ABSTRACT The Mount Diablo region has been located within a hypothesized persistent corridor for clastic sediment delivery to the central California continental margin over the past ~100 m.y. In this paper, we present new detrital zircon U-Pb geochronology and integrate it with previously established geologic and sedimentologic relationships to document how Late Cretaceous through Cenozoic trends in sandstone composition varied through time in response to changing tectonic environments and paleogeography. Petrographic composition and detrital zircon age distributions of Great Valley forearc stratigraphy demonstrate a transition from axial drainage of the Klamath Mountains to a dominantly transverse Sierra Nevada plutonic source throughout Late Cretaceous–early Paleogene time. The abrupt presence of significant pre-Permian and Late Cretaceous–early Paleogene zircon age components suggests an addition of extraregional sediment derived from the Idaho batholith region and Challis volcanic field into the northern forearc basin by early–middle Eocene time as a result of continental extension and unroofing. New data from the Upper Cenozoic strata in the East Bay region show a punctuated voluminous influx (>30%) of middle Eocene–Miocene detrital zircon age populations that corresponds with westward migration and cessation of silicic ignimbrite eruptions in the Nevada caldera belt (ca. 43–40, 26–23 Ma). Delivery of extraregional sediment to central California diminished by early Miocene time as renewed erosion of the Sierra Nevada batholith and recycling of forearc strata were increasingly replaced by middle–late Miocene andesitic arc–derived sediment that was sourced from Ancestral Cascade volcanism (ca. 15–10 Ma) in the northern Sierra Nevada. Conversely, Cenozoic detrital zircon age distributions representative of the Mesozoic Sierra Nevada batholith and radiolarian chert and blueschist-facies lithics reflect sediment eroded from locally exhumed Mesozoic subduction complex and forearc basin strata. Intermingling of eastern- and western-derived provenance sources is consistent with uplift of the Coast Ranges and reversal of sediment transport associated with the late Miocene transpressive deformation along the Hayward and Calaveras faults. These provenance trends demonstrate a reorganization and expansion of the western continental drainage catchment in the California forearc during the late transition to flat-slab subduction of the Farallon plate, subsequent volcanism, and southwestward migration of the paleodrainage divide during slab roll-back, and ultimately the cessation of convergent margin tectonics and initiation of the continental transform margin in north-central California.

ABSTRACT Two construction aggregate companies, Cemex and Hanson Aggregates, operate respective crushed stone quarries on the east and west slopes of Mount Zion in Clayton, California. These sidehill quarries utilize a single highwall and mine Jurassic diabase of the Coast Range ophiolite that formed as a sheeted dike complex. Hydrothermal veins, some containing 20%–30% disseminated pyrite and chalcopyrite, cut the diabase. The east quarry, operated by Cemex, was started by the Harrison-Birdwell Company in 1947. The west quarry, operated by Hanson, was started by the Henry J. Kaiser Sand and Gravel Company in 1954. The Cemex quarry highwall is visible as you come into the city of Clayton on Marsh Creek Road, with a height of ~280 m (920 ft). The height of the highwall at the Hanson quarry is ~215 m (700 ft). Both operations remove weathered diabase overburden to expose fresh diabase, which is drilled, blasted, and hauled to the plant for processing. To ensure aggregate is suitable for construction, quality assurance testing is conducted in accordance with the specifications of various agencies. These quarries supply the surrounding area with aggregate for hospitals, schools, highways, dams, and other buildings. Noteworthy projects supplied by the Clayton quarries include the Concord BART Station, Interstate-680, Interstate-580, Calaveras Dam, Sherman Island Levee, Highway 4, Highway 24, and Bay Bridge epoxy asphalt. Before aggregate was mined, Mount Zion was the site of a copper rush from 1862 to 1864. Gold and silver were also reported in various assays from the Clayton district. Although prospecting created excitement around Clayton, no productive orebodies were ever discovered.

