Abstract This introduction briefly outlines the potential impact of igneous processes on sedimentary basins and their energy resources. The associated volume includes contributions across a range of scales; from margin-wide rifting to impacts on reservoir quality. The impact of igneous systems on elements such as tectonics, heat flow, hydrocarbon (and other) fluid charge, structuration and reservoirs are reviewed with a direct impact on hydrocarbon exploration and production, geothermal and carbon capture storage projects. A strong understanding of these commonly overlooked, igneous processes is likely to enable successful exploration for additional energy resources such as frontier hydrocarbons, geothermal heat, hydrogen as well as helium.

Abstract The thermal evolution of continental rifted margins is key to understanding margin subsidence and hydrocarbon prospectivity. Observed heat-flow values, however, do not always comply with classic rifting models. Here, we use 2D numerical models to investigate the relationship between rifting, sedimentation and thermal history of margins. We find that during the synrift, the basement heat-flow and temperature are not only controlled by extension factor, but also by synrift sediment thickness and the evolution of deformation. As this progressively focuses oceanward, the proximal sectors thermally relax, while the distal sectors experience peak temperatures. In the post-rift, the lithosphere under the hyperextended margins does not return to its original state, at least for c. 100 Myr after break-up. Instead, it mimics that of the adjacent oceanic plate, which is thinner than the original continental plate. This results in heat-flow increasing oceanward at post-rift stages, when classic rifting theory predicts complete thermal relaxation. Our models also predict slightly increased heat-flows in the adjacent oceanic crust, potentially extending hydrocarbon plays into distal margins and oceanic crust, previously discarded as immature. Finally, our models indicate that commonly used temperature approximations to calculate heat-flow during rifting may strongly differ from those occurring in nature.

Abstract The record of igneous activity (magmatism and volcanism) can significantly affect natural resource exploration and exploitation, including the search for hydrocarbons, critical minerals, natural hydrogen and geothermal energy sources, as well as using mafic igneous rocks as storage sites for CO 2 . These effects will vary depending on the nature and timing of the activity, the structural framework and the crustal architecture of the affected country-rock. To understand these effects and the interplay with other factors, we must first know the igneous record's distribution, timing, and petrology. In this paper, we describe a new geospatial database of the igneous rock record designed to provide a baseline digital resource that is application-agnostic and can be applied across the broadest range of research and resource exploration activities. We discuss the challenges we have faced and solved at each of the three main stages of geospatial mapping: database design, database population and database visualization. This includes the importance of a comprehensive audit trail so that users can differentiate between well and poorly-constrained interpretations, helping identify areas requiring additional work and data acquisition. The result is a geospatial database that will facilitate a better understanding of the Earth system and natural resource exploration.

Abstract The opening of the South Atlantic Ocean in the Early Cretaceous was only the final stage of the complex rifting process of SW Gondwana. In this contribution, we reassess the chronology of Mesozoic basin formation in southern South America and Africa and integrate it in the long-term rifting and break-up history of SW Gondwana. During the Triassic, after the Gondwanides orogeny, plate-scale instabilities produced intracontinental rifting in Africa, and retro-arc extension on the SW-margin of Gondwana. This process was followed and accentuated by the impingement of the Karoo plume in the Early Jurassic, which triggered rifting in East Africa and ultimately produced the break-up of Eastern from Western Gondwana in the Middle Jurassic. Retro-arc extension continued to affect the palaeo-Pacific margin, with emplacement of the Chon Aike magmatic province in the Patagonian retro-arc during the Early–Middle Jurassic. By the Late Jurassic, retro-arc rifting reached a point of oceanic crust accretion, with the establishment of the Rocas Verdes back-arc basin in southern Patagonia, together with the formation of the Weddell Sea further south, between the South American plate and Antarctica. The core of the Late Paleozoic Gondwanides orogen, between southern South America and Africa, was subjected to oblique rifting at this time and produced the Outeniqua and Rawson/Valdés basins. This area was the locus of extension and oceanization in the Early Cretaceous associated with a rotation of the stress field from NE–SW to east–west extension. The formation of the South Atlantic Ocean resulted from lithospheric extension and was accompanied by extensive intrusive magmatism and extrusive flood basalts identified as seaward dipping reflectors, which were emplaced diachronically from south to north, along different segments along both conjugate margins. These volcanic rocks form the South Atlantic Large Igneous Province. The chronology of the South Atlantic opening and the magmatic sources and processes associated with the formation of seaward dipping reflectors remain interpretative as they have only been studied on seismic data but are still undrilled; hence, scientific drilling will be key to unravel many of these unknowns.

