ABSTRACT The Appalachian Mountains were formed through multiple phases of Paleozoic orogenesis associated with terrane accretion. The timing, tempo, and significance of each event in New England are obscured by overprinting, the limits of geochronologic tools, and differences between lithotectonic domains. We present new monazite and xenotime geochronology, 40 Ar/ 39 Ar thermochronology, and major- and trace-element thermobarometry from major tectonic domains in southern New England and across multiple structural levels. These data show contrasting pressure-temperature-time ( P-T-t ) paths across tectonic domains and highlight eastward metamorphic overprinting associated with younger tectonic events. Our data and geochemical proxies suggest two major periods of crustal thickening, ca. 455–440 Ma and 400–380 Ma, and a heterogeneous record of thinning/exhumation. Ordovician (Taconic) crustal thickening postdates the interpreted accretion of the Moretown terrane by ~20 m.y. and may have been related to shallow subduction after subduction polarity reversal. Subsequent cooling and exhumation (440–430 Ma) may have been related to the end of the Taconic orogeny and opening of the Connecticut Valley basin. (Neo)Acadian tectono-metamorphism is recognized in accreted terranes of New England and is absent in the Taconic block. Amphibolite- to (high-pressure) granulite-facies metamorphism, slow cooling, and protracted anatexis ca. 400–340 Ma support the existence of a long-lived orogenic plateau in southern New England. Exhumation, which began at 340–330 Ma, may have involved ductile (channel) flow. The boundary between continental Laurentia and accreted terranes has been reactivated at multiple times and is presently manifested as a 12–15 km Moho step. At the latitude of our samples, Alleghanian-age tectonism (ca. 310–285 Ma) was limited to retrograde metamorphism, and relatively minor loading and exhumation in the vicinity of the Pelham dome. Our results highlight the sensitivity of the integrative petrochronologic approach and the transition of the eastern margin of Laurentia from terrane accretion to the formation of a high-elevation plateau.

ABSTRACT The Avalon terrane of southeastern New England is a composite terrane in which various crustal blocks may have different origins and/or tectonic histories. The northern part (west and north of Boston, Massachusetts) correlates well with Avalonian terranes in Newfoundland, Nova Scotia, and New Brunswick, Canada, based on rock types and ages, U-Pb detrital zircon signatures of metasedimentary rocks, and Sm-Nd isotope geochemistry data. In the south, fewer data exist, in part because of poorer rock exposure, and the origins and histories of the rocks are less well constrained. We conducted U-Pb laser ablation–inductively coupled plasma–mass spectrometry analysis on zircon from seven metasedimentary rock samples from multiple previously interpreted subterranes in order to constrain their origins. Two samples of Neoproterozoic Plainfield Formation quartzite from the previously interpreted Hope Valley subterrane in the southwestern part of the southeastern New England Avalon terrane and two from the Neoproterozoic Blackstone Group quartzite from the adjacent Esmond-Dedham subterrane to the east have Tonian youngest detrital zircon age populations. One sample of Cambrian North Attleboro Formation quartzite of the Esmond-Dedham subterrane yielded an Ediacaran youngest detrital zircon age population. Detrital zircon populations of all five samples include abundant Mesoproterozoic zircon and smaller Paleoproterozoic and Archean populations, and are similar to those of the northern part of the southeastern New England Avalon terrane and the Avalonian terranes in Canada. These are interpreted as having a Baltican/Amazonian affinity based primarily on published U-Pb and Lu-Hf detrital zircon data. Based on U-Pb detrital zircon data, there is no significant difference between the Hope Valley and Esmond-Dedham subterranes. Detrital zircon of two samples of the Price Neck and Newport Neck formations of the Neoproterozoic Newport Group in southern Rhode Island is characterized by large ca. 647–643 and ca. 745–733 Ma age populations and minor zircon up to ca. 3.1 Ga. This signature is most consistent with a northwest African affinity. The Newport Group may thus represent a subterrane, terrane, or other crustal block with a different origin and history than the southeastern New England Avalon terrane to the northwest. The boundary of this Newport Block may be restricted to the boundaries of the Newport Group, or it may extend as far north as Weymouth, Massachusetts, as far northwest as (but not including) the North Attleboro Formation quartzite and associated rocks in North Attleboro, Massachusetts, and as far west as Warwick, Rhode Island, where eastern exposures of the Blackstone Group quartzite exist. The Newport Block may have amalgamated with the Amazonian/Baltican part of the Avalon terrane prior to mid-Paleozoic amalgamation with Laurentia, or it may have arrived as a separate terrane after accretion of the Avalon terrane. Alternatively, it may have arrived during the formation of Pangea and been stranded after the breakup of Pangea, as has been proposed previously for rocks of the Georges Bank in offshore Massachusetts. If the latter is correct, then the boundary between the Newport Block and the southeastern New England Avalon terrane is the Pangean suture zone.