ABSTRACT Two spatially separated areas of Neogene volcanic rocks are located on the northeast limb of the Mount Diablo anticline. The southernmost outcrops of volcanics are 6 km east of the summit of Mount Diablo in the Marsh Creek area and consist of ~12 hypabyssal dacite intrusions dated at ca. 7.8–7.5 Ma, which were intruded into the Great Valley Group of Late Cretaceous age. The intrusions occur in the vicinity of the Clayton and Diablo faults. The rocks are predominantly calc-alkaline plagioclase biotite dacites, but one is a tholeiitic plagioclase andesite. Mercury mineralization was likely concomitant with emplacement of these late Miocene intrusions. The northernmost outcrops of Neogene volcanic rocks occur ~15 km to the north of Mount Diablo in the Concord Naval Weapons Station and the Los Medanos Hills and are probably parts of a single andesite flow. A magnetometer survey indicates that the flow originated from a feeder dike along the Clayton fault. The lava flow is flat-lying and occupies ancient stream channels across an erosional surface of tilted Markley Sandstone of middle Eocene age. New radiometric dates of the flow yield an age of 5.8–5.5 Ma, but due to alteration the age should be used with caution. The flow is a calc-alkaline andesite rich in clinopyroxene and plagioclase. What appear to be uplifted erosional remnants of the flow can be traced northeastward in the Los Medanos Hills across a surface of tilted Cenozoic rocks that eventually rest on formations as young as the Lawlor Tuff dated at 4.865 ± 0.011 Ma. This stratigraphic relationship suggests that the andesite flow is probably late Pliocene in age and was impacted by the more recent uplift of the Los Medanos Hills but postdates the regional folding and faulting of the rocks of Mount Diablo. In terms of timing, location, and composition, the evidence suggests these two areas of dacitic and andesitic volcanics fit into a series of migrating volcanic centers in the California Coast Ranges that erupted following the northward passage of the Mendocino Triple Junction.

ABSTRACT The basic stratigraphic and structural framework of Mount Diablo is described using a revised geologic map, gravity data, and aeromagnetic data. The mountain is made up of two distinct stratigraphic assemblages representing different depocenters that were juxtaposed by ~20 km of late Pliocene and Quaternary right-lateral offset on the Greenville-Diablo-Concord fault. Both assemblages are composed of Cretaceous and Cenozoic strata overlying a compound basement made up of the Franciscan and Great Valley complexes. The rocks are folded and faulted by late Neogene and Quaternary compressional structures related to both regional plate-boundary–normal compression and a restraining step in the strike-slip fault system. The core of the mountain is made up of uplifted basement rocks. Late Neogene and Quaternary deformation is overprinted on Paleogene extensional deformation that is evidenced at Mount Diablo by significant attenuation in the basement rocks and by an uptilted stepped graben structure on the northeast flank. Retrodeformation of the northeast flank suggests that late Early to early Late Cretaceous strata may have been deposited against and across a steeply west-dipping basement escarpment. The location of the mountain today was a depocenter through the Late Cretaceous and Paleogene and received shallow-marine deposits periodically into the late Miocene. Uplift of the mountain itself happened mostly in the Quaternary.

ABSTRACT Over the past 150 years, Mount Diablo has served as a window into the evolving understanding of California geology. In the 1800s, geologists mapped this easily accessible peak located less than 100 km (62 miles) from the rapidly growing city of San Francisco and the geology departments at the University of California at Berkeley and Stanford University. Later, the mountain served as a focal point for investigating San Francisco Bay area tectonics. The structural interpretation of the up-thrusting mechanisms has evolved from a simple compressional system involving a few local faults to a more complex multifault and multiphase mountain-building theory. The stratigraphic interpretation and understanding have been advanced from a general description of the lithologies and fossils to a detailed description using sequence stratigraphy to define paleogeographic settings and depositional regimes.

ABSTRACT Mount Diablo is flanked on its northeast side by a thick section of Late Cretaceous and Tertiary sedimentary rocks, which produced small hydrocarbon accumulations in the Los Medanos, Willow Pass, Mulligan Hill, and Concord gas fields. The first well was drilled in 1864, and today most of the active wells on the northeast flank are used for gas storage by Pacific Gas and Electric Company. These fields, which also include the Brentwood oil field, lie to the northeast of Mount Diablo and have produced 6.4 million cubic meters (225 billion cubic feet) of natural gas and over 57 million cubic meters (9.1 million barrels) of oil. The main reservoirs for the Sacramento Basin are sandstones in the Late Cretaceous and Paleogene section. The source rock there is primarily from the Upper Cretaceous Dobbins Shale, which began generation 75 m.y. ago, and the Winters Shale, which began generation 35 m.y. ago. The Livermore Basin is located on the western and southwestern sides of the mountain. The only commercial field in that basin is the small Livermore oil field. This field produces primarily from Miocene sandstones. The Livermore Basin is a Neogene basin that was syntectonically formed in the last few million years and continues to grow today. Studies of the black oils found in the Livermore field show that the source rock is likely the Eocene Nortonville Shale, though the Upper Cretaceous Moreno shale is also considered to be a possible source. The Livermore field has produced 12 million cubic meters of oil (1.9 million barrels).