Abstract Intruding magma can create space by uplift and elastic bending of the overburden, which locally fractures the deforming volume and produces flat-topped or dome-like forced folds. Here, I map such fracture networks and quantify their geometry and connectivity across a range of natural and modelled intrusion-induced forced folds. I show that there is a positive relationship between forced fold length and amplitude, and all fracture networks comprise traces, with variable lengths and orientations, that are more intense and denser where fold curvature is greatest. Fracture length populations are typically best described by power-law distributions, but some fit better to log-normal or exponential distributions. Connectivity of fracture networks is low and generally increases with folding, but resurfacing by eruptive products can disrupt this trend. My work supports previous analyses of forced folds and fractures, suggesting that we can use the fracture characteristics of exposed forced folds to predict that of buried forced folds. Due to their geometry and fracture network, intrusion-induced forced folds make ideal fluid traps. As these forced folds are common in many volcanic settings and sedimentary basins, we should consider their potential as exploration targets for water, magmatic-related mineral and metal deposits, and particularly CO 2 storage.

Abstract The Northern Carnarvon Basin (NCB) located on Australia's North West Shelf hosts an extensive (∼40 000 km 2) intrusive igneous complex related to Mesozoic rifting and break-up. Using an extensive suite of modern 3D seismic reflection surveys, we have mapped this intrusive system across the NCB. We identify three predominant intrusion morphologies: stacked sheets of large interconnected sill intrusions (up to ∼170 km long) and smaller (8–30 km long) isolated, strata concordant intrusions, which often interact with normal faults emplaced into deltaic sedimentary rocks, and variably sized (10–40 km long) saucer-shaped intrusions emplaced into marine shales, spread across seven zones (geographically constrained groups of intrusions of a specific morphology). We consider the zones’ margin-parallel orientation, suggesting control by subcrustal extensional processes during rifting, and the variation in intrusion morphology between these zones, suggesting a dominant control by host rock mechanical properties. We integrate previous work with our observations, constraining emplacement to between the Kimmeridgian and Valanginian, coinciding with key phases of margin evolution. Finally, we assess the impact of this intrusive complex on local petroleum systems. There is likely little to no adverse impact on source rock maturation or reservoir contamination by CO 2 , but there is a spatial dissociation between the location of groups of intrusions and the gas fields, particularly in the Exmouth Plateau. This suggests that migrating hydrocarbons may be blocked, baffled and/or redirected by emplaced igneous rocks.

Abstract Igneous intrusions in sedimentary petroleum basins are often perceived as having a negative impact on the elements of the petroleum system, though the impact of intrusion-related deformation features on petroleum systems and broader geoenergy applications is not well understood. In this study, we use 3D seismic reflection data to document a variety of deformation styles that are spatially and temporally associated late Cenozoic magmatic activity in the Bass Basin, offshore southeastern Australia; three types of normal fault systems (conjugate faults, concentric faults, radial faults) and fluid escape pipes. These deformation features occur in the overburden up to ∼600 m above underlying igneous intrusions, within the Eocene to Miocene Demons Bluff and Torquay formations. The conjugate faults bound graben and are interpreted to have formed in response to underlying dyke intrusions. The radial faults are interpreted to have formed in response to overburden uplift, though the link between these and associated igneous activity is less clear. We identify 101 fluid escape features that show variation in both the morphology of their surficial depressions and of the seismic reflection characteristics of their infilling deposits. These features are interpreted to be hydrothermal or volcanic vents with underlying pipe-like feeders, depending on their spatial association with adjacent or underlying igneous intrusions. The concentric fault systems are associated with surficial depressions, and quantitative analysis of reflection sags within these depressions suggest that they are a result of subsurface subsidence in response to formation of maar-craters. The intrusion-related deformation features documented in this study may have multiple effects on working petroleum systems, such as providing secondary fluid flow pathways that can either reduce seal integrity, or enabling migration of fluids into shallower reservoirs.

