Abstract The Jurassic to Early Cretaceous magmatic and metallogenic evolution of the Lesser Caucasus and Eastern Pontides segment of the Central Tethyan orogenic belt is still poorly understood. This study reports an investigation about the link between ore formation and magmatic evolution in the major Gedabek porphyry-epithermal mining district, which is located in the Somkheto-Karabagh belt, Azerbaijan. Long-lasting magmatic arc evolution of ~50 m.y., from the Middle Jurassic to the Early Cretaceous, is supported by new U-Pb zircon ages between 164.3 ± 0.7 and 125.1 ± 0.5 Ma. Middle Jurassic magmatic rocks have a dominantly tholeiitic to transitional and primitive island-arc composition, whereas Late Jurassic to Early Cretaceous magmatic rocks are calc-alkaline to shoshonitic and have mature island-arc compositions. Radiogenic isotopes document a higher mantle contribution during petrogenesis of the Late Jurassic-Early Cretaceous magmatic rocks. The combined data document progressive magmatic arc maturation and crustal thickening from the Middle Jurassic to the Early Cretaceous, accompanied by slab roll-back and asthenospheric upwelling. This evolution is shared by other areas of the Somkheto-Karabagh belt and its southern extension in the Kapan block, which also host porphyry-epithermal mining districts. Muscovite and K-feldspar from a porphyry Cu-related potassic alteration assemblage at the Gedabek deposit (overprinted by a younger intermediate- to high-sulfidation epithermal system) have yielded 40Ar/39Ar ages between 140.1 ± 1.0 and 136.3 ± 0.9 Ma. Together with a previous Re-Os molybdenite age, they document formation of the porphyry-epithermal systems at the end of the long magmatic arc maturation of the Gedabek district. Although ore-forming events were diachronous along the arc, the relative timing of magmatic evolution and ore formation at Gedabek is shared by the other Late Jurassic to Early Cretaceous mining districts of the Somkheto-Karabagh belt and the Kapan block. Our study demonstrates that long arc maturation and crustal thickening has taken place along the southern Eurasian margin from a Middle Jurassic nascent arc to an Early Cretaceous evolved arc. This evolution is in line with the essential prerequisites for the genesis of porphyry-epithermal systems in orogenic belts. It also provides evidence that Middle Jurassic to Early Cretaceous magmatic fertile systems and porphyry-epithermal centers have been preserved in this belt.

Abstract This contribution reviews the metallogenic setting of the Lesser Caucasus within the framework of the complex geodynamic evolution of the Central Tethys belt during convergence and collision of the Arabia-, Eurasia-, and Gondwana-derived microplates. New rhenium-osmium molybdenite ages are also presented for several major deposits and prospects, allowing us to constrain the metallogenic evolution of the Lesser Caucasus. The hostrock lithologies, magmatic associations, deposit styles, ore controls, and metal endowment vary greatly along the Lesser Caucasus as a function of the age and tectono-magmatic distribution of the ore districts and deposits. The ore deposits and ore districts can essentially be assigned to two different evolution stages: (1) Mesozoic arc construction and evolution along the Eurasian margin, and (2) Cenozoic magmatism and tectonic evolution following Late Cretaceous accretion of Gondwana-derived microplates with the Eurasian margin. The available data suggest that during Jurassic arc construction along the Eurasian margin, i.e., the Som-kheto-Karabagh belt and the Kapan zone, the metallogenic evolution was dominated by subaqueous magmatic-hydrothermal systems, VMS-style mineralization in a fore-arc environment or along the margins of a back-arc ocean located between the Eurasian margin and Gondwana-derived terranes. This metallogenic event coincided broadly with a rearrangement of tectonic plates, resulting in steepening of the subducting plate during the Middle to Late Jurassic transition. Typical porphyry Cu and high-sulfidation epithermal systems were emplaced in the Somkheto-Karabagh belt during the Late Jurassic and the Early Cretaceous, once the arc reached a more mature stage with a thicker crust, and fertile magmas were generated by magma storage and MASH processes. During the Late Cretaceous, low-sulfidation-type epithermal deposits and transitional VMS-porphyry-epithermal systems were formed in the northern Lesser Caucasus during compression, uplift, and hinterland migration of the magmatic arc, coinciding with flattening of the subduction geometry. Late Cretaceous collision of Gondwana-derived terranes with Eurasia resulted in a rearrangement of subduction zones. Cenozoic magmatism and ore deposits stitched the collision and accretion zones. Eocene porphyry Cu-Mo deposits and associated precious metal epithermal systems were formed during subduction-related magmatism in the southernmost Lesser Caucasus. Subsequently, late Eocene-Oligocene accretion of Arabia with Eurasia and final closure of the southern branch of the Neotethys resulted in the emplacement of Neogene collision to postcollision porphyry Cu-Mo deposits along major translithospheric faults in the southernmost Lesser Caucasus. The Cretaceous and Cenozoic magmatic and metallogenic evolutions of the northern Lesser Caucasus and the Turkish Eastern Pontides are intimately linked to each other. The Cenozoic magmatism and metal-logenic setting of the southernmost Lesser Caucasus can also be traced southward into the Cenozoic Iranian Urumieh-Dokhtar and Alborz belts. However, contrasting tectonic, magmatic, and sedimentary records during the Mesozoic are consistent with the absence of any metallogenic connection between the Alborz in Iran and the southernmost Lesser Caucasus.