ABSTRACT Franciscan subduction complex rocks of Mount Diablo form a 8.5 by 4.5 km tectonic window, elongated E-W and fault-bounded to the north and south by rocks of the Coast Range ophiolite and Great Valley Group, respectively, which lack the burial metamorphism and deformation displayed by the Franciscan complex. Most of the Franciscan complex consists of a stack of lawsonite-albite–facies pillow basalt overlain successively by chert and clastic sedimentary rocks, repeated by faults at hundreds of meters to <1 m spacing. Widely distributed mélange zones from 0.5 to 300 m thick containing high-grade (including amphibolite and eclogite) assemblages and other exotic blocks, up to 120 m size, form a small fraction of exposures. Nearly all clastic rocks have a foliation, parallel to faults that repeat the various lithologies, whereas chert and basalt lack foliation. Lawsonite grew parallel to foliation and as later grains across foliation. The Franciscan-bounding faults, collectively called the Coast Range fault, strike ENE to WNW and dip northward at low to moderate average angles and collectively form a south-vergent overturned anticline. Splays of the Coast Range fault also cut into the Franciscan strata and Coast Range ophiolite and locally form the Coast Range ophiolite–Great Valley Group boundary. Dip discordance between the Coast Range fault and overlying Great Valley Group strata indicates that the northern and southern Coast Range fault segments were normal faults with opposite dip directions, forming a structural dome. These relationships suggest accretion and fault stacking of the Franciscan complex, followed by exhumation along the Coast Range fault and then folding of the Coast Range fault.

ABSTRACT Late Cenozoic growth of the Mount Diablo anticline in the eastern San Francisco Bay area, California, USA, has produced unique 3D exposures of stratigraphic relationships and normal faults that record Late Cretaceous uplift and early Tertiary extension in the ancestral California forearc basin. Several early Tertiary normal faults on the northeast flank of Mount Diablo have been correlated with structures that accommodated Paleogene subsidence of the now-buried Rio Vista basin north of Mount Diablo. Stepwise restoration of deformation at Mount Diablo reveals that the normal faults probably root into the “Mount Diablo fault,” a structure that juxtaposes blueschist-facies rocks of the Franciscan accretionary complex with attenuated remnants of the ophiolitic forearc basement and relatively unmetamorphosed marine forearc sediments. This structure is the local equivalent of the Coast Range fault, which is the regional contact between high-pressure Franciscan rocks and structurally overlying forearc basement in the northern Coast Ranges and Diablo Range, and it is folded about the axis of the Mount Diablo anticline. Apatite fission-track analyses indicate that the Franciscan rocks at Mount Diablo were exhumed and cooled from depths of 20+ km in the subduction zone between ca. 70−50 Ma. Angular unconformities and growth relations in the Cretaceous and Paleogene stratigraphic sections on the northeast side of Mount Diablo, and in the Rio Vista basin to the north, indicate that wholesale uplift, eastward tilting, and extension of the western forearc basin were coeval with blueschist exhumation. Previous workers have interpreted the structural relief associated with this uplift and tilting, as well as the appearance of Franciscan blueschist detritus in Late Cretaceous and early Tertiary forearc strata, as evidence for an “ancestral Mount Diablo high,” an emergent Franciscan highland bordering the forearc basin to the west. This outer-arc high is here interpreted to be the uplifted footwall of Coast Range fault. The stratigraphic and structural relations exposed at Mount Diablo support models for exposure of Franciscan blueschists primarily through syn-subduction extension and attenuation of the overlying forearc crust in the hanging wall of the Coast Range fault, accompanied by (local?) uplift and erosion of the exhumed accretionary prism in the footwall.

