ABSTRACT This field guide highlights the Paleozoic geology of the Knoxville, Tennessee, area, framed in the context of the historic, halcyon days of Knox County’s marble industry and the railroads built to serve the area’s many limestone quarries and mills. The Three Rivers Rambler excursion train (the “Rambler”) is pulled by an 1890 “Consolidation” steam locomotive, which has been restored and is now operated by the Knoxville & Holston River Railroad Co., Inc. The Rambler route follows the north bank of the Tennessee River; passes through a sequence of Lower and Middle Ordovician carbonates, shales, and sandstones of the Knox and Chickamauga Groups; crosses the High Bridge at the confluence of the Holston and French Broad Rivers; and ends near Marbledale Quarry before returning to Knoxville. The two geologic groups are dominated by carbonates and lie in the syncline that contained most of the commercial marble that was quarried in the Knoxville area for the past 150 years. Exposures of the Holston Formation, a limestone commercially referred to as Holston [M]arble, were excavated to build the railroad ~125 years ago. It is possible to observe four of the seven formations making up the Knox and Chickamauga Groups along the route, but the outcrops are not accessible during typical railroad operations or by automobile. Arrangements were made for a field trip during the 2018 Geological Society of America Southeastern Section meeting, and this guide provides details for four selected exposures between Knoxville and the Forks of the River Marble District, with three optional stops. Only during the field trip, passengers will be able to disembark the train to examine carbonate and shale outcrops, structures, and discuss facies relationships of the foreland basin bryozoan reef deposits along the western flank of the Taconic (Sevier) foredeep. In addition to the local geology, this field guide describes the key role of railroads in the development of the Knox County marble industry, the history of what is today the Knoxville & Holston River Railroad, a corporate descendent of the 1887 Knoxville Belt Railroad Company, and the Tennessee Marble industry.

ABSTRACT Limestone provides many lessons about Earth’s systems (geosphere, hydrosphere, atmosphere, cryosphere, and biosphere) through the geochemical, hydrologic, ­tectonic, and rock cycles. Limestone is ideal for teaching cross-disciplinary STEM (science, technology, engineering, and math) subjects of biology, chemistry, and physics, along with history and culture through its uses in society as a valuable economic resource. Carbon and calcium chemistry is part of the everyday environment, and limestone deposits around the world are important archives of biotic and abiotic Earth history. Limestones provide data for reconstructing global climate change and provide important “documents” for recreating Earth’s changing biodiversity throughout geologic time, including human history. Limestone precipitation is Earth’s antidote to global warming. Limestone is volumetrically one of our most valuable natural resources with a variety of uses, as well as frequently involved with natural and human-induced environmental hazards. Limestone is a common commodity readily available to all teachers and students, thus it is the ideal material for ­budget-strapped STEM educators to use to address Next Generation Science Standards. Some uses include: using fossils to develop concepts of paleoecology and evolution; using limestones to reconstruct ancient geography (including plate tectonics); and addressing the relevance of limestone to our society as a building stone, for its medical uses, and as a potential hazard associated with karst (caves and sinkholes). Five cross-disciplinary content concepts are addressed to aid teachers in preparing limestone-centric instruction: (1) enhancement of the understanding of chemical reactions and geochemical cycles, (2) biological evolution, (3) physics applications, (4) economic and environmental impacts, and (5) historical and fine arts’ use of limestone.

