Abstract The tectonic evolution of Antarctica in the Mesozoic and Cenozoic eras was marked by igneous activity that formed as a result of simultaneous continental rifting and subduction processes acting during the final stages of the southward drift of Gondwana towards the South Pole. For the most part, continental rifting resulted in the progressive disintegration of the Gondwana supercontinent from Middle Jurassic times to the final isolation of Antarctica at the South Pole following the Cenozoic opening of the surrounding ocean basins, and the separation of Antarctica from South America and Australia. The initial rifting into East and West Gondwana was proceeded by emplacement of large igneous provinces preserved in present-day South America, Africa and Antarctica. Continued rifting within Antarctica did not lead to continental separation but to the development of the West Antarctic Rift System, dividing the continent into the East and West Antarctic plates, and uplift of the Transantarctic Mountains. Motion between East and West Antarctica has been accommodated by a series of discrete rifting pulses with a westward shift and concentration of the motion throughout the Cenozoic leading to crustal thinning, subsidence, elevated heat flow conditions and rift-related magmatic activity. Contemporaneous with the disintegration of Gondwana and the isolation of Antarctica, subduction processes were active along the palaeo-Pacific margin of Antarctica recorded by magmatic arcs, accretionary complexes, and forearc and back-arc basin sequences. A low in magmatic activity between 156 and 142 Ma suggests that subduction may have ceased during this time. Today, following the gradual cessation of the Antarctic rifting and surrounding subduction, the Antarctic continent is situated close to the centre of a large Antarctic Plate which, with the exception of an active margin on the northern tip of the Antarctic Peninsula, is surrounded by active spreading ridges.

Abstract In the last two centuries, demographic expansion and extensive urbanization of volcanic areas have increased the exposure of our society to volcanic hazards. Antarctica is no exception. During the last decades, the permanent settlement and seasonal presence of scientists, technicians, tourists and logistical personnel close to active volcanoes in the south polar region have increased notably. This has led to an escalation in the number of people and the amount of infrastructure exposed to potential eruptions. This requires advancement of our knowledge of the volcanic and magmatic history of Antarctic active volcanoes, significant improvement of the monitoring networks, and development of long-term hazard assessments and vulnerability analyses to carry out the required mitigation actions, and to elaborate on the most appropriate response plans to reduce loss of life and infrastructure during a future volcanic crisis. This chapter provides a brief summary of the active volcanic systems in Antarctica, highlighting their main volcanological features, which monitoring systems are deployed (if any), and recent (i.e. Holocene and/or historical) eruptive activity or unrest episodes. To conclude, some notes about the volcanic hazard assessments carried out so far on south polar volcanoes are also included, along with recommendations for specific actions and ongoing research on active Antarctic volcanism.

Abstract The break-up of Gondwana during the Early–Middle Jurassic was associated with flood basalt volcanism in southern Africa and Antarctica (Karoo–Ferrar provinces), and formed one of the most extensive episodes of continental magmatism of the Phanerozoic. Contemporaneous felsic magmatism along the proto-Pacific margin of Gondwana has been referred to as a silicic large igneous province, and is exposed extensively in Patagonian South America, the Antarctic Peninsula and elsewhere in West Antarctica. Jurassic-age silicic volcanism in Patagonia is defined as the Chon Aike province and forms one of the most voluminous silicic provinces globally. The Chon Aike province is predominantly pyroclastic in origin, and is characterized by crystal tuffs and ignimbrite units of rhyolite composition. Silicic volcanic rocks of the once contiguous Antarctic Peninsula form a southward extension of the Chon Aike province and are also dominated by silicic ignimbrite units, with a total thickness exceeding 1 km. The ignimbrites include high-grade rheomorphic ignimbrites, as well as unwelded, lithic-rich ignimbrites. Rhyolite lava flows, air-fall horizons, debris-flow deposits and epiclastic deposits are volumetrically minor, occurring as interbedded units within the ignimbrite succession.

