ray fluorescence (µXRF) as a state-of-the-art, time-efficient, and nondestructive alternative for major- and trace-element analysis for both small and large samples (up to 20 cm wide) of proximal impactites. We applied µXRF element mapping on 44 samples from the Chicxulub, Popigai, and Ries impact structures, including impact breccias, impact melt rocks, and shocked target lithologies. The µXRF mapping required limited to no sample preparation and rapidly generated high-resolution major- and trace-element maps (~1 h for 8 cm 2 , with a spatial resolution of 25 µm). These chemical distribution maps can be used as qualitative multi-element maps, as semiquantitative single-element heat maps, and as a basis for a novel image analysis workflow quantifying the modal abundance, size, shape, and degree of sorting of segmented components. The standardless fundamental parameters method was used to quantify the µXRF maps, and the results were compared with bulk powder techniques. Concentrations of most major elements (Na 2 O–CaO) were found to be accurate within 10% for thick sections. Overall, we demonstrate that µXRF is more than only a screening tool for heterogeneous impactites, because it rapidly produces bulk and phase-specific geochemical data sets that are suitable for various applications within the earth sciences.

ABSTRACT During hypervelocity impacts, target rocks are subjected to shock wave compression with high pressures and differential stresses. These differential stresses cause microscopic shear-induced deformation, which can be observed in the form of kinking, twinning, fracturing, and shear faulting in a range of minerals. The orientation of these shear-induced deformation features can be used to constrain the maximum shortening axis. Under the assumption of pure shear deformation, the maximum shortening axis is parallel to the maximum principal axis of stress, σ 1 , which gives the propagation direction of the shock wave that passed through a rock sample. In this study, shocked granitoids cored from the uppermost peak ring of the Chicxulub crater (International Ocean Discovery Program [IODP]/International Continental Drilling Project [ICDP] Expedition 364) were examined for structures formed by shearing. Orientations of kink planes in biotite and basal planar deformation features (PDFs) in quartz were measured with a U-stage and compared to a previous study of feather feature orientations in quartz from the same samples. In all three cases, the orientations of the shortening axis derived from these measurements were in good agreement with each other, indicating that the shear deformation features all formed in an environment with similar orientations of the maximum principal axis of stress. These structures formed by shearing are useful tools that can aid in understanding the deformational effects of the shock wave, as well as constraining shock wave propagation and postshock deformation during the cratering process.