ABSTRACT The geology of Great Smoky Mountains National Park (GRSM) in Tennessee and North Carolina is dominated by siliciclastics and metamorphic strata. However, in the western portion of GRSM, a series of carbonate fensters (windows) expose the Lower Ordovician–age section of the Knox Group, a series of dolomite and limestone units that are partially marbleized as a result of contact metamorphism from the Great Smoky fault. The fensters create opportunities for allogenic recharge to occur at points along the contact of the surrounding insoluble strata with the underlying soluble carbonates. The combination of chemically aggressive surface recharge and vertical relief has resulted in the formation of deep caves, many of which have active streams and water resources. Though the karst is limited in extent and the number of caves is fairly small, the significance of the resources is substantial, with several of the caves in the area over 150 m in depth and at least two being major bat hibernacula. In 2017, the U.S. Geological Survey (USGS) began a study to better understand the hydrologic behavior of these karst systems through hydrologic and geochemical monitoring, groundwater tracing using fluorescent dyes, and seepage runs. Stage and water-quality instrumentation was installed in two caves in GRSM, the main stream of Bull Cave, and in a sump pool in Whiteoak Blowhole, at 173 m and 70 m below land surface, respectively. Following setup of the cave sites, dye injections were conducted to determine discharge points for four of the deep cave systems on Rich Mountain and Turkeypen ridge. Results show water in these systems has an extremely rapid travel time, with tracers detected from caves to springs in less than 24 h for each of the systems. This field guide describes the complex geology, regional hydrogeology, and unique landscape characterized by high-gradient subterranean streams, carbonate fensters, and deep caves of the GRSM karst.

ABSTRACT Hotspots represent the ephemeral introduction of nutrients into an environment, and occur in both the modern and geologic past. The annual deposition of deciduous leaves in temperate forests, tree falls, animal excrement, and vertebrate carcass deposition all result in the pulsed introduction of nutrients to an ecosystem. Hotspots are critical for providing limiting nutrients, including nitrogen and carbon, to be incorporated into soil microbial biomass and plant biomass. For vertebrate ­carcasses, following the release of labile compounds from soft tissues, bones are often left behind, and provide a more recalcitrant reservoir of organic carbon and nitrogen, phosphorus, calcium, and, in some environments, water, for micro- and macro-fauna. Taphonomy—the physical, chemical, and biological processes following plant or animal death—studied in modern systems can be used to interpret hotspot processes operating in the past. East Tennessee is a region where studies of modern and fossil vertebrate hotspots have provided new insights into taphonomy. This guide describes two hotspot localities in east Tennessee—the Miocene-aged Gray Fossil Site in Gray, Tennessee, and the Anthropology Research Facility (“the Body Farm”) at the University of Tennessee, Knoxville, a human decomposition experimental site. The goal of this interdisciplinary field guide is to provide a view of nutrient hotspots from their formation in the modern to their preservation over geologic time.

ABSTRACT The Flynn Creek impact structure was originally recognized in 1968 by David Roddy as one of the original six confirmed impact structures on Earth. The Flynn Creek impact structure is also the first recognized marine-target impact structure. Exposure at Flynn Creek varies, as there is no obvious rim and the geological map of the area does not look like a crater. But, there is an impact breccia unit dominated by two classes of breccia—the lower, chaotic, slump breccia and the upper graded resurge breccia. The post-impact unit is Chattanooga Shale, of which one facies is present only in the crater itself. Participants will visit historical outcrops identified by Roddy, including both the breccia units and the central uplift. New results from ongoing reinvestigations of a drill core from Flynn Creek, as well as insight from other marine-target impact structures in the southeast, will add to lively discussions.

ABSTRACT This field guide describes three accessible sites along the Dandridge-Vonore fault zone in the Eastern Tennessee seismic zone. These sites reveal bedrock faulted against Quaternary river sediments, including (1) a thrust fault on the Little River near Alcoa, Tennessee; (2) a series of thrust faults exposed in a drainage ditch that thrust Conasauga Shale against Quaternary colluvium in the footwall; and (3) a normal fault at Tellico Lake near Vonore, Tennessee, with Quaternary sediments faulted against Conasauga Shale.

ABSTRACT This guide explores relationships among macroscale folds, mesoscale structures, the Nashville dome, and an inferred Precambrian or Cambrian rift in the basement beneath the dome. The Nashville dome, central Tennessee, is an ~12,000 km 2 north-northeast–trending, elliptical cratonic uplift. A published crustal density model shows that a previously undescribed Precambrian or Cambrian rift, herein named the Nashville rift, probably runs from northwestern Alabama through the Nashville dome to southern Kentucky. Within the Nashville dome, macroscale folds and mesoscale structures of the Stones River and Harpeth River fault zones have been interpreted previously as the surface manifestation of subsurface normal faults. This road guide describes two previously undescribed inferred subsurface fault zones: the Marshall Knobs fault zone and the Northern Highland Rim fault zone. The Marshall Knobs fault zone, which is ~16.3 km long, is associated with ~35 m of structural relief, trends east-southeast, is down on the north side, and is inside the geophysically defined rift. The Northern Highland Rim fault zone consists of east-northeast–­striking minor normal and reverse faults and a minor strike-slip fault exposed above the western margin of the geophysically defined rift. The authors hypothesize that the Northern Highland Rim fault zone may be the surface manifestation of the subsurface continuation of a macroscale fault previously mapped at the surface 25 km to the southwest. All of the inferred faults fit into a tectonic model in which they originally formed within a rift and later reactivated, accommodating extension of the uppermost crust during uplift of the Nashville dome.

