ABSTRACT Times of higher paleolake levels in Mono Lake basin correspond to higher abundances of authigenic minerals such as calcite and Mg-smectite in the Wilson Creek Formation, the lake sediments exposed around the modern lake that represent the persistent wetter conditions of the last glacial cycle. It has been suggested that precipitation of these minerals in Mono Lake is controlled by the flux of water (surface and ground), which replenishes Ca 2+ and Mg 2+ ions in the lake. This water is subsequently depleted due to the high rates of evaporation in the Mono Basin, resulting in precipitation of calcite and Mg-smectite mineral phases. Thermodynamic evaporation models starting with Sierra Nevada spring water can simulate the chemical composition of Mono Lake remarkably well. These models do not, however, consider the mixing of freshwaters in the lake that is hypothesized to result in precipitation of calcite and Mg-smectite. Here, we present the results of our empirical evaporation and mixing (E&M) model using simple thermodynamic approaches. Although this model is highly simplified, it provides a valuable test of the hypothesis.

ABSTRACT Uplift of the central Andes during the Miocene was followed by large-scale reorganization of Atlantic-draining rivers in Argentine Patagonia. Here, we document the abandonment of one large river in the late Pliocene and the establishment of the modern drainage in the Early Pleistocene. A chronology for these events is provided by 40 Ar/ 39 Ar ages on basalt flows. Remnants of the Pliocene paleovalley system are well preserved in the Lago Cardiel–Gobernador Gregores area, where they are eroded into flat-lying basalt flows dated from ca. 13.9 Ma to 8.6 Ma. Younger basalts that erupted onto the abandoned floor of the paleovalley are as young as 3.7 Ma. Abandonment of the Pliocene paleovalley and establishment of the modern Río Chico and Río Shehuen catchments happened near the close of the Pliocene when Andean glaciers incised the east-sloping pediment on which the late Miocene drainage was established. Lago Cardiel sits within a large endorheic basin that is inset into the late Pliocene paleovalley. The basin began to develop just before 4 Ma, after the paleovalley was abandoned. It became larger and deeper during the Pleistocene due to mass movements along its margins, deflation of the basin floor during times when Lago Cardiel was dry or nearly dry, and possibly lowering along bounding faults. The Pliocene–Pleistocene landscape and drainage changes that we have documented are not unique to the Lago Cardiel–Gobernador Gregores area; similar changes are apparent elsewhere in Patagonia east of the crest of the Andes.

Abstract Iceberg discharges into the North Atlantic are important sources of fresh water, and the sediments they deposit can provide constraints on which sectors of different ice sheets were contributing icebergs. 40 Ar/ 39 Ar ages of sand-sized hornblende grains provide useful constraints on IRD (ice-rafted detritus) source areas. Heinrich events are intervals of anomalously high percentages of IRD in marine sediment cores of the North Atlantic IRD belt. In contrast to the others, Heinrich event 3 (H3) records a significantly lower flux of IRD. This study compares 40 Ar/ 39 Ar hornblende age distributions from the interval around and including H3 in giant gravity core EW9303-GGC31 from Orphan Knoll, in the southern part of the Labrador Sea, with piston core V28-82 in the eastern part of the North Atlantic IRD belt. Collectively, these results confirm that H3 represents a Hudson Strait IRD event, but that it was smaller than during H1, H2, H4 and H5, and therefore comprises only a small fraction of the detritus at the eastern North Atlantic location of V28-82. These results support a previously published interpretation of across-strait ice flow during H3 at Hudson Strait. Supplementary material: Appendix 1 is 40 Ar/ 39 Ar data from core EW9303-GGC31; Appendix 2 is grain counts across H3 from core V28-82; Appendix 3 is 40 Ar/ 39 Ar data from core V28-82; these are available at http://www.geolsoc.org.uk/SUP18631 .