ABSTRACT The Paleozoic plate boundary zone between Laurussia and Gondwana in western Pangea hosts major magmatic and hydrothermal Sn-W-Ta, Au, and U mineralization. Individual mineral deposits represent the results of the superposition of a series of exogenic and endogenic processes. Exogenic processes controlled (1) the enrichment of the ore elements in sedimentary protoliths via residual enrichment during intense chemical weathering and via climatically or tectonically controlled redox traps, (2) the spatial distribution of fertile protoliths, and, thus, eventually (3) the spatial distribution of mineralization. Endogenic processes resulting in metamorphism and crustal melting controlled the mobilization of Sn-W, Au, and U from these enriched protoliths and, thus, account for the age distribution of Sn-W and Au mineralization and U-fertile granites. It is the sequence of exogenic and endogenic processes that eventually results in the formation of mineralization in particular tectonic zones. Whereas the endogenic processes were controlled by orogenic processes during the assembly of western Pangea itself, the exogenic processes were linked to the formation of suitable source rocks for later mineralization. The contrasting distribution of magmatic and hydrothermal Sn-W-Ta, Au, and U mineralization on the Laurussia and Gondwana sides of the plate boundary zone reflects the contrasting distribution of fertile protoliths and the contrasting tectonic situation on these margins. The Laurussian margin was an active margin during most of the Paleozoic, and the distribution of different mineralization types reflects the distribution of terranes of contrasting provenance. The Gondwanan margin was a passive margin during most of the Paleozoic, and the similar distribution of a wide range of different metals (Sn, W, Ta, Au, and U) reflects the fact that the protoliths for the various metals were diachronously accumulated on the same shelf, before the metals were mobilized during Acadian, Variscan, and Alleghanian orogenic processes.

ABSTRACT Avalonia and Ganderia are composite microcontinental fragments in the northern Appalachian orogen likely derived from Gondwanan sources. Avalonia includes numerous Neoproterozoic magmatic arc sequences that represent protracted and episodic subduction-related magmatism before deposition of an Ediacaran–Ordovician cover sequence of mainly siliciclastic rocks. We characterized the nature of the basement on which these arcs were constructed using zircon grains from arc-related magmatic rocks in Atlantic Canada that were analyzed for their Lu-Hf isotope composition. The majority of zircon grains from Avalonia are characterized by initial 176 Hf/ 177 Hf values that are more radiogenic than chondritic uniform reservoir, and calculated crust formation Hf T DM (i.e., depleted mantle) model ages range from 1.2 to 0.8 Ga. These data contrast with those from Ganderia, which show typically positive initial εHf values and Hf T DM model ages that imply magmatism was derived by melting of crustal sources with diverse ages ranging from ca. 1.8 to 1.0 Ga. The positive distribution of initial εHf values along with the pattern of Hf T DM model ages provide a clear record of two distinct subduction systems. Cryogenian–Ediacaran magmatism is interpreted to have resulted from reworking of an evolved Mesoproterozoic crustal component in a long-lived, subduction-dominated accretionary margin along the margin of northern Amazonia. A change in Hf isotope trajectory during the Ediacaran implies a greater contribution of isotopically evolved material consistent with an arc-arc–style collision of Ganderia with Avalonia. The shallow-sloping Hf isotopic pattern for Paleozoic Ganderian magmatism remains continuous for ~200 m.y., consistent with tectonic models of subduction in the Iapetus and Rheic Oceans and episodic accretion of juvenile crustal terranes to Laurentia.

ABSTRACT More than 100 air-fall volcanic tephra beds are currently documented from Devonian strata in the eastern United States. These beds act as key sources of various geological data. These include within-basin to basin-to-basin correlation, globally useful geochronologic age dates, and a relatively detailed, if incomplete, record of Acadian–Neoacadian silicic volcanism. The tephras occur irregularly through the vertical Devonian succession, in clusters of several beds, or scattered as a few to single beds. In this contribution, their vertical and lateral distribution and recent radiometric dates are reviewed. Current unresolved issues include correlation of the classic Eifelian-age (lower Middle Devonian) Tioga tephras and dates related to the age of the Onondaga-Marcellus contact in the Appalachian Basin. Here, we used two approaches to examine the paleovolcanic record of Acadian–Neoacadian silicic magmatism and volcanism. Reexamination of volcanic phenocryst distribution maps from the Tioga tephras indicates not one but four or more volcanic sources along the orogen, between southeastern Pennsylvania and northern North Carolina. Finally, radiometric and relative ages of the sedimentary basin tephras are compared and contrasted with current radiometric ages of igneous rocks from New England. Despite data gaps and biases in both records, their comparisons provide insights into Devonian silicic igneous activity in the eastern United States, and into various issues of recognition, deposition, and preservation of tephras in the sedimentary rock record.