ABSTRACT The eastern Great Smoky Mountains basement complex consists of the following components: (1) ca. 1350–1325 Ma orthogneiss and mafic xenoliths that represent some of the oldest crust in Appalachian Grenville massifs (similar to “pre-Grenville” basement components in the Adirondack, Green Mountain, Hudson Highland, and Shenandoah massifs); (2) ca. 1150 Ma augen orthogneisses and granitic orthogneisses correlating with the Shawinigan phase of Grenville magmatism; and (3) paragneisses (cover rocks) that have either pre- or syn-Grenville (i.e., Mesoproterozoic) versus post-Grenville (Neoproterozoic) depositional ages, and that experienced Taconian metamorphism and migmatization. Mesoproterozoic paragneisses contain major zircon age modes that require a component of Proterozoic crust in the source region. The Neoproterozoic paragneisses exhibit the archetypical “Grenville doublet” in detrital zircon age distributions that matches the age distribution of Ottawan and Shawinigan magmatic/metamorphic events in eastern Laurentia. Most zircon U-Pb age systematics exhibit variable lead loss interpreted to result from high-grade Taconian (ca. 450 Ma) regional metamorphism and migmatization. Neodymium mantle model ages (T DM) for ortho- and paragneisses range from 1.8 to 1.6 Ga, indicating that all rocks were derived from recycling of Proterozoic crust (i.e., they are not juvenile), which is consistent with Proterozoic detrital zircon ages in pre- to syn-Grenville paragneisses. Lead isotope compositions confirm the presence of an exotic (Amazonian) crustal component in the source region for the protoliths of the pre-Grenville orthogneisses and xenoliths, and that this exotic component was incorporated to varying degrees in the evolution of the basement complex. The oldest age component may represent an Amazonian pre-Grenville analog to the ca. 1.35 Ga native Laurentian crust present in Adirondack and northern Appalachian basement massifs.

ABSTRACT The southern Appalachian orogen is a Paleozoic accretionary-collisional orogen that formed as the result of three Paleozoic orogenies, Taconic, Acadian and Neoacadian, and Alleghanian orogenies. The Blue Ridge–Piedmont megathrust sheet exposes various crystalline terranes of the Blue Ridge and Inner Piedmont that record the different effects of these orogenies. The western Blue Ridge is the Neoproterozoic to Ordovician Laurentian margin. Constructed on Mesoproterozoic basement, 1.2–1.0 Ga, the western Blue Ridge transitions from two rifting events at ca. 750 Ma and ca. 565 Ma to an Early Cambrian passive margin and then carbonate bank. The Hayesville fault marks the Taconic suture and separates the western Blue Ridge from distal peri-Laurentian terranes of the central and eastern Blue Ridge, which are the Cartoogechaye, Cowrock, Dahlonega gold belt, and Tugaloo terranes. The central and eastern Blue Ridge terranes are dominantly clastic in composition, intruded by Ordovician to Mississippian granitoids, and contain ultramafic and mafic rocks, suggesting deposition on oceanic crust. These terranes accreted to the western Blue Ridge during the Taconic orogeny at 462–448 Ma, resulting in metamorphism dated with SHRIMP (sensitive high-resolution ion microprobe) U-Pb ages of metamorphic zircon. The Inner Piedmont, which is separated from the Blue Ridge by the Brevard fault zone, experienced upper amphibolite, sillimanite I and higher-grade ­metamorphism during the Acadian and Neoacadian orogenies, 395–345 Ma. These events also affected the eastern Blue Ridge, and parts of the western Blue Ridge. The Acadian and Neoacadian orogeny is the result of the oblique collision and accretion of the peri-Gondwanan Carolina superterrane overriding the Inner Piedmont. During this collision, the Inner Piedmont was a forced mid-crustal orogenic channel that flowed NW-, W-, and SW-directed from underneath the Carolina superterrane. The Alleghanian orogeny thrust these terranes northwestward as part of the Blue Ridge–Piedmont megathrust sheet during the collision of Gondwana (Africa) and the formation of Pangea.

