ABSTRACT Early Ordovician to late Permian orogenies at different plate-boundary zones of western Pangea affected continental crust derived from the plates of North America (Laurentia), Europe (East European Craton including Baltica plus Arctida), and Gondwana. The diachronic orogenic processes comprised stages of intraoceanic subduction, formation and accretion of island arcs, and collision of several continents. Using established plate-tectonic models proposed for different regions and time spans, we provide for the first time a generic model that explains the tectonics of the entire Gondwana-Laurussia plate-boundary zone in a consistent way. We combined the plate kinematic model of the Pannotia-Pangea supercontinent cycle with geologic constraints from the different Paleozoic orogens. In terms of oceanic lithosphere, the Iapetus Ocean is subdivided into an older segment (I) and a younger (II) segment. Early Cambrian subduction of the Iapetus I and the Tornquist oceans at active plate boundaries of the East European Craton triggered the breakup of Pannotia, formation of Iapetus II, and the separation of Gondwana from Laurentia. Prolonged subduction of Iapetus I (ca. 530 –430 Ma) culminated in the Scandian collision of the Greenland-Scandinavian Caledonides of Laurussia. Due to plate-tectonic reorganization at ca. 500 Ma, seafloor spreading of Iapetus II ceased, and the Rheic Ocean opened. This complex opening scenario included the transformation of passive continental margins into active ones and culminated in the Ordovician Taconic and Famatinian accretionary orogenies at the peri-Laurentian margin and at the South American edge of Gondwana, respectively. Rifting along the Avalonian-Cadomian belt of peri-Gondwana resulted in the separation of West Avalonian arc terranes and the East Avalonian continent. The vast African/Arabian shelf was affected by intracontinental extension and remained on the passive peri-Gondwana margin of the Rheic Ocean. The final assembly of western Pangea was characterized by the prolonged and diachronous closure of the Rheic Ocean (ca. 400–270 Ma). Continental collision started within the Variscan-Acadian segment of the Gondwana-Laurussia plate-boundary zone. Subsequent zipper-style suturing affected the Gondwanan Mauritanides and the conjugate Laurentian margin from north to south. In the Appalachians, previously accreted island-arc terranes were affected by Alleghanian thrusting. The fold-and-thrust belts of southern Laurentia, i.e., the Ouachita-Marathon-Sonora orogenic system, evolved from the transformation of a vast continental shelf area into a collision zone. From a geodynamic point of view, an intrinsic feature of the model is that initial breakup of Pannotia, as well as the assembly of western Pangea, was facilitated by subduction and seafloor spreading at the leading and the trailing edges of the North American plate and Gondwana, respectively. Slab pull as the plate-driving force is sufficient to explain the entire Pannotia–western Pangea supercontinent cycle for the proposed scenario.

Abstract Mudrocks are highly heterogeneous in a range of physical and chemical properties, including: porosity and permeability, fissility, colour, particle composition, size, orientation, carbon loading, degree of compaction, and diagenetic overprint. It is therefore important that the maximum information be extracted as efficiently and completely as possible. This can be accomplished through high-resolution analysis of polished thin sections by scanning electron microscopy (SEM), with the collection of large-area images and X-ray elemental map montages, and the application of targeted particle analysis. A workflow model, based on these techniques, for the digitization of mudrocks is presented herein. A range of the data that can be collected and the variety of analyses that can be achieved are also illustrated. Data collection is discussed in terms of inherent problems with acquisition, storage, transfer and manipulation, which can be time-consuming and non-trivial. Similar information and resolutions can be achieved through other techniques, such as QEMSCAN and infra-red (IR)/Raman spectroscopic mapping. These can be seen as complementary to the workflow described herein.

Abstract Petroleum systems within rifted margin basins affected by volcanism continue to remain challenging for the exploration of hydrocarbons, most notably owing to the volume of intrusions that pose imaging, drilling and exploration problems. Typically, intrusions possess small thermal aureoles, but despite this, there is evidence that intrusions could none the less be responsible for the generation of commercial volumes of hydrocarbons. Here we shed new light on this petroleum systems challenge by integrating organic geochemical and Raman spectroscopic techniques to produce potential volumetric data for hydrocarbons generated as a result of igneous intrusion. The results indicate that, in areas with immature source rock intervals, it may be possible for intrusions to generate volumes of oil that would be capable of comfortably filling likely known oil reservoirs. This is a critical step forward in integrating several analytical techniques, indicating that under the right conditions there is the potential for hydrocarbon generation as a result of igneous intrusion.

Abstract The term quick clay has been used to denote the behaviour of highly sensitive Quaternary marine clays that, due to post depositional processes, have the tendency to change from a relatively stiff condition to a liquid mass when disturbed. On failure these marine clays can rapidly mobilise into high velocity flow slides and spreads often completely liquefying in the process. For a clay to be defined as potentially behaving as a quick clay in terms of its geotechnical parameters it must have a sensitivity (the ratio of undisturbed to remoulded shear strength) of greater than 30 together with a remoulded shear strength of less than 0.5 kPa. The presence of quick clays in the UK is unclear, but the Quaternary history of the British islands suggests that the precursor conditions for their formation could be present and should be considered when undertaking construction in the coastal zone.