Abstract: The lacustrine carbonate reservoirs of the South Atlantic host significant accumulations of chemically reactive and Al-free Mg-silicate minerals (e.g. stevensite, kerolite and talc). Petrographic data from units such as the Cretaceous Barra Velha Formation in the Santos Basin suggest that Mg-silicate minerals strongly influenced, and perhaps created, much of the observed secondary porosity. The diagenetic interactions between reactive Mg-silicate minerals and carbonate sediments are, however, poorly known. Here we develop a conceptual model for the origin of secondary porosity in the Barra Velha Formation guided by considerations of the chemistry that triggers Mg-silicate crystallization, as well as the geochemical and mineralogical factors that act as prerequisites for rapid Mg-silicate dissolution during early and late diagenesis. We conclude that sub-littoral zones of volcanically influenced rift lakes would have acted as the locus for widespread Mg-silicate accumulation and preservation. Organic-rich profundal sediments, however, would be especially prone to Mg-silicate dissolution and secondary porosity development. Here, organic matter diagenesis (especially methanogenesis) plays a major role in modifying the dissolved inorganic carbon budget and the pH of sediment porewaters, which preferentially destabilizes and then dissolves Mg-silicates. Together, the sedimentological, stratigraphic and geochemical predictions of the model explain many enigmatic features of the Barra Velha Formation, providing a novel framework for understanding how Mg-silicate–carbonate interactions might generate secondary porosity more broadly in other lacustrine carbonate reservoirs across the South Atlantic.

Abstract The cyclic distribution of various types of carbonates and Mg-clays in early Cretaceous rift-sag phase lacustrine carbonates from the subsurface of the South Atlantic provides an insight into how evolving lake chemistries in highly alkaline settings control facies development. The typically subdecametre scale symmetrical and asymmetrical cyclothems exhibit three main components: mud-grade laminated carbonates, millimetre-diameter spherulites with evidence of having been in a matrix of Mg-silicates, and millimetre–centimetre calcitic shrub-like growths. The laminites contain conspicuous numbers of ostracods and vertebrate remains and were produced by short-lived pluvial events, causing expansion of shallow lakes. Later evaporation triggered Mg-silicate precipitation and calcite nucleation within gels to produce spherulitic textures. When the rate of gel precipitation decreased or ceased, calcite growth, now less inhibited, produced shrub-like calcites resembling those produced abiotically in modern travertines, although still with some evidence of the former presence of some Mg-silicates. Physical reworking of these sediments led to the dispersion of the gels and the concentration of detrital carbonate components. Despite earlier proposals, evidence of microbial processes producing carbonates in these Cretaceous lake deposits is rare and the application of facies models based on modern and ancient microbialite analogues maybe be misplaced.

Abstract The relatively simplistic facies models for lacustrine carbonates do not currently incorporate either the diversity of microbialite carbonate development or the influence of volcanic-related processes found in rift settings. The basic nature of the carbonate factories in these systems, whether microbial, macrophytic, skeletal or abiogenic, is not resolved. Lacustrine microbialites can develop in shallow lakes as concentrations of microbialite mounds covering many hundreds of square kilometres, or as bathymetrically controlled facies belts, but in many rift settings vent-related thermal and non-thermal carbonates (travertines and tufas) are a major component. Subaqueous vent-related carbonates, with evidence of microbial activity, can produce seismic-scale carbonate build-ups in deeper lakes or apparently more stratiform accumulations in shallow lakes. In lakes with only volcanic catchments, Mg and silica activity, coupled with high carbonate alkalinity and microbial influences, can potentially generate a complex set of mineral–microbe interactions and products, creating a unique set of challenges for predicting and understanding reservoirs in such settings.

Abstract It is now well established that seawater chemistry, as well as influencing non-skeletal marine precipitation (‘calcite’ and ‘aragonite seas’), has affected skeletal mineral secretion in some algal and marine invertebrate groups. Skeletal mineralogy has had a yet more profound consequence on fossil preservation. The realization that the fossil record of marine organisms with an aragonite shell is widely depleted in some shelf settings through early, effectively syn-depositional, dissolution (‘missing molluscs’ effect) has led to a re-evaluation of the composition, diversity, ecological and trophic structure of marine benthic communities. Comparisons of molluscan lagerstätten from ‘calcite’ and ‘aragonite seas’ show a similar pattern of skeletal mineralogical loss, that is, no differences are discernibly linked to changed seawater geochemistry. It is notable that the rare mollusc-rich skeletal lagerstätten faunas in the fossil record include many small individuals. Micromolluscs are quantitatively important among modern shell assemblages, yet small size is a major source of taphonomic and biodiversity loss in the fossil record. In skeletal lagerstätten faunas, micromolluscs contribute variably to mollusc biodiversity but appear particularly significant through at least to Triassic times. They highlight a further ‘missing molluscs’ effect of taphonomic loss through early dissolution.

Preservational bias in paleosol formation is rarely discussed and remains a major issue in paleopedology. The relatively simple paleosol profiles of the Silurian-Devonian Old Red Sandstone alluvial successions of southwest Wales provide an opportunity to investigate the completeness of a widespread type of calcic Vertisol. Reactivated, truncated cumulate horizons provide means of assessing the dynamics of floodplain erosion and accumulation. While these distinctive profiles are not especially common, effects of low-magnitude erosion events were probably masked, affecting only the topmost part of the upper soil horizon. In the absence of a stabilizing rooted vascular plant cover in pre–mid-Paleozoic sediments, such mobile upper soil horizons were likely a common feature. La posibilidad de preservación de paleosuelos es un hecho raramente discutido, a pesar de ser un tema importante dentro de la paleoedafología. Los perfiles de paleosuelos relativamente sencillos de las sucesiones aluviales del Silúrico-Devónico de la Old Red Sandstone en el suroeste de Gales ofrecen una buena oportunidad para investigar si el registro de algunos tipos de paleosuelos muy frecuentes, los Vertisuelos cálcicos, es completo o no. Los horizontes reactivados, truncados y compuestos de estos paleosuelos nos aportan los medios para conocer la dinámica de la erosión y acumulación dentro de la llanura de inundación. En los casos en los que estos perfiles no son muy comunes, los efectos de eventos erosivos de baja magnitud quedan enmascarados afectando sólo a la parte más alta del horizonte superior del suelo. En ausencia de una cobertera vegetal de plantas vasculares enraizadas que estabilizaran la superficie, como es el caso de los sedimentos anteriores al Paleozoico medio, estos horizontes móviles del suelo fueron probablemente un rasgo característico.