ABSTRACT The California Coast Ranges mercury deposits are part of the western North America mercury belt, in which mercury occurs most commonly as red cinnabar (α-HgS), sometimes associated with its high-temperature polymorph, metacinnabar (β-HgS). In the Coast Ranges, ores were deposited from hydrothermal solutions and range in age from Miocene to Holocene. Ore deposition at Mount Diablo generally occurred along active faults and associated extension fractures in the Franciscan complex, most often in serpentinite that had been hydrothermally altered to silica-carbonate rock. The Mount Diablo mine lies ~48 km (~30 miles) northeast of San Francisco in Contra Costa County and is mineralogically unique in California, because metacinnabar, the higher-temperature polymorph of mercury sulfide, is a major primary ore mineral in the deposit, while at all other mercury mines in California, it is quite rare. In addition, hydrothermal activity is so recent that sulfurous gases and methane continued to be released into the mine at least into the 1940s. Historically, long before active large-scale mining began in the 1800s, the Mount Diablo mercury deposits were known to the Indigenous people of the Ohlone tribes, who used the cinnabar in rituals as well as for red pigment to decorate their bodies, and as a prized trade item. The deposit was later rediscovered in 1863 and mined intermittently until 1958. The Mount Diablo mine and adjacent Rhyne (also variously spelled Ryne or Rhine) mine were the sites of most of the mercury operations in the region, and at both mines, mercury ore occurs in structurally controlled lenticular bodies of silica-carbonate rock and serpentinite. The total district production probably exceeded 12,300 flasks (at 76 pounds or ~34.5 kg per flask) at an estimated grade of 2711 g per metric ton. Low-grade ore reserves are believed to still exist, with 17,000 short tons of indicated and inferred ore. Other minor deposits of copper, silver, and gold occur on Mount Diablo, principally in and around Eagle Peak, but mercury is not associated with these deposits. The most serious environmental problem associated with the mercury mines is the transport of mercury via mine drainage from the Mount Diablo mines to Dunn Creek, a tributary to Marsh Creek, which ultimately drains into Suisun and San Francisco Bay. The concern is that elemental mercury (Hg 0 ) and the mercury ion Hg(II) can be biologically converted to toxic monomethylmercury (MeHg). To combat this problem, a long-term process of mine remediation has been undertaken.

ABSTRACT Mount Diablo State Park exemplifies many other conservation areas where managers balance the dual missions of protecting natural resources while providing public access. Roads and trails that crisscross the park are etched into the geomorphic surface, capturing and redirecting storm runoff, and presenting both a challenge for soil conservation and a consequence of construction and maintenance. We used field mapping, remote sensing, and modeling to assess erosion along the roads and trails in Mount Diablo State Park, which encompasses the headwaters of several urbanized watersheds. The field mapping in 2011 determined that 56% of the assessed roads and trails required either repair or reconstruction to control erosion and that ~67% of the culverts in the park required either repair or replacement. Aerial photography and modeling showed that other erosion (unrelated to roads or trails) preferentially occurred during wet periods, in specific lithologies, and on convergent slopes. Although lithology and climate drive slope-forming geomorphic processes, we found that the road and trail system (1) expanded the stream network with a capillary-like system of rills, (2) catalyzed prolonged erosion, and (3) altered the timing and pattern of sediment yield. In addition to water-driven erosion during wet periods, road and trail surfaces were subject to mechanical and wind erosion during dry periods. Spatially, dry erosion and runoff both conformed with and crossed topographic gradients by following the road and trail network. Road- and trail-induced erosion occurred across a wider range of rock properties and slope geometries than is typical for other erosion. Hence, the roads and trails have expanded the spatial and temporal boundary conditions over which geomorphic processes operate and, due to continual soil disturbance, have accelerated erosion rates. Although road density is a commonly used metric to rank road-related impacts at watershed scales, it misses both spatial variability and the opportunity to identify specific road and trail segments for remediation. We developed a spatially explicit scoring scheme based on actual erosion and the potential for sedimentation of discrete waterbodies. The data were incorporated into the park’s road and trail management plan in 2016.

ABSTRACT Paleogene marine strata in the eastern San Francisco Bay area are exposed in discontinuous outcrops in the various tectonic blocks. Although there are many missing intervals, the strata were previously thought to span most of the Paleocene and Eocene. Revision of biochronology and calibration to the international time scale as well as to the global oxygen isotope curve and sea-level curves indicate that the strata are latest Paleocene through middle Eocene in age and contain faunal changes that are linked to the overall global climate trends and hyperthermals of that time. The Paleocene-Eocene thermal maximum, third Eocene thermal maximum, early Eocene climatic optimum, and middle Eocene climatic optimum are all identified in the eastern San Francisco Bay marine strata. The dominance of smoothly finished, dissolution-resistant agglutinated benthic foraminiferal species corresponds with a rapid shoaling and rapid deepening (overcorrection) of the calcium compensation depth associated with the Paleocene-Eocene thermal maximum. The benthic foraminiferal extinction event was a dramatic turnover of benthic foraminiferal species that occurred shortly after the onset of the Paleocene-Eocene thermal maximum. Opportunistic species such as Bulimina , which indicate environmental stress and lower oxygen conditions, are commonly associated with the Paleocene-Eocene thermal maximum. Environmental changes similar to those observed during the Paleocene-Eocene thermal maximum also characterize the third Eocene thermal maximum, based on the agglutinated and opportunistic species. The early Eocene climatic optimum is noted by the presence of foraminiferal assemblages that indicate a stable, warmer water mass, abundant food, and an influx of terrigenous material. The onset and end of the middle Eocene climatic optimum are recognized by the dominance of siliceous microfossils. This research updates the age and environmental interpretations of the Paleogene formations occurring in the vicinity of Mount Diablo, eastern San Francisco Bay area. The revised interpretations, which are based on foraminifers and calcareous nannoplankton, make it possible to identify various global climatic and biotic events.