Abstract Auriferous quartz (±carbonate) veins in the El-Sid mine cut through the western margin of the Fawakhir granitic intrusion and the immediate country ophiolites. Gold mineralization is spatially and temporally associated with ENE–WSW fault/shear zones developed late in the deformational history of the area. Field and microscopic studies suggest two distinct ore stages; namely an early gold-Fe–As-sulphide, and a late gold-base metal mineralization. New microthermometric and Raman data suggest gold deposition as a result of a complex history of fluid immiscibly, dilution of low-salinity aqueous-carbonic fluids in the early mineralization stage, while wall-rock alteration and pressure loss precipitated Au from intermediate-salinity aqueous ore fluids during the late stage. Fluid inclusion isochoric reconstructions, combined with oxygen and sulphur isotope data, indicate conditions of 320±20 °C and 1.3±0.2 kbar for the early gold-Fe–As-sulphide mineralization, and c. 200±15 and 0.6±0.9 kbar for the late gold-Zn–Pb–Cu-sulphide stage. The clockwise evolution path in pressure-temperature space likely documents gold mineralization under post-peak metamorphic conditions. The calculated sulphide δ 34 S H2S equilibrium values −9.04‰ to –4.75‰, may refer to a variable redox state of sulphur in the ore fluids from the early to late mineralization stages. The stable isotope signature of the vein quartz and calcite suggest mixed magmatic and metamorphic fluid sources (δ 18 O H2O =+4.9‰ to +7.4‰). Unusually low δ 13 C values of calcite in the late mineralization (−13.9‰ to −14.7‰) may reflect input of magmatic CO 2 and/or oxidized carbonaceous material in the infiltrating fluid.

Abstract Precious metal epithermal, sedimentary-rock-hosted prospects constitute a new class of ore deposits recently described in the Tertiary Eastern Rhodopes of southeastern Bulgaria. The Stremtsi prospect investigated in this contribution is located in a distal location with respect to the main cluster of sedimentary-rock-hosted Ada Tepe and Rosino gold prospects of the Eastern Rhodopes. The Stremtsi prospect is hosted by a Priabonian clastic sedimentary rock sequence, overlying metamorphic rocks of the Central Rhodopean dome. The eastern part of the Stremtsi prospect contains high gold grades, and is characterized by a strongly silicified zone, including adularia and silicified dolomite blades, diagnostic for boiling conditions during ore formation in such low-sulphidation epithermal systems. The western part of the Stremtsi prospect consists of a barite, sphalerite and galena mineralization, associated with silicification, and illite and carbonate alteration. Both parts are underlain by subvertical quartz-carbonate-pyrite veins. Primary and secondary fluid inclusions, respectively, in dolomite and barite yield homogenization temperatures ranging between 90 and 247 °C. The salinity of primary inclusions in dolomite falls between 1.9 and 5.1 wt% NaCl equivalent, whereas the one of secondary fluid inclusions in barite ranges between 0.0 and 3.1 wt% NaCl equivalent. The variable homogenization temperatures reflect post-entrapment re-equilibration of the fluid inclusions, whereas the salinities were preserved and the inclusions in dolomite are interpreted in terms of dilution of a saline fluid in the western part of the Stremtsi prospect. The sulphur isotope compositions of sulphides from Stremtsi range mainly between −4 and +4‰. They are not diagnostic and can be attributed to magmatic, metamorphic, and sedimentary sources. They overlap with the main compositional range of sulphides from other sedimentary-rock-hosted epithermal systems and reveal the existence of hydrothermal fluids with common characteristics during ore formation throughout the Eastern Rhodopes. In addition, at Stremtsi, negative δ 34 S values between −42.6‰ and −8.8‰ combined with framboidal pyrite and elevated δ 34 S values of +7.0‰ to +19.5‰ support locally derived sulphur generated, respectively, by bacterial and thermochemical sulphate reduction. Modelling of O, C, and Sr isotope data of dolomite support the above described ore-forming processes. A positive correlation between δ 18 O (+12.7‰ to +19.7‰ V-SMOW) and δ 13 C (−2.8‰ to +1.5‰ V-PDB) values for dolomite from the eastern, silicified and gold-enriched zone of the Stremtsi prospect is satisfactorily modelled by boiling between 140 and 180 °C of a deeply circulating fluid characterized by δ 18 O and δ 13 C values of +5.5‰ V-SMOW and −1.5‰ V-PDB, respectively, and radiogenic strontium leached from the metamorphic basement rocks or its clastic counterparts in the Priabonian host rocks. By contrast, negative correlations of δ 18 O values (+13.4‰ to +23.3‰ V-SMOW) with δ 13 C values (−0.6‰ to −3.9‰ V-PDB) and 87 Sr/ 86 Sr ratios of dolomite from the western, barite and base metal-rich zone are adequately modelled by a shallow, low temperature (70 °C), intra-formational fluid recharged by meteoric water, which interacted with organic matter, that is, coal layers, and carbonate rocks from the Priabonian host sequence, mixing with a deep, moderate temperature (190 °C), 87 Sr-enriched fluid characterized by δ 18 O and δ 13 C values of +5.5‰ V-SMOW and −1.5‰ V-PDB, respectively. Disequilibrium conditions revealed by sulphur isotope thermometry of two galena-barite pairs yielding discrepant temperatures of 190 and 306 °C are consistent with fluid mixing. A plateau age of 37.57±0.31 Ma obtained by 40 Ar/ 39 Ar dating of adularia from Stremtsi is interpreted as a maximum age because of the saddle-shaped age spectrum. Combined with 40 Ar/ 39 Ar age data from previous studies, it reveals that the sedimentary-rock-hosted epithermal prospects constitute an independent, regional and older ore-forming hydrothermal system, distinct from the younger volcanic-rock-hosted epithermal deposits of the Bulgarian and Greek Eastern Rhodopes.