Abstract Noble gas isotopes, major element isotopes, and gas composition were obtained from the shut-in Butler #3 (API 32-105-00008) and Simpson #1 (API 32-105-00007) wells, drilled in 1998, and sample gas from the Cumnock Formation of Late Norian age. This is the first gas chemistry compilation of these wells. The wells’ gas, sampled in 2009 and in 2014, had a strong “fruity” light petroleum odor, a visible condensate plume when the wells were flowed, and are in the oil and wet gas window. Shutin well pressures were ~900 psi (Butler #3), and ~200 psi (Simpson #1); both had a substantial initial gas flow. Limited data are from the 1982 Dummitt-Palmer #1 CBM well (API 32-105-00002), now plugged and abandoned. Helium concentrations were ~0.20% to 0.24% from the noble gas analysis, neon ranged from 0.11 to 0.04 ppm, and argon was approximately 33 ppm. The measured noble gas composition contains very low atmospheric contamination with helium isotopes (0.07 R/R A ) clearly defined by a crustal origin, while neon and krypton and are mainly attributed to atmospheric origin ( 20 Ne/ 22 Ne ~9.8, 86 Kr/ 84 Kr ~0.3). Argon isotopes are mixed between crustal and atmospheric origins with 40 Ar/ 36 Ar values ~ 418 to 520. The F 20 Ne/ 36 Ar (~0.9 to 2.6), F 84 Kr/ 36 Ar (~0.8) and F 132 Xe/ 36 Ar (0.6-0.7) in the gas show enrichment in the light isotope associated with multi-stage fractionation processes with gas and fluid interaction. The methane content (range ~58 to 64%) is inverse to the nitrogen content from denitrification of very thin ammonium-bearing units (also rich in oil), and likely from illite in overlying strata.

Laguna Mar Chiquita (central Argentina; ~latitude 31°S, longitude 63°W) provides an outstanding opportunity to examine organic facies development and petroleum source-rock potential in a modern thick-skinned foreland basin lake. In this case study, we define profundal, paleodelta, and lake-margin depositional environments based on trends in bathymetry and lake-floor sediment particle size. Sedimentary geochemical analyses indicate that organic carbon–rich muds accumulate in profundal environments during the extant lake-level highstand. The lateral variability of organic facies is minimal. The quality of organic facies is controlled by lake level and depositional environment, both of which dictate patterns of algal productivity, siliciclastic dilution, and early diagenesis. We present conceptual models of lacustrine source rocks in both thick-skinned and thin-skinned foreland basins based on modern analog data from both Laguna Mar Chiquita and other lakes in the central Andean foreland. Over relatively short time intervals (10 2 –10 4 yr), climatically driven water-level fluctuations influence the source-rock potential of these basins. Over time intervals >10 5 yr, contraction and lateral migration of the basin flexural profile control stratal stacking patterns and the potential for hydrocarbon play development.

This study examines the relationship between depositional environment and sedimentary organic geochemistry in Lake Malawi, East Africa, and evaluates the relative significance of the various processes that control sedimentary organic matter (OM) in lacustrine systems. Total organic carbon (TOC) concentrations in recent sediments from Lake Malawi range from 0.01 to 8.80 wt% and average 2.83 wt% for surface sediments and 2.35 wt% for shallow core sediments. Hydrogen index (HI) values as determined by Rock-Eval pyrolysis range from 0 to 756 mg HC g −1 TOC and average 205 mg HC g −1 TOC for surface sediments and 228 mg HC g −1 TOC for shallow core samples. On average, variations in primary productivity throughout the lake may account for ~33% of the TOC content in Lake Malawi sediments (as much as 1 wt% TOC), and have little or no impact on sedimentary HI values. Similarly, ~33% to 66% of the variation in TOC content in Lake Malawi sediments appears to be controlled by anoxic preservation of OM (~1–2 wt% TOC), although some component of the water depth–TOC relationship may be due to physical sediment transport processes. Furthermore, anoxic preservation has a minimal effect on HI values in Lake Malawi sediments. Dilution of OM by inorganic sediment may account for ~16% of variability in TOC content in Lake Malawi sediments (~0.5 wt% TOC). The effect of inputs of terrestrial sediment on the organic character of surface sediments in these lakes is highly variable, and appears to be more closely related to the local depositional environment than the regional flux of terrestrial OM. Total nitrogen and TOC content in surface sediments collected throughout the lake are found to be highly correlated (r 2 = 0.95), indicating a well-homogenized source of OM to the lake bottom. The recurring suspension and deposition of terrestrial sediment may account for significant amounts of OM deposited in offshore regions of the lake. This process effectively separates denser inorganic sediment from less dense OM and allows terrestrial OM to preferentially be transported farther offshore. The conclusion is that for the organic carbon content in these regions to be elevated a mixed terrestrial-lacustrine origin is required. The hydrodynamic separation of mineral and organic constituents is most pronounced in regions with shallow bathymetric gradients, consistent with previous findings from Lake Tanganyika.

