Abstract Tabular igneous intrusions (sills) are common features in sedimentary basins and have the potential to be useful seals for fluids (e.g. CO 2 or H 2 ) in geological storage scenarios, and may be important as the need for geological carbon sequestration and alternative fuel storage increases. This is advantageous in regions without ready access to large-volume reservoirs in depleted hydrocarbon plays and saline aquifers, such as the northeastern USA. Moreover, geological H 2 storage requires more demanding conditions than those typically associated with oil and gas. An enhanced seal will have the properties of a traditional seal – competent, low permeability and laterally extensive – with the addition of being able to self-seal pre-existing and induced fractures. Self-sealing will occur along fluid pathways like fractures where CO 2 , water and minerals like plagioclase, olivine and pyroxene react together. Dolerite sills from the Gettysburg Basin, Pennsylvania, have remarkably low permeability and homogeneous compositions that include minerals that will readily react with CO 2 dissolved in water. Here, we characterize the physical properties and chemical gradients within several mafic sills cored in five boreholes. In addition, preliminary CO 2 -reaction experiments on dolerite samples demonstrated rapid carbonate mineralization.

ABSTRACT The Rosario segment of the Early Cretaceous Alisitos oceanic arc exposes the transition from upper-crustal volcanic and hypabyssal rocks to middle-crustal plutons, which formed in an extensional environment. The Rosario segment forms a structurally intact, unmetamorphosed, spectacularly well-exposed, gently tilted section that is 50 km long and 7 km deep. The top of the exposed section is unconformably overlain by flat-lying Late Cretaceous sedimentary rocks (Rosario Group, described elsewhere), and the base of the section passes downward into ductilely deformed metamorphic rocks (not mapped herein). We divided the Rosario segment into three subsegments: a central subaerial edifice, underpinned by the La Burra pluton; a southern volcano-bounded basin (dominantly shallow marine), underpinned by the San Fernando pluton; and a northern fault-bounded basin (dominantly deep marine), underpinned by the Los Martires pluton. Using a combination of published and new geochronologic data, we infer that the time span represented by the arc crustal section could be as little as 1.7 m.y., dated at ca. 111–110 Ma. Volcanic and plutonic samples show a continuum from basalt/basaltic andesite to rhyolite, are low to medium K, and are transitional tholeiite to calc-alkaline in character. Hf isotopic data from zircons indicate primitive magma, consistent with previously published whole-rock isotopic data. The volcanic stratigraphy can be correlated across all three subsegments using the tuff of Aguajito (Ki-A) , a distinctive rhyolite welded ignimbrite that fills the 15-km-wide, >3.6-km-deep La Burra caldera on the central subaerial edifice. Additionally, a second caldera is preserved below the tuff of Aguajito (Ki-A) in the northern fault-bounded basin, floored by a large rhyolite sill complex, up to 700 m thick with a lateral extent of >7 km. Up section from the tuff of Aguajito (Ki-A) , there is an abrupt shift to dominantly mafic volcanism that we correlated across all three subsegments of the Rosario segment, dividing the section into two distinct parts (phase 1 and phase 2). The pluton beneath the central subaerial edifice (La Burra) is associated with the caldera that produced the tuff of Aguajito (Ki-A) during phase 1. Plutons beneath the northern fault-bounded basin (Los Martires) and the southern volcano-bounded basin (San Fernando) were emplaced during phase 2. However, we infer that the La Burra pluton, which is associated with the phase 1 La Burra caldera, continued to grow incrementally during phase 2 because it intruded and tilted both phase 1 and phase 2 strata. The Rosario segment escaped postmagmatic deformation, other than gentle tilting (25°–35°) to the west as a single rigid block. The Rosario segment of the Cretaceous Alisitos arc represents an extensional oceanic arc with abundant silicic pyroclastic rocks, culminating in arc rifting with outpouring of mafic magmas. The excellent exposure and preservation provide us with the opportunity to herein describe the following: (1) caldera collapse features and the products of varying explosive eruptive styles; (2) caldera plumbing systems, including silicic sill complexes; (3) the transition from plutons through hypabyssal intrusions to eruptive products; (4) incremental pluton growth and its effects on the structure of the roof rocks; (5) the products of deep-water mafic to silicic eruptions; and (6) flow transformations that occur when hot pyroclastic flows enter marine basins on gentle slopes versus steep slopes. We also used this data set to address questions highly complementary to the work being done on understanding the growth of continental crust at subduction zones. Finally, this volume serves as a model for detailed geologic study of paleo-arcs.

The Rosario segment of the Cretaceous Alisitos arc (Baja California, Mexico) is arguably the best-exposed structurally intact and unmetamorphosed oceanic arc crustal section on Earth. The gently tilted, 50-km-long section exposes the transition from upper-crustal volcanic rocks to mid-crustal plutonic rocks, formed in an extensional environment. This book presents a detailed geologic map, based on an exhaustive data set including geochemistry, geochronology, and annotated outcrop photos and photomicrographs. Subsegments within the Rosario segment include a subaerial edifice, a volcano-bounded basin, and a fault-bounded basin, each underpinned by separate plutons. The entire data set is integrated across these subsegments in a time slice reconstruction of arc evolution and the relationships between plutonism and volcanism. The data set provides constraints on the evolution of silicic calderas and tectonic triggers for caldera collapse, caldera resurgence by emplacement of sill complexes and by incremental growth of plutons, and comparison with velocity profiles in modern arcs.