Abstract Large-volume rhyolitic volcanism along the proto-Pacific margin of Gondwana consists of three major episodes of magmatism or ‘flare-ups’. The initial episode (V1) overlaps with the Karoo–Ferrar large igneous provinces at c. 183 Ma. A second (V2) episode was erupted in the interval 171–167 Ma, and a third episode (V3) was emplaced in the interval 157–153 Ma. The magmatic events of the V1 and V2 episodes of the Antarctic Peninsula are reviewed here describing major and trace elements, and isotopic (Sr, Nd, O) data from rhyolitic volcanic rocks and more minor basaltic magmatism. An isotopically uniform intermediate magma developed as a result of anatexis of hydrous mafic lower crust, which can be linked to earlier, arc-related underplating. The subsequent lower-crust partial melts mixed with fractionated mafic underplate, followed by mid-crust storage and homogenization. Early Jurassic (V1) volcanic rocks of the southern Antarctic Peninsula are derived from the isotopically uniform magma, but they have mixed with melts of upper-crustal paragneiss in high-level magma chambers. The V2 rhyolites from the northern Antarctic Peninsula are the result of assimilation and fractional crystallization of the isotopically uniform magma. This process took place in upper-crust magma reservoirs involving crustal assimilants with an isotopic composition akin to that of the magma. A continental margin-arc setting was critical in allowing the development of an hydrous, fusible lower crust. Lower-crustal anatexis was in response to mafic underplating associated with the mantle plume thought to be responsible for the contemporaneous Karoo magmatic province and rifting associated with the initial break-up of Gondwana.

Abstract The voluminous continental margin volcanic arc of the Antarctic Peninsula is one of the major tectonic features of West Antarctica. It extends from the Trinity Peninsula and the South Shetland Islands in the north to Alexander Island and Palmer Land in the south, a distance of c. 1300 km, and was related to east-directed subduction beneath the continental margin. Thicknesses of exposed volcanic rocks are up to c. 1.5 km, and the terrain is highly dissected by erosion and heavily glacierized. The arc was active from Late Jurassic or Early Cretaceous times until the Early Miocene, a period of climate cooling from subtropical to glacial. The migration of the volcanic axis was towards the trench over time along most of the length of the arc. Early volcanism was commonly submarine but most of the volcanism was subaerial. Basaltic–andesitic stratocones and large silicic composite volcanoes with calderas can be identified. Other rock associations include volcaniclastic fans, distal tuff accumulations, coastal wetlands and glacio-marine eruptions. Other groups of volcanic rocks of Jurassic age in Alexander Island comprise accreted oceanic basalts within an accretionary complex and volcanic rocks erupted within a rift basin along the continental margin that apparently predate subduction.

Abstract The Antarctic Peninsula contains a record of continental-margin volcanism extending from Jurassic to Recent times. Subduction of the Pacific oceanic lithosphere beneath the continental margin developed after Late Jurassic volcanism in Alexander Island that was related to extension of the continental margin. Mesozoic ocean-floor basalts emplaced within the Alexander Island accretionary complex have compositions derived from Pacific mantle. The Antarctic Peninsula volcanic arc was active from about Early Cretaceous times until the Early Miocene. It was affected by hydrothermal alteration, and by regional and contact metamorphism generally of zeolite to prehnite–pumpellyite facies. Distinct geochemical groups recognized within the volcanic rocks suggest varied magma generation processes related to changes in subduction dynamics. The four groups are: calc-alkaline, high-Mg andesitic, adakitic and high-Zr, the last two being described in this arc for the first time. The dominant calc-alkaline group ranges from primitive mafic magmas to rhyolite, and from low- to high-K in composition, and was generated from a mantle wedge with variable depletion. The high-Mg and adakitic rocks indicate periods of melting of the subducting slab and variable equilibration of the melts with mantle. The high-Zr group is interpreted as peralkaline and may have been related to extension of the arc.

