Abstract The Eocene Goldstrike system on the Carlin Trend in Nevada is the largest known Carlin-type gold system, with an endowment of 58 million ounces (Moz) distributed among several coalesced deposits in a structural window of gently dipping carbonate rocks below the regional Roberts Mountains thrust. The 3.5- × 2.5-km Goldstrike system is bounded to the east by the Post normal fault system and to the south by the Jurassic Goldstrike diorite stock and is partly hosted in the favorable slope-facies apron of the Bootstrap reef margin that passes through the system. The carbonate and clastic sedimentary sequence is openly folded, cut by sets of reverse and normal faults, and intruded by the Jurassic Goldstrike stock and swarms of Jurassic and Eocene dikes, establishing the structural architecture that controlled fluid flow and distribution of Eocene mineralization. A proximal zone of permeability-enhancing decarbonatization with anomalous gold (>0.1 ppm) extends a few hundreds of meters beyond the ore footprint and lies within a carbonate δ 18 O depletion anomaly extending ~1.4 km farther outboard. The full extent of the larger hydrothermal system hosting Goldstrike and adjacent deposits on the northern Carlin Trend is outlined by a 20- × 40-km thermal anomaly defined by apatite fission-track analyses. The bulk of the mineralization is hosted in decarbonatized sedimentary units with elevated iron contents and abundant diagenetic pyrite relative to background. Gold is associated with elevated concentrations of As, Tl, Hg, and Sb, and occurs in micron-sized arsenian pyrite grains or in arsenian pyrite overgrowths on older, principally diagenetic pyrite, with sulfidation of available iron as the main gold precipitation mechanism. The intersection of a swarm of Jurassic lamprophyre dikes with the edge of the limestone reef provided a favorable deeply penetrating structural conduit within which a Jurassic stock acted as a structural buttress, whereas the reef’s slope-facies apron of carbonate units, with high available iron content, provided a fertile setting for Carlin-type mineralization. The onset of Eocene extension coupled with a southwestward-sweeping Cenozoic magmatic front acted as the trigger for main-stage gold mineralization at 40 to 39 Ma. All these factors contributed to the exceptional size and grade of Goldstrike.

Abstract Epithermal, Carlin, and orogenic Au deposits form in diverse geologic settings and over a wide range of depths, where Au precipitates from hydrothermal fluids in response to various physical and chemical processes. The compositions of Au-bearing sulfidic hydrothermal solutions across all three deposit types, however, are broadly similar. In most cases, they comprise low-salinity waters, which are reduced, have a near-neutral pH, and CO 2 concentrations that range from <4 to >10 wt %. Experimental studies show that the main factor controlling the concentration of Au in hydrothermal solutions is the concentration of reduced S, and in the absence of Fe-bearing minerals, Au solubility is insensitive to temperature. In a solution containing ~300 ppm H 2 S, the maximum concentration of Au is ~1 ppm, representing a reasonable upper limit for many ore-forming solutions. Where Fe-bearing minerals are being converted to pyrite, Au solubility decreases as temperature cools due to the decreasing concentration of reduced S. High Au concentrations (~500 ppb) can also be achieved in strongly oxidizing and strongly acidic chloride solutions, reflecting chemical conditions that only develop during intense hydrolytic leaching in magmatic-hydrothermal high-sulfidation epithermal environments. Gold is also soluble at low to moderate levels (10–100 ppb) over a relatively wide range of pH values and redox states. The chemical mechanisms which induce Au deposition are divided into two broad groups. One involves achieving states of Au supersaturation through perturbations in solution equilibria caused by physical and chemical processes, involving phase separation (boiling), fluid mixing, and pyrite deposition via sulfidation of Fe-bearing minerals. The second involves the sorption of ionic Au on to the surfaces of growing sulfide crystals, mainly arsenian pyrite. Both groups of mechanisms have capability to produce ore, with distinct mineralogical and geochemical characteristics. Gold transport and deposition processes in the Taupo Volcanic Zone, New Zealand, show how ore-grade concentrations of Au can accumulate by two different mechanisms of precipitation, phase separation and sorption, in three separate hydrothermal environments. Phase separation caused by flashing, induced by depressurization and associated with energetic fluid flow in geothermal wells, produces sulfide precipitates containing up to 6 wt.% Au from a hydrothermal solution containing a few ppb Au. Sorption on to As-Sb-S colloids produces precipitates containing tens to hundreds of ppm Au in the Champagne Pool hot spring. Sorption on to As-rich pyrite also leads to anomalous endowments of Au of up to 1 ppm in hydrothermally altered volcanic rocks occurring in the subsurface. In all of these environments, Au-undersaturated solutions produce anomalous concentrations of Au that match and surpass typical ore-grade concentrations, indicating that near-saturated concentrations of dissolved metal are not a prerequisite for generating economic deposits of Au. The causes of Au deposition in epithermal deposits are related to sharp temperature-pressure gradients that induce phase separation (boiling) and mixing. In Carlin deposits, Au deposition is controlled by surface chemistry and sorption processes on to rims of As-rich pyrite. In orogenic deposits, at least two Au-depositing mechanisms appear to produce ore; one involves phase separation and the other involves sulfidation reactions during water-rock interaction that produces pyrite; a third mechanism involving codeposition of Au-As in sulfides might also be important. Differences in the regimes of hydrothermal fluid flow combined with mechanisms of Au precipitation play an important role in shaping the dimensions and geometries of ore zones. There is also a strong link between Au-depositing mechanisms and metallurgical characteristics of ores.