Abstract Well-preserved Mesozoic terrestrial fossils were discovered in the Haifanggou Formation and the overlying Lanqi Formation (or their correlative strata) in NE China. The recent discoveries of Schmeissneria sinensis and Xingxueanthus sinensis from the middle and upper Jurassic Haifanggou Formation provide evidence that the origin of angiosperms could be predate the Early Cretaceous. In addition to the finding of pre-Cretaceous angiosperms from the Haifanggou Formation, the overlying Lanqi Formation yields a rich and varied terrestrial flora. The high diversity and abundance of the palaeoflora from these formations provide a unique window to understand floral evolution and its diversification in the Mesozoic. Two tuff samples and one andesite sample collected from the Haifanggou and Lanqi formations near Beipiao City, Liaoning, NE China yield robust 40 Ar/ 39 Ar age results. Our 40 Ar/ 39 Ar age of 166.7 ± 1.0 Ma for plagioclases from one tuff interbedded in the fossiliferous horizons of the middle Haifanggou Formation provides accurate age calibration for the pre-Cretaceous angiosperms for the first time. Moreover, our age results for these fossil-bearing formations will improve our knowledge of the Jurassic environment in general, including the link between plants and atmospheric CO 2 . Supplementary material: Details of analysis procedures, Ar isotopic data corrected for blanks, mass discrimination, radioactive decay and J values are available at: http://www.geolsoc.org.uk/SUP18575 .

Four different sand types (termed FSP1, FSP2, FSP3, and FSP4) have been recognized in the Paleocene succession of the Faroe-Shetland Basin, NE Atlantic, on the basis of conventional heavy mineral analysis, major element geochemistry of garnet, trace element geochemistry of rutile, U-Pb dating of detrital zircon, and palynofloral analysis. Sand types FSP1, FSP2, and FSP4 were all sourced from the eastern margin of the basin, whereas FSP3 was supplied from the west. No single technique discriminates all four sand types. Conventional heavy mineral analysis discriminates FSP3 from the other three sand types but does not discriminate FSP1, FSP2, and FSP4. Garnet geochemistry distinguishes FSP1, FSP2 and FSP4, but FSP3 garnet populations overlap those of FSP1 and FSP2. Rutile geochemistry distinguishes FSP2 from FSP1 and FSP4 but cannot be easily applied to FSP3 owing to the scarcity of rutile in this sand type. Zircon age spectra in FSP1, FSP2, and FSP4 are similar to one another, but FSP4 can be recognized on the basis of a higher proportion of Archean zircons. Some of the individual techniques have certain limitations: e.g., one of the key conventional heavy mineral parameters is the presence of clinopyroxene, but this is not always reliable owing to the instability of this mineral during burial diagenesis. Likewise, garnet geochemistry cannot be applied to the most deeply buried sandstones in the Faroe-Shetland Basin owing to complete garnet dissolution. Furthermore, care is required when interpreting garnet data from sandstones that have undergone partial garnet dissolution, as there may have been modification of the range of garnet compositions as a result of the greater instability of Ca-rich garnets compared with Ca-poor types. Finally, the “Greenland flora,” which occurs in association with sand type FSP3, has been found in some wells that lack FSP3 sandstones. This discrepancy is attributed to the difference in hydrodynamic behavior of palynomorphs compared with sand particles. This chapter illustrates the importance of adopting an integrated approach, as significant detail would have been lost if only one technique had been applied, and integration of a number of different techniques overcomes limitations associated with individual approaches. An integrated approach also builds a more comprehensive picture of source area characteristics.

