Abstract We conducted a high-resolution multi-disciplinary analysis of two core sections in the borehole Ellesmere Port-1, Cheshire, UK. Biostratigraphic analysis indicates that the core sections are Kinderscoutian and late Arnsbergian–Chokierian in age, respectively. Both cores are assigned to the Bowland Shale Formation (Holywell Shale). Coupled core scan and discrete geochemical analysis enables interpretation of syngenetic processes at a high stratigraphic resolution. Both cores exhibit the classic cyclicity of limestones, calcareous to non-calcareous mudstones and siltstones, interpreted to represent sediment deposition during fourth-order sea-level fluctuation. Machine learning of the well log data coupled to the core scan data enabled prediction of the key lithofacies through the entire Bowland Shale interval in Ellesmere Port-1. The machine predictions show that the Bowland Shale is interfingered with three turbiditic leaves of the Cefn-y-Fedw Sandstone Formation and contains at least 12 complete fourth-order cycles. The Bowland Shale exhibits high radiogenic heat productivity in comparison with other sedimentary rocks, due primarily to relative U enrichment under intermittently euxinic conditions. Thermal modelling, however, shows that the radiogenic heat productivity of the Bowland Shale contributes a negligible source of additional heat at the scale of hundreds of metres.

Abstract This volume showcases recent geological, geophysical and geochemical research on the Carboniferous Bowland Shale Formation. The Bowland Shale is a relatively thick and extensive Palaeozoic black shale unit with a long history of debate and controversy in the UK. The Bowland Shale is proven in many of the key Carboniferous basins in the Midlands, northern England and North Wales, and represents a significant, near-continuous temporal record spanning 16 Myr including the important mid-Carboniferous boundary (Mississippian–Pennsylvanian). Since the first geological surveys in the late nineteenth century, the Bowland Shale has been of interest for a variety of reasons, including the search for Irish-type Pb–Zn base metal mineral deposits, and as a source rock in conventional hydrocarbon systems. In the mid-2000s, attention turned to the Bowland Shale as a target for unconventional hydrocarbon extraction, shale gas, following success in the USA. This placed the Bowland Shale at the centre of a series of interconnected controversies and debates from the local to national scale. The geological credibility of the purported shale gas resource in the UK was – and continues to be – highly contentious. This volume contributes to a more updated view of the Bowland Shale, covering topics such as sedimentary, geochemical and physical properties and processes, basin-forming events, hydrocarbon prospectivity, mineralization and heat and fluid flow in the subsurface. The volume also includes a field guide to some of the key localities in the UK. With the benefit of hindsight offered by the latest generation of research, the early regional shale gas assessments failed to attach sufficient weight to the compositional heterogeneity, structural complexity, compartmentalization and highly variable exhumation, erosion and palaeo-heat flow history of the Bowland Shale. The following topics are identified as promising avenues for future research beyond shale gas: (1) the role of the Bowland Shale in the context of mineral systems; (2) the role of the Bowland Shale as a cap rock in the Lower Carboniferous limestone geothermal play and potentially as an analogue of CO 2 or radioactive waste storage in the UK; and (3) pathways and mechanisms for weathering, alteration and trace element release from the Bowland Shale into the surface and/or subsurface environment.

Abstract The recent shale gas revolution originated in the USA in the late 1990s with the exploration of the Carboniferous Barnett Shale in Texas. Success in a number of additional basins in North America, such as the Marcellus, Eagle Ford and Bakken basins, stimulated a search for similar opportunities elsewhere around the world. Among the shales and basins targeted by industry was the Carboniferous Bowland Shale (and equivalents) in northern England. The initial premise that the Barnett Shale represented an excellent analogue for the Bowland Shale led to over-optimistic reserve estimates that have since been shown to be largely incorrect. On the basis of visual inspection of wellbore cores, the Carboniferous Barnett and Bowland shales appear to be very similar. Unfortunately, it is there that the similarity ends. Research carried out for the UK Unconventional Hydrocarbons project has highlighted important differences adversely impacting prospectivity. These can be summarized as basin type/continuity and structural complexity. The total organic carbon, maturity, mineralogy and thickness of the Bowland Shale and equivalents are broadly similar to the successful US examples. Our conclusion is that the Bowland Shale in the UK does not represent a technically significant resource, and in hindsight did not merit the considerable industry and media attention that has been associated with it. One key learning is that fundamental research based on heritage data and modern analytical and modelling techniques should have preceded drilling and fracking operations in northern England.