Abstract Magmatic activity can severely alter the thermal structure of a sedimentary basin, with variable effects on the petroleum system. The Namibe Basin of Angola (Cretaceous South Atlantic rift) contains well-exposed magmatic and petroleum system elements and allows integrated assessment of how magmatic activity can modify the petroleum system. The basin was affected by syn-rift and post-rift magmatic events, and bitumen is observed within both the Pre- and Post-Salt stratigraphical sections. In the Pre-Salt, fluorescent bitumen has a lacustrine signature and is associated with calcite and quartz cements. Onshore Pre-Salt units are thermally immature, and therefore the source rock that generated the Pre-Salt bitumen is likely located offshore. Hydrocarbons migrated or re-migrated via magmatically driven fluids, reaching the present-day onshore. Closer to magmatic units, non-fluorescent pyrobitumen was instead observed, evidencing hydrocarbon cracking processes following emplacement. In the Post-Salt, bitumen is in situ and shows marine-like signatures compatible with an immediate Post-Salt source rock depositional environment. In the immediate Post-Salt, units with very high total organic carbon values (TOC; up to 13.8%) and excellent source rock properties (hydrogen index >600 mgHC g −1 TOC) have reached thermal maturation. Within the Namibe Basin these Post-Salt source units lie in proximity to major Turonian–Coniacian–Santonian volcanic centres and associated shallow intrusions, which are likely to have caused thermally forced maturation processes and generation of the Post-Salt hydrocarbons. This paper demonstrates the importance of an integrated field, petrographic and geochemical approach in unravelling the influence of magmatic activity on basin thermal structure and petroleum systems.

Abstract Cooling subvolcanic igneous intrusions are known to have a tremendous impact on fluid flow in the shallow Earth's crust. However, the long-term post-cooling legacy of subvolcanic intrusions on fluid flow has received much less attention. Here we describe geological examples in the Andean foothills, Argentina, showing that igneous intrusions have long-term effects on fluid flow after their emplacement and cooling. The case study consists of ∼11 Myr-old eroded andesitic intrusions of Cerro Alquitrán and Cerro La Paloma, northern Neuquén Basin, Argentina, at the rims of which large volumes of bitumen are naturally seeping out at the Earth's surface. The intrusions exhibit laccolithic shapes with steep-sided contacts with the host rock. Near the intrusive contacts, the andesite is intensely broken along concentric breccia bands and fracture bands, interpreted as resulting from syn-emplacement brittle magma deformation, which represent high-permeability pathways for the migrating bitumen. Organic geochemical analyses of the bitumen show that the seeping oils were generated from incipiently mature Vaca Muerta sections located in a regional kitchen to the west, implying a lateral migration of ∼10–20 km. The Cerro Alquitrán and Cerro La Paloma intrusions are demonstrative examples highlighting how extinct subvolcanic intrusions have long-term consequences for subsurface fluid circulations in sedimentary basins.

Abstract This contribution presents a detailed geological study of a well-exposed igneous petroleum system at Sierra de Cara Cura, Neuquén Basin, Argentina, which consists of sills, dykes, laccoliths and hybrid intrusion morphologies. The size of the exposed intrusive complex (19 km in north–south direction) is similar to those of sill-clusters hosting producing oil fields of the nearby Río Grande Valley. Most sills (>80%) are preferentially emplaced in the organic-rich rocks such as Vaca Muerta and Agrio Formations. Sills are extensively fractured and represent potentially good fractured hydrocarbon reservoirs. We document several fracturing mechanisms that can lead to heterogeneous fracture distribution. Laccoliths represent very different igneous reservoirs with a typical zonation: the core of the laccoliths are massive and poorly fractured, whereas the rims consist of a breccia formed during laccolith emplacement. The Vaca Muerta and Agrio Formations are thermally altered by the cooling of the sills. The deep parts of the outcropping laccoliths likely altered thermally the shale formations they were emplaced in. Hydrogen Index (HI) and Transformation Ratio (TR) of the organic matter are the best parameters to determine the thickness of the thermal aureole. The Sierra de Cara Cura appears as a world-class field analogue of igneous petroleum systems.

