ABSTRACT The late early to middle Miocene period (18–12.7 Ma) was marked by profound environmental change, as Earth entered into the warmest climate phase of the Neogene (Miocene climate optimum) and then transitioned to a much colder mode with development of permanent ice sheets on Antarctica. Integration of high-resolution benthic foraminiferal isotope records in well-preserved sedimentary successions from the Pacific, Southern, and Indian Oceans provides a long-term perspective with which to assess relationships among climate change, ocean circulation, and carbon cycle dynamics during these successive climate reversals. Fundamentally different modes of ocean circulation and carbon cycling prevailed on an almost ice-free Earth during the Miocene climate optimum (ca. 16.9–14.7 Ma). Comparison of δ 13 C profiles revealed a marked decrease in ocean stratification and in the strength of the meridional overturning circulation during the Miocene climate optimum. We speculate that labile polar ice sheets, weaker Southern Hemisphere westerlies, higher sea level, and more acidic, oxygen-depleted oceans promoted shelf-basin partitioning of carbonate deposition and a weaker meridional overturning circulation, reducing the sequestration efficiency of the biological pump. X-ray fluorescence scanning data additionally revealed that 100 k.y. eccentricity-paced transient hyperthermal events coincided with intense episodes of deep-water acidification and deoxygenation. The in-phase coherence of δ 18 O and δ 13 C at the eccentricity band further suggests that orbitally paced processes such as remineralization of organic carbon from the deep-ocean dissolved organic carbon pool and/or weathering-induced carbon and nutrient fluxes from tropical monsoonal regions to the ocean contributed to the high amplitude variability of the marine carbon cycle. Stepwise global cooling and ice-sheet expansion during the middle Miocene climate transition (ca. 14.7–13.8 Ma) were associated with dampening of astronomically driven climate cycles and progressive steepening of the δ 13 C gradient between intermediate and deep waters, indicating intensification and vertical expansion of ocean meridional overturning circulation following the end of the Miocene climate optimum. Together, these results underline the crucial role of the marine carbon cycle and low-latitude processes in driving climate dynamics on an almost ice-free Earth.

Abstract Preserved rocks in the Jurassic Ferrar Large Igneous Province consist mainly of intrusions, and extrusive rocks, the topic of this chapter, comprise the remaining small component. They crop out in a limited number of areas in the Transantarctic Mountains and southeastern Australia. They consist of thick sequences of lavas and sporadic occurrences of volcaniclastic rocks. The latter occur mainly beneath the lavas and represent the initial eruptive activity, but also are present within the lava sequence. The majority are basaltic phreatomagmatic deposits and in at least two locations form immense phreatocauldrons filled with structureless tuff breccias and lapilli tuffs with thicknesses of as much as 400 m. Stratified sequences of tuff breccias, lapilli tuffs and tuffs are up to 200 m thick. Thin tuff beds are sparsely distributed in the lava sequences. Lava successions are mainly 400–500 m thick, and comprise individual lavas ranging from 1 to 230 m thick, although most are in the range of 10–100 m. Well-defined colonnade and entablature are seldom displayed. Lava sequences were confined topographically and locally ponded. Water played a prominent role in eruptive activity, as exhibited by phreatomagmatism, hyaloclastites, pillow lava and quenching of lavas. Vents for lavas have yet to be identified.