ABSTRACT Two models have been proposed to explain continental crust generation in accretionary orogens. One model suggests that accretionary orogens are formed by the successive collision of juvenile arcs. The second model invokes tectonic switching, which is the repeated cycles of slab rollback and extensional backarc basin formation followed by basin collapse caused by collision, shallow subduction, and/or increased convergence rate. The northern Colorado Front Range, specifically in and around the Big Thompson, Rist, and Poudre Canyons, offers excellent exposures of Paleoproterozoic rocks to test which accretionary model best explains crust generation for a portion of the Yavapai Province. In this contribution we have two goals: The first is to provide a field-trip guide that augments Mahan et al.’s (2013) field guide, which uses many stops that have become inaccessible or have changed because of catastrophic flooding that occurred in September 2013. This more current guide focuses on a variety of mostly Paleoproterozoic rocks within what some call the Poudre Basin. These rocks include clastic metasedimentary rocks, amphibolite, the Big Thompson Canyon tonalite suite, the northern Front Range granodiorite, granitic pegmatites, and Mesoproterozoic Silver Plume granite. The second goal is to present and synthesize new and existing geochemistry, geochronology, and isotopic data, and then discuss the origins, age, deformation, and metamorphism of these rocks in the context of the proposed tectonic models. These data were synthesized into the following tectonic model for the Poudre Basin. At ca. 1780 Ma, the juvenile Green Mountain arc, located today along the Colorado-Wyoming border, formed and extended shortly thereafter during slab rollback, resulting in the extensional backarc Poudre basin between the diverging arc fragments. Sedimentation within the basin began at inception and continued to ca. 1735 Ma when basin rocks were intruded by the Big Thompson Canyon tonalite suite and the northern Front Range granodiorite, all of which were subsequently metamorphosed and deformed at ca. 1725 Ma. Felsic magmatism and deformation within the basin were perhaps driven by the northward shallow subduction of an oceanic plateau or seamount. This suggests that following accretion of the Green Mountain Arc, tectonic switching explains formation and collapse of the Poudre Basin and creation of some of northern Colorado’s crust.

Abstract The genetic analysis of fold and thrust belts is facilitated by tracking the evolution of their organic endowment (petroleum tectonics). Petroleum tectonic analysis of convergent orogenic systems provides an audit of the processes that control the deformation and kinematics of orogenic belts. The distribution and deformation paths of the organic endowment intervals are key factors in determining the petroleum system evolution of fold and thrust belts. This comparison of orogenic systems illustrates the importance of flexural v. dynamic processes, orogenic wedge taper, mechanical stratigraphy and inherited architecture on the creation, preservation and destruction of petroleum accumulations. The Zagros, Pyrenees, Sevier and Beni Sub-Andean convergent systems share key characteristics of fold and thrust belts, with major differences in scale, degree of incorporation of organic endowment in evolution of the fold and thrust belt and its foreland, and preservation of fold and thrust belt wedge-top deposits. The Zagros is an orogen dominated by flexural processes that is a perfect storm for hydrocarbon generation and preservation. Its multiple stacked sources ensure continuous hydrocarbon generation while stacked detachments foster a low taper and thick wedge-top basins. The Pyrenees is also a flexurally dominated orogen, but the early consumption of its source rocks led to minimal survival of hydrocarbon accumulations during exhumation in a long lasting, high-taper orogenic wedge. The Sevier was initially a flexural orogen that was later dominated by dynamic uplift of the fold and thrust belt and distal foreland subsidence with foreland deformation. The consumption of its pre-orogenic sources during the early low-taper phase indicates a probable robust petroleum system at that time. However, the late high-taper phase exhumed and destroyed much of the early petroleum system. The addition of syntectonic foreland sources to be matured by both local and dynamic subsidence created an additional later set of petroleum systems. Post-orogenic events have left only remnants of world-class petroleum systems. The Beni segment of the Sub-Andean Orogen is a flexural system with probable dynamic overprints. Its most robust petroleum system probably occurred during its early low-taper flexural phase, with dynamic subsidence enhancement. Its late high-taper phase with possible dynamic uplift shuts down and stresses the petroleum systems. Comparison of these orogenic systems illustrates the importance of flexural v. dynamic processes, orogenic wedge taper kinematics, mechanical stratigraphy, distribution of source rocks relative to shortening and inherited architecture on the creation, preservation and destruction of petroleum accumulations in fold and thrust belts.

Abstract The eastern central Front Range of the Rocky Mountains in Colorado has long been a region of geologic interest because of Laramide-age hydrothermal polymetallic vein-related ores. The region is characterized by a well-exposed array of geologic structures associated with ductile and brittle deformation, which record crustal strain over 1.7 billion years of continental growth and evolution. The mineralized areas lie along a broad linear zone termed the Colorado Mineral Belt. This lineament has commonly been interpreted as following a fundamental boundary, such as a suture zone, in the North American Proterozoic crust that acted as a persistent zone of weakness localizing the emplacement of magmas and associated hydrothermal fluid flow. However, the details on the controls of the location, orientation, kinematics, density, permeability, and relative strength of various geological structures and their specific relationships to mineral deposit formation are not related to Proterozoic ancestry in a simple manner. The objectives of this field trip are to show key localities typical of the various types of structures present, show recently compiled and new data, offer alternative conceptual models, and foster dialogue. Topics to be discussed include: (1) structural history of the eastern Front Range; (2) characteristics, kinematics, orientations, and age of ductile and brittle structures and how they may or may not relate to one another and mineral deposit permeability; and (3) characteristics, localization, and evolution of the metal and non-metal-bearing hydrothermal systems in the eastern Colorado Mineral Belt.

