ABSTRACT Supermature siliciclastic sequences were deposited between 1.64 Ga and 1.59 Ga over a broad swath of southern Laurentia in the Archean, Penokean, Yavapai, and Mazatzal Provinces. These siliciclastic sequences are notable for their extreme mineralogical and chemical maturity, being devoid of detrital feldspar and ferromagnesian minerals, containing the clay mineral kaolinite (or its metamorphic equivalent, pyrophyllite), and having a chemical index of alteration >95. Such maturity is the result of a perfect confluence of tectonic and climatic conditions, including a stable continental crust with low topographic relief (the Archean, Penokean, and Yavapai Provinces ca. 1.70 Ga), a warm humid climate, an elevated level of atmospheric CO 2 , and relatively acidic pore fluids in the critical zone. The weathered detritus was transported and deposited by southward-flowing streams across the Archean, Penokean, and Yavapai Provinces, ultimately to be deposited on 1.66 Ga volcanic and volcaniclastic rocks in the Mazatzal continental arc along the southern margin of Laurentia.