Lake deposystems are commonly associated with retroarc mountain belts in the geological record. These deposystems are poorly characterized in modern retroarcs, placing limits on our ability to interpret environmental signals from ancient deposits. To address this problem, we have synthesized our existing knowledge about the distribution, morphometrics, and sedimentary geochemical characteristics of tectonically formed lakes in the central Andean retroarc. Large, active mountain belts such as the Andes frequently create an excess of sediment, to the point that modeling and observational data both suggest their adjacent retroarc basins will be rapidly overfilled by sediments. Lake formation, requiring topographic closure, demands special conditions such as topographic isolation and arid climatic conditions to reduce sediment generation, and bedrock lithologies that yield little siliciclastic sediment. Lacustrine deposition in the modern Andean retroarc has different characteristics in the six major morphotectonic zones discussed. (1) High-elevation hinterland basins of the arid Puna-Altiplano Plateau frequently contain underfilled and balanced-filled lakes that are potentially long-lived and display relatively rapid sedimentation rates. (2) Lakes are rare in piggyback basins, although a transition zone exists where basins that originally formed as piggybacks are transferred to the hinterland through forward propagation of the thrust belt. Here, lakes are moderately abundant and long-lived and display somewhat lower sedimentation rates than in the hinterland. (3) Wedge-top and (4) foredeep deposystems of the Andean retroarc are generally overfilled, and lakes are small and ephemeral. (5) Semihumid Andean back-bulge basins contain abundant small lakes, which are moderately long-lived because of underfilling by sediment and low sedimentation rates. (6) Broken foreland lakes are common, typically underfilled, large, and long-lived playa or shallow systems.

Abstract A study of the Upper Devonian-Lower Mississippian Woodford Shale was undertaken on samples at low thermal maturity from the Arbuckle Mountains, southern Oklahoma, to dientify possible mechanisms by which natural gas might be stored in Woodford reservoirs in the adjacent Anadarko Basin. The two main lighologies in the Woodford, chert and mudstone, display different inorganic and organic characteristics. Cherts have (1) variable porosity from 0.59% to 4.90%, (2) low calculated permeabilities, and (3) small mean pore apertures. Intercrystalline pores dominate in cherts. In contrast, mudstones generally have (1) porosities ranging from 1.97% to 6.31%, (2) low calculated permeabilities, and (3) small mean pore apertures. Interparticle, intraparticle, and moldic pores all are present in mudstones. Because of their high quartz content, cherts are brittle and commonly demonstrate microfracturing that is lithologically controlled and bedding perpendicular, whereas much less microfracturing exists in mudstones. The early diagenetic intercrystalline porosity in cherts has likely been preserved since it formed because of the rigid, internal framework provided by the abundant authigenic quartz. Coupled with their relatively high TOC contents, cherts then may be important intervals of gas generation and storage in the Woodford. Where abundant, cherts may then play a significant role as source and reservoir intervals within the formation in the Anadarko Basin.

Abstract The Powder River Basin of northeast Wyoming and southeast Montana contains coal resources larger than those of any other basin of comparable size in the United States. These coal resources are developed in 16 strip mines for coal-fired power plants and for coalbed methane in more than 20,000 wells for distribution throughout the country. During this field trip, strip mining methodology and technology at the Wyodak coal mine, and operations at the nearby Wyodak power plant and in coalbed methane fields will be observed and discussed. The power plant utilizes feed coal from the mine and supplies electricity for the City of Gillette and surrounding areas. Coalbed methane development in the basin has coexisted with coal mining since the early 1980s. The same coal beds that are being mined yield gas in the subsurface, which is produced, collected, and moved to pipelines to access the interstate pipeline grid to serve the Rocky Mountains, Midwest, and California customers. Keywords: Powder River Basin, Wyoming, coal, coalbed methane, gas.