Abstract Infiltration of surface water through mine waste can be an important or even dominant source of contaminants in a watershed. The Waldorf mine site in Clear Creek County, Colorado, is typical of tens of thousands of small mines and prospects on public lands throughout the United States. In this study, electromagnetic (EM) conductivity and direct current (dc) resistivity surveys were conducted in tandem with a NaCl tracer study to delineate ground-water flow paths through a mine-waste dump and adjacent wetland area. The tracer was used to tag adit water infiltrating from braided channels flowing over the top of the dump to seeps at the base of the dump. Infiltration from the braided channels had a maximum flow rate of 92 m/day and a hydraulic conductivity of 1.6 × 10 4 cm 3 /s. After rerouting of adit flow around the waste dump, discharge at some of the largest seeps was reduced, although not all seepage was eliminated entirely. Integrating results of the tracer study with those of the EM and dc geophysical surveys revealed two main flow paths of ground water, one beneath the dump and one through the dump. The main source of water to the first flow path is deeper ground water emerging from the fault zone beneath the collapsed adit. This flow path travels beneath the waste dump and appears to have been unaffected by rerouting of the adit discharge around the waste dump. The source of the second flow path is infiltration of adit water from braided channels flowing over the top of the dump, which is intermediate in depth and flows through the center of the waste dump. Following rerouting of adit flow, discharge to seeps at the toe of the dump along this flow path was reduced by as much as two-thirds, although not eliminated entirely. Improved understanding of ground-water flow paths through this abandoned mine site is important in developing effective remediation strategies to target sources of metals emanating from the adit, waste dump, and contaminated wetland area. Any use of trade, firm, or product names is for descriptive purposes only and does not imply endorsement by the U.S. government.

Abstract Base flow water in Leavenworth Creek, a tributary to South Clear Creek in Clear Creek County, Colorado, contains copper and zinc at levels toxic to aquatic life. The metals are predominantly derived from the historical Waldorf mine, and sources include an adit, a mine-waste dump, and mill-tailings deposits. Tracer-injection and water-chemistry synoptic studies were conducted during low-flow conditions to quantify metal loads of mining-impacted inflows and their relative contributions to nearby Leavenworth Creek. During the 2-year investigation, the adit was rerouted in an attempt to reduce metal loading to the stream. During the first year, a lithium-bromide tracer was injected continuously into the stream to achieve steady-state conditions prior to synoptic sampling. Synoptic samples were collected from Leavenworth Creek and from discrete surface inflows. One year later, synoptic sampling was repeated at selected sites to evaluate whether rerouting of the adit flow had improved water quality. The largest sources of copper and zinc to the creek were from surface inflows from the adit, diffuse inflows from wetland areas, and leaching of dispersed mill tailings. Major instream processes included mixing between mining- and non-mining-impacted waters and the attenuation of iron, aluminum, manganese, and othermetals by precipitation or sorption. One year after the rerouting, the Zn and Cu loads in Leavenworth Creek from the adit discharge versus those from leaching of a large volume of dispersed mill tailings were approximately equal to, if not greater than, those before. The mine-waste dump does not appear to be a major source of metal loading. Any improvement that may have resulted from the elimination of adit flow across the dump was masked by higher adit discharge attributed to a larger snow pack. Although many mine remediation activities commonly proceed without prior scientific studies to identify the sources and pathways of metal transport, such strategies do not always translate to water-quality improvements in the stream. Assessment of sources and pathways to gain better understanding of the system is a necessary investment in the outcome of any successful remediation strategy.

An interdisciplinary group of faculty from the University of Colorado and from Colorado State University is studying molybdenum in the environment. Molybdenum plays an essential role in the nitrogen cycle of plants and may cause disturbance of copper metabolism in animals. The world's largest molybdenum-producing mine is at Climax, Colorado. Rivers in Colorado exhibit some of the highest reported concentrations of molybdenum in the United States. Colorado offers a model system for the study of the release and effect of molybdenum. The geochemistry of molybdenum is complex. The principal dissolved form of the metal in natural waters is an anion, MoO 4 − − . At values of pH below about 6, the bimolybdate ion, HMoO 4 − , becomes dominant. The bimolybdate ion is relatively immobile in natural systems at low pH, probably because of adsorption or coprecipitation on metal hydroxides. In the acid soils of the alpine environment of Colorado, molybdenum forms a well-defined halo of elevated concentrations around a mineralized, undisturbed zone in the bedrock. We have attempted to define a natural datum or background level of molybdenum in the vicinity of the undisturbed mineralized zone and to compare the concentrations of molybdenum in the undisturbed area to those present in the vicinity of mines and mills in the same mountainous area. Such a comparison is extremely difficult and tenuous because of differences in drainage and glaciation between the two areas.