Abstract: Deformation bands significantly alter the local petrophysical properties of sandstone reservoirs, although it is not known how the intrinsically variable characteristics of sandstones (e.g. grain size, sorting and mineralogy) influence the nature and distribution of deformation bands. To address this, cataclastic deformation bands within fine- and coarse-grained Triassic Sherwood Sandstone at Thurstaston, UK were analysed, for the first time, using a suite of petrographical techniques, outcrop studies, helium porosimetry and image analysis. Deformation bands are more abundant in the coarse-grained sandstone than in the underlying fine-grained sandstone. North- and south-dipping conjugate sets of cataclastic bands in the coarse-grained sandstone broadly increase in density (defined by number/m 2 ) when approaching faults. Microstructural analysis revealed that primary grain size controls deformation band density. Deformation bands in both coarse and fine sandstones led to significantly reduced porosity, and so can represent barriers or baffles to lateral fluid flow. Microstructural data show preferential cataclasis of K-feldspar grains within the host rock and deformation band. The study is of direct relevance to the prediction of reservoir quality in several petroleum-bearing Lower Triassic reservoirs in the near offshore, as deformation band development occurred prior to Carboniferous source-rock maturation and petroleum migration.

Abstract: Current understanding of porosity preservation in deeply buried sandstone reservoirs tends to be focused on how diagenetic grain coatings of clay minerals and microquartz can inhibit macroquartz cementation. However, the importance of overpressure developed during initial (shallow) burial in maintaining high primary porosity during subsequent burial has generally not been appreciated. Where pore fluid pressures are high, and the vertical effective stress is low, the shallow arrest of compaction can allow preservation of high porosity and permeability at depths normally considered uneconomic. The deeply buried fluvial sandstone reservoirs of the Triassic Skagerrak Formation in the Central Graben, North Sea, show anomalously high porosities at depths greater than 3500 metres below sea floor (mbsf ). Pore pressures can exceed 80 MPa in the upper part of the Skagerrak Formation at depths of 4000–5000 mbsf, where temperatures are above 140°C. The Skagerrak reservoirs commonly have high primary porosities of up to 35%, little macroquartz cement and variable amounts of diagenetic chlorite grain coats. This research sheds light on the complex controls on reservoir quality in the fluvial sandstones of the Skagerrak Formation by identifying the role of shallow overpressure in arresting mechanical compaction and the importance of chlorite detrital grain coatings in inhibiting macroquartz cement overgrowth as temperature increases during progressive burial.

Abstract: The occurrence and distribution of minerals in modern sedimentary systems hold many clues to help unravel the origin and distribution of reservoir quality-controlling minerals in ancient and deeply buried sandstones, but few quantitative studies have been undertaken. Here we have used a range of techniques including X-ray diffraction, scanning electron microscopy and fully automated mineralogical QEMSCAN analysis to provide a comprehensive understanding of mineral composition and distribution within the post-glacial, clastic sediments of the Ravenglass Estuary, NW England. The Ravenglass Estuary is fed by two main rivers: one drains a granite-dominated hinterland, the other drains a hinterland that contains andesite and Triassic red bed sandstones. The granite-supplied arm has slightly more quartz-rich and Fe mineral-poor sediment than the andesite- and red bed-supplied sediment. The provenance signals are muted for feldspar and mica minerals heavy-mineral garnet populations seem to be sensitive to provenance. Detrital K-feldspar grains are preferentially associated with illite-dominated clay mineral coats, whereas all plagioclase mineral grains are preferentially associated with kaolinite-dominated clay mineral coats. This can be explained by rapid early diagenesis in the sediment with K-feldspar grain surfaces replaced by illite and plagioclase grain surfaces replaced by kaolinite. The andesite- and red bed-supplied sediment contains twice the amount of Fe minerals, which are dominated by chlorite, than the granite-supplied sediment. Chlorite rarely is associated with grain coatings on feldspar grains, possibly because it is predominantly a detrital mineral. Detrital Fe minerals seem to be locally replaced by pyrite due to bacterial sulphate reduction, suggesting that some early diagenetic processes may serve to lock away iron and prevent it from creating Fe-rich clay minerals.

Using zircons taken from two granite plutons, Strontian (Caledonian, northwestern Scotland) and Kameruka (Bega Batholith, southeastern Australia), this study presents observations that have a bearing on refractory zircons as provenance indicators. Two broad textural types of refractory zircon were identified: (1) those which show simple two-stage growth histories; and (2) those which have apparently undergone repeated periods of growth, resorption, mechanical abrasion, fracturing and fracture-healing. SHRIMP U–Pb ages obtained from the Kameruka zircons indicate that the cores are the textural manifestation of inheritance. The shapes of refractory cores are not unambiguously indicative of their ultimate origin, since they may also be modified by processes that occur before and after incorporation into the magma. The cores within the two populations show a great diversity in types and styles of zoning, and in composition, implying that they have not chemically equilibrated internally, or externally with their host melt.