Abstract Volcanic plumbing systems emplaced in sedimentary basins may exert significant mechanical and thermal effects on petroleum systems. The last decade of research has evidenced that igneous intrusions may enhance thermal maturation of organic matter in source rocks and lead to both small- and large-scale structures that can deeply impact fluid migration or trapping. This contribution describes how the emplacement of a whole intrusive complex generated a dome structure of the overburden, which is the main trapping structure of a large producing oilfield. Our case study is the lower Miocene Cerro Bayo de la Sierra Negra (CBSN) intrusive complex, Neuquén Basin, Argentina, associated with the El Trapial oilfield where the main trapping structure is a large domal antiform centred on the CBSN complex. This study integrates the large subsurface dataset produced during the development of the El Trapial oilfield. More than 1200 vertical wells (producers and injectors) have been drilled in the flanks of CBSN complex. In addition, five 3D seismic cubes have been acquired over the years that have been merged and reprocessed into a single volume. Such a dataset allows a detailed characterization of both the structure affecting the Mesozoic strata and the geometry of the intrusive complex. Igneous rocks have been recognized along the entire stratigraphic section. Sill intrusions appear to concentrate in the shale units and the stacking of them has a direct impact on the doming structure generation. Our study allowed us to establish a direct correlation between the distribution of the intrusions and the extent, amplitude and style of doming, showing that the dome structure results from the emplacement of the intrusive complex. We also show that part of the doming is related to intrusions emplaced in the Mesozoic formations of the Neuquén Basin, whereas the other part of the doming is related to deeper structures not imaged on the geophysical data. We estimate that the amplitude of the doming reaches up to c. 500 m. The voluminous subsurface data, combined with exposed outcrops, makes the CBSN complex a world-class case study for showing how the shallow plumbing system of a volcanic complex may control the growth of large-scale trapping structures for various fluids, such as drinkable water, geothermal fluids and hydrocarbons.

Abstract Oil seeps related to igneous rocks in the Neuquén Basin have been known since pre-Hispanic times (sixteenth century) and have been explored in the southern Mendoza province since the late nineteenth century. In the 1980s, YPF (Yacimientos Petrolíferos Fiscales) began the exploration of igneous rocks as hydrocarbon reservoirs in the Río Grande Valley area. The possible productivity of these ‘unconventional’ reservoirs was recognized by studying outcrops and well data of sills and dykes emplaced in different formations of the fold and thrust belt of the northern Neuquén Basin. Mud-logging control and evaluations with drill stem tests (DST) were decisive to define these reservoirs as prospective. From petrographical reports on samples from outcrops and cores, six lithological types could be distinguished in the igneous units of this region. Recent works confirm that this volcanism belongs to two predominant cycles: from the late Oligocene to the Miocene (‘Molle’) and from the Middle to upper Miocene (‘Huincán’). Although in igneous reservoirs it is difficult to forecast the estimated ultimate recovery (EUR), sills that crosscut the source rocks of the Vaca Muerta and Agrio formations demonstrate surprisingly high production rates, although the number of wells for the complete development is always difficult to establish.

Abstract The Browse Basin is one of Australia's major hydrocarbon provinces, where significant discoveries have been made in recent decades including the Ichthys and Prelude fields, which accounted for ∼15% of the cumulative Australian liquified natural gas (LNG) production in 2019–20. This rift basin hosts extensive Mesozoic intrusive and extrusive igneous rocks, having been identified from both well and seismic data, and which are recognized as one of the key challenges for exploration and production activities in this region. Their impact on petroleum exploration is demonstrated by the number of wells which encountered unpredicted or thicker than expected igneous rock units both within and adjacent to target sections. This study therefore aims to document the reasons of such unexpectedness, and to develop capability to predict the occurrence of igneous rock units prior to drilling in the Browse Basin and other rift settings that contain igneous rocks. Multiple case studies of uncommercial exploration wells are developed by integrating petrophysical and seismic reflection data, focusing in particular along the outboard part of the basin where igneous rocks are most prevalent. Our study highlights the importance of understanding petrophysical, spatial and chemical heterogeneities of igneous rocks in basins to explain their emplacement and distribution, and thereby predict their occurrence prior to exploration and development activities.

