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NARROW
GeoRef Subject
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all geography including DSDP/ODP Sites and Legs
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Africa
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Southern Africa
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Barberton greenstone belt (1)
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Kaapvaal Craton (5)
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Namibia (1)
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South Africa
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Asia
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Oman (1)
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Australasia
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Australia
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Canada
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Eastern Canada
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Newfoundland and Labrador
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Quebec
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Nunavut
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Caribbean region
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North America
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Glacier National Park (1)
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United States
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Montana (3)
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Utah
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Wyoming (1)
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commodities
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elements, isotopes
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isotope ratios (6)
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metals
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sulfur
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fossils
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Invertebrata
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Plantae
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geochronology methods
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Paleozoic
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sulfides
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pyrite (3)
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Primary terms
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absolute age (4)
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Africa
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Southern Africa
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Barberton greenstone belt (1)
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Kaapvaal Craton (5)
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Namibia (1)
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South Africa
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Transvaal region (1)
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Asia
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Arabian Peninsula
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Oman (1)
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atmosphere (2)
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Australasia
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Australia
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Western Australia
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Pilbara Craton (4)
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Yilgarn Craton (1)
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bitumens (1)
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Canada
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Eastern Canada
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Baffin Island (1)
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Newfoundland and Labrador
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Newfoundland (1)
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Quebec
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Anticosti Island (1)
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Nunavut
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Baffin Island (1)
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Western Canada
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Northwest Territories (1)
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carbon
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C-13/C-12 (4)
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organic carbon (2)
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Caribbean region
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Cenozoic
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Invertebrata
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isotopes
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stable isotopes
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C-13/C-12 (4)
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O-18/O-16 (1)
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S-34/S-32 (1)
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Si-30/Si-28 (1)
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Mesozoic
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Cretaceous
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Upper Cretaceous
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Castlegate Sandstone (1)
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Mesaverde Group (1)
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metal ores
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base metals (1)
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iron ores (1)
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polymetallic ores (1)
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metals
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alkaline earth metals
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calcium (1)
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iron (1)
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mineral deposits, genesis (1)
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North America
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Basin and Range Province (1)
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Belt Basin (1)
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Glacier National Park (1)
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oxygen
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O-18/O-16 (1)
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paleobotany (1)
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paleoecology (2)
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Paleozoic
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Cambrian
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Lower Cambrian (1)
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Carboniferous
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Lower Carboniferous (1)
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Lower Mississippian
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Tournaisian (1)
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Devonian
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Upper Devonian
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Frasnian (1)
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Jefferson Group (1)
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Ellis Bay Formation (1)
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Ordovician
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Lower Ordovician
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Saint George Group (1)
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Pogonip Group (1)
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Upper Ordovician
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Ashgillian (1)
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Hirnantian (1)
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palynomorphs
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Chitinozoa (1)
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paragenesis (1)
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phosphorus (1)
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Plantae
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algae
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Rhodophyta (1)
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Precambrian
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Archean
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Kromberg Formation (1)
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Neoarchean (2)
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Paleoarchean (1)
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Warrawoona Group (1)
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Brockman Iron Formation (1)
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Hamersley Group (1)
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Johnnie Formation (1)
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Onverwacht Group (1)
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Transvaal Supergroup (3)
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upper Precambrian
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Proterozoic
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Great Oxidation Event (2)
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Belt Supergroup (2)
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Newland Limestone (1)
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Neoproterozoic
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Ediacaran (3)
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Paleoproterozoic (6)
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sea water (1)
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sedimentary rocks
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chemically precipitated rocks
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clastic rocks
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soils
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United States
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dolostone (1)
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chemically precipitated rocks
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chert (5)
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clastic rocks
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black shale (1)
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claystone (1)
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sedimentary structures
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burrows (1)
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bedding plane irregularities
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ripple marks (1)
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biogenic structures
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microbial mats
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planar bedding structures
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bedding (1)
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sediments
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oolite (1)
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sediments
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carbonate sediments (2)
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clastic sediments
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mud (1)
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siliciclastics (1)
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soils
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soils
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laterites (1)
-
-
Depositional history of Devonian to lower Carboniferous (Tournaisian) strata, northern Wyoming and southern Montana, USA
Did nutrient-rich oceans fuel Earth’s oxygenation?
High Carbonate Alkalinity Lakes on Mars and their Potential Role in an Origin of Life Beyond Earth
Apatite nanoparticles in 3.46–2.46 Ga iron formations: Evidence for phosphorus-rich hydrothermal plumes on early Earth
U-Pb dating of overpressure veins in late Archean shales reveals six episodes of Paleoproterozoic deformation and fluid flow in the Pilbara craton
A 1.25 Ga depositional age for the “Paleoproterozoic” Mapedi red beds, Kalahari manganese field, South Africa: New constraints on the timing of oxidative weathering and hematite mineralization
Evidence from laminated chert in banded iron formations for deposition by gravitational settling of iron-silicate muds
Active Ooid Growth Driven By Sediment Transport in a High-Energy Shoal, Little Ambergris Cay, Turks and Caicos Islands
Erosional surfaces in the Upper Cretaceous Castlegate Sandstone (Utah, USA): Sequence boundaries or autogenic scour from backwater hydrodynamics?
Precise age of Bangiomorpha pubescens dates the origin of eukaryotic photosynthesis
Pyrite-walled tube structures in a Mesoproterozoic sediment-hosted metal sulfide deposit
The redox state of the mid-Proterozoic oceans, lakes, and atmospheres is still debated, but it is vital for understanding the emergence and rise of macroscopic organisms and eukaryotes. The Appekunny Formation, Belt Supergroup, Montana, contains some of these early macrofossils dated between 1.47 Ga and 1.40 Ga and provides a well-preserved record of paleoenvironmental conditions. We analyzed the iron chemistry and mineralogy in samples from Glacier National Park, Montana, by pairing bulk rock magnetic techniques with textural techniques, including light microscopy, scanning electron microscopy, and synchrotron-based X-ray absorption spectroscopy. Field observations of the Appekunny Formation combined with mineralogical information allowed revised correlations of stratigraphic members across the park. However, late diagenetic and/or metasomatic fluids affected primary iron phases, as evidenced by prevalent postdepositional phases including base-metal sulfides. On the west side of the park, pyrrhotite and chlorite rims formed during burial metamorphism in at least two recrystallization events. These complex postdepositional transformations could affect bulk proxies for paleoredox. By pairing bulk and textural techniques, we show primary records of redox chemistry were preserved in early diagenetic and often recrystallized framboidal pyrite, submicron magnetite grains interpreted to be detrital in origin, and red-bed laminae interpreted to record primary detrital oxides. Based on these observations, we hypothesize that the shallow waters of the mid-Proterozoic Belt Basin were similar to those in modern marine and lacustrine waters: fully oxygenated, with detrital reactive iron fluxes that mineralized pyrite during organic diagenesis in suboxic, anoxic, and sulfidic conditions in sedimentary pore waters.