The source of volcanic material in the Upper Triassic Chinle Formation on the Colorado Plateau has long been speculated upon, largely owing to the absence of similar-age volcanic or plutonic material cropping out closer than several hundred kilometers distant. These strata, however, together with Upper Triassic formations within El Antimonio and Barranca Group sedimentary rocks in northern Sonora, Mexico, yield important clues about the inception of Cordilleran magmatism in Triassic time. Volcanic clasts in the Sonsela Member of the Chinle Formation range in age from ca. 235 to ca. 218 Ma. Geochemistry of the volcanic clasts documents a hydrothermally altered source region for these clasts. Detrital zircons in the Sonsela Member sandstone are of similar age to the clasts, as are detrital zircons from the El Antimonio and Barranca Groups in Sonora. Most noteworthy about the Colorado Plateau Triassic zircons, however, are their Th/U ratios, which range from ~1 to 3.5 in both clast and detrital zircons. Thorium/uranium ratios in the Sonoran zircons, in contrast, range from ~0.4 to ~1. These data, together with rare-earth-element geochemistry of the zircons, shed light on likely provenance. Geochemical comparisons support correlation of clasts in the Sonsela Member with Triassic plutons in the Mojave Desert in California that are of the same age. Zircons from these Triassic plutons have relatively low Th/U ratios, which correspond well with values from El Antimonio and Barranca Group sedimentary rocks, and support derivation of the strata, at least in part, from northern sources. The Sonsela Member zircons, in contrast, match Th/U values obtained from Proterozoic through Miocene volcanic, volcaniclastic, and plutonic rocks in the eastern and central Mojave Desert. Similarly, rare-earth-element compositions of zircons from Jurassic ignimbrites in the Mojave Desert, though overlapping those of zircons from Mojave Desert plutons, also closely resemble those from Sonsela Member zircons. We use these data to speculate that erosion of Triassic volcanic fields in the central to eastern Mojave Desert shed detritus that became incorporated into the Chinle Formation on the Colorado Plateau.

Detrital zircon U-Pb geochronology can make an extremely valuable contribution to provenance studies and paleogeographic reconstructions, but the technique cannot distinguish grains with similar ages derived from different sources. Hafnium isotope analysis of zircon crystals combined with U-Pb dating can help make such distinctions. Five Paleogene formations in West Java have U-Pb age populations of 80–50 Ma (Late Cretaceous–Paleogene), 145–74 Ma (Cretaceous), 298–202 Ma (Permian–Triassic), 653–480 Ma (mid-Neoproterozoic–latest Cambrian), and 1290–723 Ma (late Mesoproterozoic–early Neoproterozoic). Hf-isotopes have been analyzed for 311 zircons from these formations. Differences in zircon U-Pb age and Hf-isotope populations reflect changing sources with time. Late Cretaceous and Paleogene zircons are interpreted as having been derived from two temporally discrete volcanic arcs in Java and West Sulawesi, respectively. The Java arc was active before micro-continent collision, and the W Sulawesi arc developed later, on newly accreted crust at the SE Sundaland margin. The collision age is estimated to be ca. 80 Ma. U-Pb age and 176 Hf/ 177 Hf i characteristics allow a distinction to be made between Cretaceous granitic and volcanic arc sources. Zircons that are older than ca. 80 Ma have a continental Sundaland provenance. Mid-Cretaceous zircons in all upper Eocene and lower Oligocene formations were derived from granites of the Schwaner Mountains of SW Borneo. Permian–Triassic zircons were derived predominantly from granites in the SE Asian Tin Belt. 176 Hf/ 177 Hf i ratios permit distinction between Tin Belt granites in the Main Range and Eastern Provinces, and indicate that only the lower Oligocene Cijengkol Formation contains significant input from the Main Range Province, suggesting a partial change in drainage pattern. Older zircon ages are more difficult to interpret but probably record contributions from allochthonous basement and sedimentary rocks that were deposited prior to rifting of continental blocks from Gondwana in the early Mesozoic.