Abstract Young volcanic centres of the Bransfield Strait and James Ross Island occur along back-arc extensional structures parallel to the South Shetland island arc. Back-arc extension was caused by slab rollback at the South Shetland Trench during the past 4 myr. The variability of lava compositions along the Bransfield Strait results from varying degrees of mantle depletion and input of a slab component. The mantle underneath the Bransfield Strait is heterogeneous on a scale of approximately tens of kilometres with portions in the mantle wedge not affected by slab fluids. Lavas from James Ross Island east of the Antarctic Peninsula differ in composition from those of the Bransfield Strait in that they are alkaline without evidence for a component from a subducted slab. Alkaline lavas from the volcanic centres east of the Antarctic Peninsula imply variably low degrees of partial melting in the presence of residual garnet, suggesting variable thinning of the lithosphere by extension. Magmas in the Bransfield Strait form by relatively high degrees of melting in the shallow mantle, whereas the magmas some 150 km further east form by low degrees of melting deeper in the mantle, reflecting the diversity of mantle geodynamic processes related to subduction along the South Shetland Trench.

Abstract The Antarctic Peninsula is distinguished by late Neogene volcanic activity related to a series of northerly younging ridge crest–trench collisions and the progressive opening of ‘slab windows’ in the subjacent mantle. The outcrops were amongst the last to be discovered in the region, with many occurrences not visited until the 1970s and 1980s. The volcanism consists of several monogenetic volcanic fields and small isolated centres. It is sodic alkaline to tholeiitic in composition, and ranges in age between 7.7 Ma and present. No eruptions have been observed (with the possible, but dubious, exception of Seal Nunataks in 1893) but very young isotopic ages for some outcrops suggest that future eruptions are a possibility. The eruptions were overwhelmingly glaciovolcanic and the outcrops have been a major source of information on glaciovolcano construction. They have also been highly influential in advancing our understanding of the configuration of the Plio-Pleistocene Antarctic Peninsula Ice Sheet. However, our knowledge is hindered by a paucity of modern, precise isotopic ages. In particular, there is no obvious relationship between the age of ridge crest–trench collisions and the timing of slab-window volcanism, a puzzle that may only be resolved by new dating.

Abstract Scattered occurrences of Miocene–Recent volcanic rocks of the alkaline intraplate association represent one of the last expressions of magmatism along the Antarctic Peninsula. The volcanic rocks were erupted after the cessation of subduction which stopped following a series of northward-younging ridge crest–trench collisions. Volcanism has been linked to the development of a growing slab window beneath the extinct convergent margin. Geochemically, lavas range from olivine tholeiite through to basanite and tephrite. Previous studies have emphasized the slab-window tectonic setting as key to allowing melting of peridotite in the asthenospheric void caused by the passage of the slab beneath the locus of volcanism. This hypothesis is revisited in the light of more recent petrological research, and an origin from melting of subducted slab-hosted pyroxenite is considered here to be a more viable alternative for their petrogenesis. Because of the simple geometry of ridge subduction, and the well-established chronology of ridge crest–trench collisions, the Antarctic Peninsula remains a key region for understanding the transition from active to passive margin resulting from cessation of subduction. However, there are still some key issues relating to their tectonomagmatic association, and, principally, the poor geochronological control on the volcanic rocks requires urgent attention.

Abstract Deception Island (South Shetland Islands) is one of the most active volcanoes in Antarctica, with more than 15 explosive eruptive events registered over the past two centuries. Recent eruptions (1967, 1969 and 1970) and volcanic unrest episodes in 1992, 1999 and 2014–15 demonstrate that the occurrence of future volcanic activity is a valid and pressing concern for scientists, logistic personnel and tourists that are visiting or are working on or near the island. Over the last few decades, intense research activity has been carried out on Deception Island to decipher the origin and evolution of this very complex volcano. To that end, a solid integration of related scientific disciplines, such as tectonics, petrology, geochemistry, geophysics, geomorphology, remote sensing, glaciology, is required. A proper understanding of the island's evolution in the past, and its present state, is essential for improving the efficiency in interpreting monitoring data recorded during volcanic unrest periods and, hence, for future eruption forecasting. In this chapter, we briefly present Deception Island's most relevant tectonic, geomorphological, volcanological and magmatic features, as well as the results obtained from decades of monitoring the island's seismic activity and ground deformation.