ABSTRACT The mid-Cenozoic succession in the northeast limb of the Mount Diablo anticline records the evolution of plate interactions at the leading edge of the North America plate. Subduction of the Kula plate and later Farallon plate beneath the North America plate created a marine forearc basin that existed from late Mesozoic to mid-Cenozoic times. In the early Cenozoic, extension on north-south faults formed a graben depocenter on the west side of the basin. Deposition of the Markley Formation of middle to late? Eocene age took place in the late stages of the marine forearc basin. In the Oligocene, the marine forearc basin changed to a primarily nonmarine basin, and the depocenter of the basin shifted eastward of the Midland fault to a south-central location for the remainder of the Cenozoic. The causes of these changes may have included slowing in the rate of subduction, resulting in slowing subsidence, and they might also have been related to the initiation of transform motion far to the south. Two unconformities in the mid-Cenozoic succession record the changing events on the plate boundary. The first hiatus is between the Markley Formation and the overlying Kirker Formation of Oligocene age. The succession above the unconformity records the widespread appearance of nonmarine rocks and the first abundant appearance of silicic volcanic detritus due to slab rollback, which reversed the northeastward migration of the volcanic arc to a more proximal location. A second regional unconformity separates the Kirker/Valley Springs formations from the overlying Cierbo/Mehrten formations of late Miocene age. This late Miocene unconformity may reflect readjustment of stresses in the North America plate that occurred when subduction was replaced by transform motion at the plate boundary. The Cierbo and Neroly formations above the unconformity contain abundant andesitic detritus due to proto-Cascade volcanism. In the late Cenozoic, the northward-migrating triple junction produced volcanic eruptive centers in the Coast Ranges. Tephra from these local sources produced time markers in the late Cenozoic succession.

ABSTRACT We present a tephrochronologic/chronostratigraphic database for the Mount Diablo area and greater San Francisco Bay region that provides a spatial and temporal framework for geologic studies in the region, including stratigraphy, paleogeography, tectonics, quantification of earth surface processes, recurrence of natural hazards, and climate change. We identified and correlated 34 tephra layers within this region using the chemical composition of their volcanic glasses, stratigraphic sequence, and isotopic and other dating techniques. Tephra layers range in age from ca. 65 ka to ca. 29 Ma, as determined by direct radiometric techniques or by correlation to sites where they have been dated. The tephra layers are of Quaternary or Neogene age except for two that are of Oligocene age. We correlated the tephra layers among numerous sites throughout northern California. Source areas of the tephra layers are the Snake River–Yellowstone hotspot trend of northern Nevada, southern Idaho, and western Wyoming; the Nevadaplano caldera complex of central Nevada; the Jemez Mountains–Valles Caldera in northwestern New Mexico; the Southern Nevada volcanic field and related source areas in eastern California and west-central Nevada; the Quien Sabe–Sonoma volcanic centers of the California Coast Ranges; and the young Cascade Range volcanic centers of northeastern California and Oregon.

Mount Diablo and the geology of the Central California Coast Ranges are the subject of a volume celebrating the Northern California Geological Society’s 75th anniversary. The breadth of research illustrates the complex Mesozoic to Cenozoic tectonic evolution of the plate boundary. Recent faulting and folding along the eastern edge of the San Andreas system have exposed in the mountain a core of Franciscan accretionary wedge complex faulted against Cretaceous and Cenozoic forearc strata. The Memoir includes papers on structure, stratigraphy, tephrochronology, zircon provenance studies, apatite fission track analyses, and foraminifera and calcareous plankton assemblages tied to Cenozoic climate events. Chapters also address the history of geologic work in the area and the resource development of oil and gas, mercury, coal, and sand, and road aggregate.