ABSTRACT The southern Appalachian western Blue Ridge preserves a Mesoproterozoic and mid-Paleozoic basement and Neoproterozoic to Ordovician rift-to-drift sequence that is metamorphosed up to sillimanite grade and dissected by northwest-directed thrust faults resulting from several Paleozoic orogenic events. Despite a number of persistent controversies regarding the age of some western Blue Ridge units, and the nature and extent of multiple Paleozoic deformational/metamorphic events, synthesis of several multidisciplinary data sets (detailed geologic mapping, geochronology and thermochronology, stable-isotope chemostratigraphy) suggests that the western Blue Ridge likely records the effects of two discrete orogenic events. The earlier Taconic (470–440 Ma) event involved a progression from open folding and emplacement of the Greenbrier–Rabbit Creek and Dunn Creek thrust sheets as a foreland fold-and-thrust to low-grade hinterland system (D 1A), followed by deep burial (>31 km), pervasive folding of the earlier-formed fault surfaces, and widespread Barrovian metamorphism (D 1B). Because this high-grade (D 1B) metamorphic event is recorded in Ordovician Mineral Bluff Group turbidites, this unit must have been deposited prior to peak orogenesis, possibly as a foreland basin or wedge-top unit in front of and/or above the developing fold-and-thrust belt. The later Alleghanian (325–265 Ma) event involved widespread northwest-directed brittle thrusting and folding related to emplacement of the Great Smoky thrust sheet (D 2 ; hanging wall of the Blue Ridge– Piedmont thrust). Mid-Paleozoic 40 Ar/ 39 Ar muscovite ages from western Blue Ridge samples likely record post-Taconic cooling (hornblende and some muscovite 40 Ar/ 39 Ar ages) and/or Alleghanian thrust-related exhumation and cooling (ca. 325 Ma muscovite 40 Ar/ 39 Ar and 300–270 Ma zircon fission-track ages), as opposed to resulting from a discrete Neoacadian thermal-deformational event. The lack of evidence for a discrete Neoacadian event further implies that all deformation recorded in the Silurian–Mississippian(?) Maggies Mill–Citico Formation must be Alleghanian. We interpret this structurally isolated sequence to have been derived from the footwall of the Great Smoky fault as an orphan slice that was subsequently breached through the Great Smoky hanging wall along the out-of-sequence Maggies Mill thrust.

ABSTRACT Ion microprobe U-Pb zircon rim ages from 39 samples from across the accreted terranes of the central Blue Ridge, eastward across the Inner Piedmont, delimit the timing and spatial extent of superposed metamorphism in the southern Appalachian orogen. Metamorphic zircon rims are 10–40 µm wide, mostly unzoned, and dark gray to black or bright white in cathodoluminescence, and truncate and/or embay interior oscillatory zoning. Black unzoned and rounded or ovoid-shaped metamorphic zircon morphologies also occur. Th/U values range from 0.01 to 1.4, with the majority of ratios less than 0.1. Results of 206 Pb/ 238 U ages, ±2% discordant, range from 481 to 305 Ma. Clustering within these data reveals that the Blue Ridge and Inner Piedmont terranes were affected by three tectonothermal events: (1) 462–448 Ma (Taconic); (2) 395–340 Ma (Acadian and Neoacadian); and (3) 335–322 Ma, related to the early phase of the Alleghanian orogeny. By combining zircon rim ages with metamorphic isograds and other published isotopic ages, we identify the thermal architecture of the southern Appalachian orogen: juxtaposed and superposed metamorphic domains have younger ages to the east related to the marginward addition of terranes, and these domains can serve as a proxy to delimit terrane accretion. Most 462–448 Ma ages occur in the western and central Blue Ridge and define a continuous progression from greenschist to granulite facies that identifies the intact Taconic core. The extent of 462–448 Ma metamorphism indicates that the central Blue Ridge and Tugaloo terranes were accreted to the western Blue Ridge during the Taconic orogeny. Zircon rim ages in the Inner Piedmont span almost 100 m.y., with peaks at 395–385, 376–340, and 335–322 Ma, and delimit the Acadian-Neoacadian and Alleghanian metamorphic core. The timing and distribution of metamorphism in the Inner Piedmont are consistent with the Devonian to Mississippian oblique collision of the Carolina superterrane, followed by an early phase of Alleghanian metamorphism at 335–322 Ma (temperature >500 °C). The eastern Blue Ridge contains evidence of three possible tectonothermal events: ~460 Ma, 376–340 Ma, and ~335 Ma. All of the crystalline terranes of the Blue Ridge–Piedmont megathrust sheet were affected by Alleghanian metamorphism and deformation.