Abstract Crustal-scale channel flow numerical models support recent interpretations of Himalayan–Tibetan tectonics proposing that gravitationally driven channel flows of low-viscosity, melt-weakened, middle crust can explain both outward growth of the Tibetan Plateau and ductile extrusion of the Greater Himalayan Sequence. We broaden the numerical model investigation to explore three flow modes: homogeneous channel flow (involving laterally homogeneous crust); heterogeneous channel flow (involving laterally heterogeneous lower crust that is expelled and incorporated into the mid-crustal channel flow); and the hot fold nappes style of flow (in which mid-/lower crust is forcibly expelled outward over a lower crustal indentor to create fold nappes that are inserted into the mid-crust). The three flow modes are members of a continuum in which the homogeneous mode is driven by gravitaţional forces but requires very weak channel material. The hot fold nappe mode is driven tectonically by, for example, collision with a strong crustal indentor and can occur in crust that is subcritical for homogeneous flows. The heterogeneous mode combines tectonic and gravitationally driven flows. Preliminary results also demonstrate the existence and behaviour of mid-crustal channels during advancing and retreating dynamical mantle lithosphere subduction. An orogen temperature-magnitude (Т–M) diagram is proposed and the positions of orogens in Т–M space that may exhibit the flow modes are described, together with the characteristic positions of a range of other orogen types.

Abstract The interpretation of the Holocene evolution of the Humber Estuary has been made possible only through integrated multidisciplinary studies involving inter alia : drilling, to obtain sedimentary records of the Holocene Estuary fill; multi-element, carbon-nitrogen-sulphur and stable carbon isotope geochemistry; heavy and clay mineralogy; palaeomagnetism; radio-carbon dating; and pollen, diatom and foraminiferal studies. Eight chemostratigraphic suites and 14 palaeo-environments have been recognized. Sediment types, environments of deposition and provenance change in response to rising sea-level, showing a range from freshwater fluvial deposition of locally derived terrestrial sediment to intertidal and subtidal deposition of sediments from marine sources. The methods used are illustrated with reference to sediment cores from inner and outer estuary locations. The results show that Holocene environmental characterization is most secure when a number of different, but complementary, techniques are used. The integration of radiocarbon dates with palaeomagnetic and geochemical data improves the understanding of the presence and significance of time breaks, which is crucial to constraining sedimentation rates and material budgets.

Abstract The Holocene sequence of the Humber Estuary displays a wide range of sediment types within which the preservation of microfossils is highly variable. Its evolution has been reconstructed using a range of environmental proxies with chronological control provided by more than 90 radiocarbon dates. Results are presented of diatom analyses from three cores typical of the inner, middle and outer estuary (HMB20, HMB7 and HMB12) and of three cores that illustrate the role of organic deposits (peats) and their associated pollen (HMB13, HMB12 and the Ancholme Valley) in the definition of sea-level index points. The reconstruction of relative sea-level change shows a rapid rise in the early Holocene, followed by a reduced rate of rise in the mid-late Holocene. This reconstruction, together with information on the pre-Holocene surface and the different palaeoenvironments from the cores have been integrated within a geographical information system and then interpreted to yield a series of palaeogeographical maps of the Humber at 1000-year time slices between 8 and 3 cal. ka bp . The marine transgression progressed up the estuary after 8 cal. ka bp , reaching the inner estuary by 6 cal. ka bp . The expansion of intertidal environments probably reached its maximum around 3 cal. ka bp . Changes since 3 cal. ka bp are described using archaeological and historical records. Tidal asymmetry is a major controlling factor on the balance of sediment accretion and erosion in the estuary. Sedimentary and bathymetric evidence suggests a damped oscillation between flood and ebb asymmetry in the Humber over the Holocene period. Such a conclusion would be of great importance to estuarine managers and users since it could be used to predict the future development of the estuary.

Abstract In order to determine the processes that have governed the accumulation and erosion of sediments in the Humber Estuary (English North Sea coast) through the Holocene, the character, volume and source of sediments were studied. Eight sediment suites were identified on the basis of chemostratigraphy, lithostratigraphy and mineralogy. The locally sourced, freshwater, Basal Suite is overlain by the Newland and Butterwick Suites, deposited between c . 8 and 7.4 cal. ka bp in brackish environments behind a morainic barrier at St Andrew’s Dock, Hull. These are overlain by the largely marine, saltmarsh sediments of the Garthorpe Suite, which in turn are overlain, with erosional contact, by the channel sandflat and mudflat deposits of the Saltend, Sunk Island and Skeffling Suites. Most of the Saltend Suite is likely to have been deposited since c . 4 ka ago, whilst the Sunk Island and Skeffling Suites are likely to have been deposited since Medieval times and from the late eighteenth century onwards, respectively, as indicated by their concentrations of anthropogenic metals. On the coast, the Spurn Suite consists of sediments, associated with a spit system, which are almost entirely marine in origin. The suites show a progressive increase in marine influence; sediments of the oldest suite being entirely from the terrestrial catchment, those of the younger suites from erosion of the North Sea floor and coast. The relationships between suites show that during the last 4 ka the geomorphological evolution of the estuary has been marked by widespread erosion episodes that have led to the partial removal or redistribution of earlier deposits. By modelling the volumes of the suites it can be shown that, of the total volume of the estuarine fill (9.6 km 3 ), over half is likely to have been deposited during this period.