The late Eocene to early Miocene Renova Formation records initial post-Laramide sediment accumulation in the intermontane basin province of southwest Montana. Recent studies that postulate deposition of the Renova Formation were restricted to a broad, low-relief, tectonically quiescent basin on the eastern shoulder of an active rift zone vastly differ from traditional models in which the Renova Formation was deposited in individual intermontane basins separated by basin-bounding uplands. This study utilizes detrital zircon geochronology to resolve the paleogeography of the Renova Formation. Detrital zircon was selected as a detrital tracer that can be used to differentiate between multiple potential sources of similar mineralogy but with distinctly different U-Pb ages. Laser ablation-multicollector-inductively coupled plasma mass spectrometry (LA-MC-ICPMS) U-Pb detrital zircon ages were determined for 11 sandstones from the Eocene-Oligocene Renova Formation exposed in the Sage Creek, Beaverhead, Frying Pan, Upper Jefferson, Melrose, and Divide basins. Detrital zircon ages, lithofacies, paleoflow, and petrography indicate that provenance of the Renova Formation includes Paleogene volcanics (Dillon volcanics and Lowland Creek volcanics), Late Cretaceous igneous intrusions (Boulder batholith, Pioneer batholith, McCartney Mountain pluton), Mesozoic strata (Blackleaf Formation, Beaverhead Group), Belt Supergroup strata, and Archean basement. The oldest deposits of the Renova are assigned Bridgerian to Uintan North American Land Mammal (NALM) ages and contain detrital zircons derived from volcanic, sedimentary, and metamorphic rocks constituting the “cover strata” to uplift-cored Late Cretaceous plutonic bodies. Regional unroofing trends are manifested by a decreased percentage of cover strata–sourced zircon and an increased percentage of pluton-sourced zircon as Renova deposits became younger. Zircon derived from Late Cretaceous plutonic bodies indicate that initial unroofing of the McCartney Mountain pluton, Pioneer batholith, and Boulder batholith occurred during Duchesnean time. Facies assemblages, including alluvial fan, trunk fluvial, and paludal-lacustrine lithofacies, are integrated with detrital zircon populations to reveal a complex Paleogene paleotopography in the study area. The “Renova basin” was dissected by paleo-uplands that shed detritus into individual intervening basins. Areas of paleo-relief include ancestral expressions of the Pioneer Range, McCartney Mountain, Boulder batholith–Highland Range, and Tobacco Root Range. First-order alluvial distributary systems fed sediment to two noncontiguous regional-trunk fluvial systems during the Chadronian. A “Western fluvial system” drained the area west of the Boulder batholith, and an “Eastern fluvial system” drained the area east of the Boulder batholith. Chadronian paleodrainages parallel the regional Sevier-Laramide structural grain and may exhibit possible inheritance from Late Cretaceous fluvial systems. Detrital zircons of the Renova Formation can be confidently attributed to local sources exposed in highlands that bound the Divide, Melrose, Beaverhead, Frying Pan, Upper Jefferson, and Sage Creek basins. The data presented in this study do not require an Idaho batholith provenance for the Renova Formation.

The particle size and provenance signature of glacial till from the Lonewolf Nunataks at the head of Byrd Glacier, Antarctica, show evidence of subglacial origin and therefore provide new information about ice-covered bedrock of East Antarctica. Particle-size data from ice-cored moraines at Lonewolf Nunataks show more abundant silt and clay (>50% fines) than active lateral moraines along downstream sites (<10% fines), and 25% of pebbles are faceted and/or striated. Sand and pebbles from moraines at Lonewolf Nunataks are a mix of locally derived Beacon Supergroup rocks and exotic felsic igneous and metamorphic rocks. The U/Pb detrital zircon data from the Lonewolf Nunataks till show significant populations of zircon ages, including early Ross and/or Pan-African ages of ca. 565–610 Ma, Grenville ages (ca. 950–1270 Ma), several Proterozoic peaks, and one prominent late Archean peak at ca. 2700 Ma. 40 Ar/ 39 Ar analyses of detrital hornblende and mica also show Ross and/or Pan-African ages from ca. 500 to 580 Ma, with a population of Grenville-age hornblende grains of ca. 1150–1250 Ma. This combination of geochronological tools can be used to identify recycled versus primary age populations eroded by the ice sheet, and so provide constraints on the age and distribution of unmapped, ice-covered bedrock. Our data show that petrologic and geochronologic signatures in East Antarctic till can be used to address geologic problems ranging from Cenozoic ice sheet history to Precambrian bedrock geology.