ABSTRACT The timing and kinematics of Paleozoic peri-Gondwanan terrane accretion along the southern and central Appalachian margin have long been debated. The Silurian–Devonian Concord plutonic suite intruded the western flank of the Carolina superterrane, suggesting east-dipping subduction of ocean crust beneath the Carolina superterrane just prior to accretion, based on Devonian–Mississippian plutonism and metamorphism in the adjacent Laurentian terranes. Geochemical and isotopic data support a subduction-related origin for the Concord plutonic suite, and our geochronologic data reveal the main pulse of plutonism occurred ca. 405 Ma. Our new sensitive high-resolution ion microprobe (SHRIMP) geochronologic data identify a suite of mafic plutons from the Carolinas to central Georgia that also belong to the Concord suite. These gabbros have U-Pb zircon ages of 372 ± 2 Ma (Gladesville contact aureole), 386 ± 5.7 Ma (Buffalo), 403.8 ± 3.7 Ma (Highway 200), 404.9 ± 6.9 Ma (Mecklenburg), and 416 ± 6.9 Ma (Calhoun Falls). The Ogden Gabbro has a U-Pb age from baddeleyite of 411.91 ± 0.25 Ma. In this study, we identified a previously unrecognized Alleghanian (Pennsylvanian) gabbro suite with U-Pb zircon ages of 308.2 ± 6.2 Ma (Farmington), 311 ± 6.2 Ma (Dutchman’s Creek), and 311 ± 6.5 Ma (Mount Carmel). These gabbros should henceforth not be included in the Concord suite. The ages of Concord suite plutons slightly predate the main phase of plutonism in the Cat Square terrane to the west, which we suggest represents the product of B-type subduction of ocean crust beneath the Carolina superterrane between 415 and 400 Ma. Arc-related magmatism terminated because of the switch to A-type subduction of the eastern Laurentian margin. Prograde upper-amphibolite- to granulite-facies metamorphism, wholesale migmatization, and extensive anatectic plutonism in the eastern Inner Piedmont occurred from Late Devonian into Mississippian time, shortly after cessation of Concord plutonic suite plutonism, which also supports this proposed model. These data, combined with the timing and geometry of foreland clastic wedges, provide compelling support for Devonian–Mississippian accretion of the Carolina superterrane via dextral transpressive obduction above the eastern Laurentian margin.