Abstract The regional character of organic matter types and depositional conditions of Pendleian, Brigantian and Arnsbergian mudstones between the Craven Basin and the Widmerpool Gulf was compared through interpretation of biomarker and pyrolysis data from 201 samples recovered from nine boreholes. The Carboniferous seaways have been determined to commonly host dysoxic conditions, enabling the preservation of a mixture of marine and terrestrial organic matter types. Photic zone anoxia, established by the presence of aryl isoprenoids, was determined to be persistent during ‘marine’ conditions represented by marine band, high-sea-level and carbonate facies. The observation and correlation of diasteranes and trisnorneohopane/trisnorhopane ratios within the samples and to other maturity parameters highlighted a significant clay mineral catalytic and/or hydrocarbon retention effect in the samples. This influenced both biomarkers and programmed pyrolysis thermal maturity indices such as T max , reducing the reliability of such results for interpreting the burial depth, and ultimately reserve potential.

Abstract Avalonia, defined by its distinctive uppermost Ediacaran–Ordovician overstep sequence, extends from New England through Atlantic Canada to Wales. It unconformably overlies: (1) parts of one cratonic Neoproterozoic arc that which records several pulses at: 760–730 Ma, 680–600 Ma and 580–540 Ma; (2) an 800–760 Ma passive margin sequence; and (3) c. 976 Ma isolated plutons, possibly basement. Comparisons with modern arc dimensions suggest the dip of the Benioff Zone ranged from c. 22° W in Newfoundland to c. 52–67° elsewhere. A 600–580 Ma hiatus in arc magmatism in Cape Breton Island is attributed to overriding an oceanic plateau, leading to a 15° decrease in the dip of the Benioff Zone. The Collector magnetic anomaly along the Grand Banks and the Minas Fault is inferred to mark the Neoproterozoic southern margin of the Avalon Plate consisting of leaky transform faults and trench segments characterized by magnetite serpentinite mantle wedge beneath forearcs. The Minas Fault/Collector Anomaly connects similar arc units in Cape Breton Island and southern New Brunswick, suggesting that they were already offset by the Minas transform fault in the late Neoproterozoic. Similar tectonic, palaeomagnetic and isotopic data in the Timan Orogen of Baltica suggest that Avalonia may correlate with the Kipchak arc.

Abstract Although the Rheic Ocean was the widest to be closed during the assembly of Pangaea, its suture zone is dominated by a younger (Rhenohercynian) Wilson Cycle. The present paper briefly summarizes the Rhenohercynian and reviews the relicts of the Rheic. The absence of a Rheic orogen is mainly due to bipolar subduction of the Rheic Ocean, which created two magmatic arcs and largely destroyed the passive margin prisms, thus depriving the collision zone of building material. Also, displacement of Variscan zones in England, France and Germany along a curvature of the dextral Bristol/Bray/Bohemia shear zone has effected their anticlockwise rotation. Younger, ENE-trending reverse faults have truncated the NE-trending structural boundaries and excised pre-Devonian, Rheic-related rocks west of the River Rhine, while the northern Rheic Arc and Cambrian–Silurian deposits of the Rheic Ocean have been preserved further east. Opening of the Rhenohercynian successor ocean to the Rheic put a brake on plate convergence and hindered formation of a large collisional belt. Scarce relicts of the southern Rheic Arc and rocks with Silurian deformation exist in the (largely eroded) upper plate of the Rhenohercynian collisional belt, mostly in the form of clasts and detrital zircons in Upper Devonian/lower Carboniferous flysch and in tectonic mélange at the base of the allochthon.