Abstract Lava flows form important fluid reservoirs and have been extensively exploited for water aquifers, geothermal energy, hydrocarbon production and, more recently, for carbon storage. Effusive subaerial mafic to intermediate lava flows account for vast rock volumes globally, and form reservoirs with properties dictated by well-known lava flow facies ranging from pāhoehoe through several transitional forms to ‘a’ā lava. These variations in flow type lead to critical differences in the pore structure, distribution, connectivity, strength and fracturing of individual lava flows, which, alongside lava flow package architectures, determine primary reservoir potential. Lava flow margins with vesicular, fracture and often autobreccia-hosted pore structures can have porosities commonly exceeding 40% and matrix permeabilities over 10 −11 m 2 (>10 D) separated by much lower porosity and permeability flow interiors. Secondary post-emplacement physicochemical changes related to fracturing, meteoric, diagenetic and hydrothermal alteration can significantly modify reservoir potential through a complex interplay of mineral transformation, pore-clogging secondary minerals and dissolution, which must be carefully characterized and assessed during exploration and appraisal. Within this contribution, a review of selected global lava flow-hosted reservoir occurrences is presented, followed by a discussion of the factors that influence lava flow reservoir potential.

Abstract Offshore CO 2 sequestration in basaltic formations of the North Atlantic Igneous Province may allow permanent storage of large volumes of CO 2 through rapid carbonate mineralization. Characterizing the internal architecture of such reservoirs is key to assessing the storage potential. In this study, six photogrammetry models and three boreholes on the Faroe Islands have been used to characterize the internal lava sequence architectures as a direct analogue to potential offshore North Atlantic Igneous Province storage sites. The studied formations are dominated by c. 5 to 50 m thick simple and compound lava flows, with drill core observations documenting a transition from pāhoehoe moving towards ‘a’ā lava flow types interbedded with thin (<5 m thick) volcaniclastic rock units. The identification of flow margin breccias is potentially important as these units form excellent reservoirs in several other localities globally. Stacked, thick simple flows may present sealing units associated with dense flow interiors. Connected porous and permeable lava flow crusts present potential reservoirs; however, the degree of secondary mineralization and alteration can alter initially good reservoir units to impermeable barriers for fluid flow. Large-scale reservoir volumes may be present mainly within both vesicular, fractured pāhoehoe and brecciated flow margins of transitional simple lava flows.

Abstract The Faroe–Shetland basin (FSB) is considered challenging for oil and gas exploration due to its complex geological structure and limited exploration drilling activity. The costs of drilling in the basin are the most expensive within the United Kingdom Continental Shelf (UKCS) due to varying geological and engineering challenges. The prevalence of igneous sill complexes within the basin present drilling hazards that contribute to drilling nonproductive time (NPT) and are documented in multiple studies. Recent advancements in ultradeep azimuthal resistivity (UDAR) technology which utilizes the look-ahead portion of the electromagnetic (EM) signal presents an opportunity to assess its suitability as a derisking tool to ‘look-ahead’ and detect igneous intrusions in volcanic basins. This paper utilizes resistivity log data from Well 214/28-1, which encountered multiple igneous intrusions and is used to validate the ability of these tools to detect the intrusions. The EM look-ahead technology detected with good confidence the top of an igneous intrusion 72 ft (22 m) true vertical depth (TVD) ahead of the transmitter and once drilled, detect the base of the intrusion 54 ft (16 m) TVD ahead of transmitter. The detection of the intrusions prior to drilling and information on intrusion thickness can enable proactive drilling decisions to reduce nonproductive time.

Abstract Volcaniclastic rocks are commonly overlooked as reservoirs or seals in hydrocarbon plays because their compositions are variably unstable and reactive during burial diagenesis. This study investigated the petrography and petrophysical characteristics of 60 volcaniclastic and four siliciclastic samples from three Paleogene volcanic provinces – East Greenland, Faroe Islands and Ethiopia. The volcaniclastic samples have highly variable helium porosities (average 25.2%), but negligible total optical porosities (average 1.9%), implying reduced reservoir potential. The samples have, however, highly variable air permeabilities (average 11 mD), suggesting that they could make tight reservoirs. The permeabilities are related to either early calcite cements or the devitrification of volcanic glass. Mercury injection capillary pressure data were collected for a subset of 33 samples that at leakage/breakthrough saturations could, under near-surface conditions, hold oil column heights of between 4 and 1181 m (average 240 m). The best seals consistently have zeolite contents of >20 vol% owing to their small pore throat radii. Conversely, the worst seals are dominated by smectite and a conspicuous absence of zeolite minerals. The zeolite-rich volcaniclastic rocks could, therefore, make good shallow seals. These features also apply to CO 2 storage, but questions remain about the reactivity of the volcanic material and secondary minerals with injected CO 2 , but also the adsorbent properties of zeolites, particularly clinoptilolite, in the presence of CO 2 .