It is now generally accepted that British Tertiary granites contain crustal and mantle components. Genesis principally by differentiation of crustally contaminated basaltic magmas is widely held and silicic melts with some remarkable trace element similarities were generated within different upper crust along the St Kilda/Skye – Carlingford zone. New whole-rock (and mineral) O isotope data for the southern sector of the province (N Arran, Ailsa Craig, Mourne Mountains, Slieve Gullion, etc) reveal that δ 18 O lies in the range +5.1 to +9.7‰ for most of the analysed granites, meteoric water-rock interaction having been in general less intensive than at Skye and Mull. Nevertheless, highly 18 O-depleted country rocks (with δ 18 O<0) exist adjacent to the N Arran and Mourne Mountains granite plutons. There is as yet no evidence for the existence of low – 18 O granitic melts in this southern sector where magmatic δ 18 O compositions (up to c . +9.5‰) can be inferred for some of the intrusions. New Nd (and Sr) isotope data indicate that although there is some similarity in initial 87 Sr/ 86 Sr ratios between the northern and southern sector granites, in northeastern Ireland initial ε Nd values for the analysed Tertiary acid major intrusions range from −3.9 to −4.5. This is in marked contrast to the Skye granites, some of which have values below −20, reflecting the involvement of different lithosphere.

Using the ion microprobe SHRIMP we have analysed zircons from the Ben Vuirich, Glen Kyllachy, Inchbae and Vagastie Bridge granites from the Scottish Caledonides, in an attempt to resolve the ages of inherited zircons shown to be present in these granites by previous conventional multigrain analyses. Middle Proterozoic age components were found in inherited zircons from all four granites. Late Proterozoic (900–1,100 Ma) components have been identified in zircons from the Glen Kyllachy and Ben Vuirich granites in the Grampian Highlands. A Late Archaean age has only been detected in one zircon from the Glen Kyllachy granite. The distribution of inherited components in the granite zircon populations could reflect fundamental divisions in the age composition of granite source rocks; however, detailed assessment of this possibility must await further ion microprobe analyses on zircons from many more granites. SHRIMP isotopic and U, Th and Pb analyses were made on successive shells of zoned zircon surrounding inherited cores from the Glen Kyllachy granite to monitor chemical changes during magmatic zircon growth. Results show that zircon shells have characteristic but significantly different Th, U and Pb concentrations. Magmatic zircon from the Vagastie Bridge granite also forms as clearly defined oscillatory zoned shells around unzoned nuclei of inherited zircon. However, the distinction between magmatic and inherited zircon in zircons from the Inchbae granite is less clear. Zircons from the Ben Vuirich granite occur as euhedral, magmatic zircons, or as rounded, subhedral, inherited zircon grains. A SHRIMP age of 597±11 (2σ) Ma for euhedral magmatic zircon from this granite is identical, within the uncertainty, to the conventional multigrain zircon age of 590± 2 (2σ) Ma reported by Rogers et al. (1989) and confirms the conclusions of those authors that sedimentation of the Dalradian sequence took place in the Precambrian.

The Criffell pluton in southwestern Scotland (397 Ma, a Newer Granite of late Caledonian age) is concentrically zoned with outer granodiorites of typically I-type aspect passing into inner granite with more evolved characteristics. The zonation is examined in terms of the compositional surfaces of bulk parameters such as SiO 2 and Rb/Sr and compositional variation is best modelled as multi-pulse, there being greater variation in bulk composition between pulses than within pulse. Published variations in Sr, Nd and O isotopes reflect the derivation of the pulses from separate and isotopically distinct sources. Other evidence for open-system behaviour includes mingling with mafic magmas to form enclaves, whereas closed-system behaviour is indicated by restite separation in the early granodiorites, and fractional crystallisation in the late granites. A dominant infracrustal I-type magma formed the first pulse followed by magma derived from more evolved crustal rocks (mainly metasediments of varying ages and maturities). Experimental fluid-absent melting of amphibolite and metapelite at about 900°C has shown that significant quantities of melt can be generated, respectively with I-type and S-type characteristics. Despite having similar bulk compositions, these melts have very different viscosities and densities for the same H 2 O contents (η S-type >η I-type and ρ s-type ≤ ρ I-type ). It is argued that the rheological controls on magma escape from the source region along complex and tortuous pathways favour the more fluid I-type melts over the more viscous (and only slightly less dense) S-type melts. This constraint could have the effect of reversing the expected buoyancy-driven emplacement sequence, and may represent an alternative rheological differentiation mechanism for the formation of some zoned plutons.