Single-step, laser-fusion 40 Ar/ 39 Ar ages of single muscovite grains with an automated micro-extraction system is a precise and relatively rapid way of analyzing large numbers of grains. This study used >500 muscovite grains from a late Wisconsinan sandy loess from eastern Long Island, New York, in order to evaluate the potential of Ar-Ar ages of single grain muscovite as a provenance tool for loess. The samples for dating were from a 2.7 m core of sediments from a small kettle hole in Wildwood State Park on the north shore of Long Island. These eolian deposits consist of a bimodal distribution of poorly sorted medium silt and medium sand that are buff colored, homogeneous, and unstratified. Long Island is a good place to test this approach, because the 40 Ar/ 39 Ar and K/Ar ages for muscovite in the potential bedrock sources to the north in New England vary systematically from ca. 450 Ma in the west to ca. 200 Ma in the east. The majority of muscovite ages in the loess range from 250 to 400 Ma, and muscovite age populations along the core show a change in proportion of muscovite input from the different provenances in New England. The results of this study confirm that using 40 Ar/ 39 Ar ages of a large number of single muscovite grains is a good method for examining the provenance of muscovite in loess, and thus understanding processes that produce loess.

The late glacial and deglacial history of the Southeastern Laurentide Ice Sheet involves the southward advance and subsequent northward retreat from southeastern Canada and the northeastern United States. Superposed on this advance and retreat are three major ice-rafting events associated with Heinrich events 2 and 1 (H2 and H1) and the Younger Dryas. Nd, Sr, and Pb isotopes were measured on the 63–150 μm, de-carbonated marine sediment for the period 24–10.5 14 C ka, from marine sediment core EW9303-GGC31, collected from the top of Orphan Knoll, a topographic high 550 km northeast of Newfoundland, Canada. In general, one of the problems with understanding ice-rafting records is the disparate provenance strategies that have been used in different studies. Nd and Sr isotopes have been widely used in the study of North Atlantic sediment provenance, and Pb isotopes and 40 Ar/ 39 Ar hornblende ages have also been used for provenance assessment in a number of studies. The new Nd, Sr, and Pb isotope data presented here are complementary to the published hornblende data from the same samples, and provide a data set that allows more confident comparison of this record with other published provenance studies. The results are consistent with reconstructions based on a combination of marine and land-based geomorphic observations.

Detrital geochronological analyses, combined with information on river sediment load, are widely employed to constrain erosion patterns in orogenic belts. Major assumptions in most detrital studies are that detrital samples are fully representative of eroding bedrock, and variation in original mineral concentration, often referred to as fertility, is negligible. Nevertheless, hydraulic sorting effects during transport may strongly affect sediment composition, and mineral fertility strongly depends on bedrock lithology. In this detrital geochronology study, we illustrate how hydraulic sorting effects can be properly evaluated, and how mineral fertility in bedrock can be determined from detrital samples, in order to infer reliable erosion patterns on short-term time scales. Fission-track, bulk-petrography, and geochemical analyses were carried out on modern sands of Rivers Dora Baltea and Arc in the Western Alps. These rivers drain in opposite directions two major fault-bounded blocks (Eastern and Western Blocks) that have undergone contrasting exhumation paths since the Miocene. Samples were collected from different sites along the river trunk, in order to investigate how the detrital signal evolves when detritus from different sub-basins is progressively added to the system. In the Dora Baltea catchment, petrographic data indicate that 29% of the total river load was derived from the Western Block, whereas the Eastern Block contributes the remaining 71%. Petrographic signatures in the modern Arc sands are more homogeneous, thus preventing a precise discrimination of the sources. Apatite fission-track data from the Dora Baltea River show that the Western Block yields 43% of the total apatite load, and the Eastern Block the remaining 57%. In the Arc catchment, apatite contribution is 29% from the Eastern Block, 14% from the Houiller-Subbriançonnais units, and 57% from the Belledonne-Dauphinois units. We assessed apatite fertility in source rocks by measuring apatite content in processed sediments, after checking for anomalous hydraulic concentrations by geochemical analyses. Apatite flux from each sub-basin was converted into a specific sediment yield to infer the short-term erosion pattern in the drainage. The annual sediment load measured along the trunk was then partitioned between sub-basins, in order to calculate erosion rates during the late- to post-glacial time interval. Results document focused erosion in the External Massifs, at rates of 0.4–0.5 mm/a, irrespective of their position inside the drainage, and a westward migration of erosional foci through time along the Western Alps transect.