ABSTRACT The Brevard fault zone is one of the largest faults in the Appalachians, extending from Alabama to Virginia. It had a very complex history of movement and reactivation, with three movement episodes: (1) Acadian-Neoacadian (403–345 Ma) movement accompanying the thermal peak of metamorphism and deformation with dextral, southwest-directed emplacement of the Inner Piedmont; (2) ductile dextral reactivation during the early Alleghanian (~280 Ma) under lower-greenschist-facies conditions; and (3) brittle dip-slip reactivation during the late Alleghanian (260 Ma?). The Brevard is comparable to other large faults with polyphase movement in other orogens worldwide, for example, the Periadriatic line in the Alps. Two types of far-traveled, fault-bounded horses have been identified in the Brevard fault zone in the Carolinas: (1) metasedimentary and granitoid horses located along the southeastern margin of the Alleghanian retrogressive ductile dextral Brevard fault zone in North and South Carolina; and (2) limestone/dolostone horses located along the brittle, late Alleghanian Rosman thrust, the contact between Blue Ridge and Brevard fault zone rocks in North and South Carolina. Field, stratigraphic, petrographic, and Sr-isotope data suggest the carbonate horses may be derived from Valley and Ridge carbonates in the Blue Ridge–Piedmont megathrust sheet footwall. The horses of metasedimentary and granitoid rocks occur along faults that cut klippen of the southwest-directed Inner Piedmont Acadian-Neoacadian Alto (Six Mile) allochthon. New laser ablation– inductively coupled plasma–mass spectrometry (LA-ICP-MS) U-Pb zircon analyses from the metasedimentary mylonite component yield a detrital zircon suite dominated by 600 and 500 Ma zircons, and a second zircon population ranging from 2100 to 1300 Ma, with essentially no Grenvillian zircons, suggesting a peri-Gondwanan provenance. The granitoid component has a sensitive high-resolution ion microprobe (SHRIMP) age of 421 ± 14 Ma, similar to the ~430 Ma plutonic suite in northern Virginia and Maryland—a prominent component of the Cat Square terrane detrital zircon suite in the Carolinas. Peri-Gondwanan Neoproterozoic to Cambrian Avalon–Carolina superterrane rocks are nowhere in contact with the Brevard fault zone at present erosion level. While these far-traveled metasedimentary and granitoid horses may have originated several hundred kilometers farther northeast in the central Appalachians, they could alternatively be remnants of Avalon–Carolina superterrane rocks that once formed the tectonic lid of the southwest-directed Neoacadian–early Alleghanian (Late Devonian–early Mississippian) orogenic channel formed during north-to-south zippered accretion of Avalon–Carolina. The remnant fossil subduction zone survives as the central Piedmont suture. Avalon–Carolina terrane rocks would have once covered the Inner Piedmont (and easternmost Blue Ridge) to depths of >20 km, and have since been eroded. Data from these two suites of horses provide additional insights into the mid- to late Paleozoic history and kinematics of the Brevard fault zone, Inner Piedmont, and Avalon–Carolina superterrane. It was six men of Indostan To learning much inclined, Who went to see the Elephant (Though all of them were blind), That each by observation Might satisfy his mind. … And so these men of Indostan Disputed loud and long, Each in his own opinion Exceeding stiff and strong, Though each was partly in the right, And all were in the wrong. —John Godfrey Saxe (1816–1887) “The Blind Men and the Elephant”

Abstract The linear Sequatchie anticline interrupts the continuity of the Appalachian Cumberland Plateau from east-Central Tennessee southward into Alabama to near the latitude of Birmingham. The anticline was breached by erosion during the late Tertiary, thereby producing Sequatchie Valley and revealing the details of its geologic structure—the anticline is thrust faulted on its northwest flank, and that thrust is now known to be part of a tectonic ramp that extends upward from the Lower Cambrian Rome Formation to flatten to the northwest into a higher detachment within the weak shale and coal beds in the Pennsylvanian deltaic sedimentary rocks. The same thrust emerges to the northwest as the Cumberland Plateau overthrust, and appears to be a mirror-image analog of the Pine Mountain fault located in the Plateau to the northeast. The purpose of this one-day field trip is to (1) provide an introduction to the Sequatchie Valley structure and the Mississippian-Pennsylvanian strata that form the crest and limbs of the anticline, and (2) gain some insight into the evolution of the topography in the southern Cumberland Plateau as the valley was exhumed during the late Tertiary. The first field trip stop is along Tennessee State Route (SR) 8 northwest of Dunlap to examine well-exposed rocks and structures along the upper detachment where it propagates along coal and shale beds in the Pennsylvanian section. The second field trip stop is up the southeast flank of the anticline along Tennessee SR-111 east of Dunlap to review the nearly continuous exposure of the Paleozoic section from the Devonian-Mississippian Chattanooga Shale to the top of the Mississippian.