Abstract Excellent coastal exposures of strongly folded and faulted Cambrian rocks occur around the St David's Peninsula of SW Wales. The best sections occur in the St David's Anticline, in the vicinity of St David's itself, and these have been the subject of scientific study since the mid-Nineteenth Century. Based on this early work, a quadripartite lithostratigraphical scheme emerged, comprising the Caerfai, Solva and Menevian groups and the Lingula Flags Formation. However, this scheme is unnecessarily complex, and sometimes unworkable in practice. The Caerfai Group is here redefined to embrace much of the Solva Group of earlier authors, while the upper part of the Solva Group, the Menevian Group and Lingula Flags are combined in the new Porth-y-rhaw Group. Traditionally, all these Cambrian rocks have been thought of as being deposited on a stable cratonic platform, but there is substantial evidence of tectonic influences on sedimentation, particularly in the older part of the succession. The Cambrian was originally recognized and defined in North Wales. There, as in many other areas, it became common practice to divide the period into three parts, but more recent work favours a four-fold chronostratigraphical subdivision. The oldest part of the Cambrian is missing in South Wales, but rocks of Terreneuvian, C2, C3 and Furongian age are all represented. Age-diagnostic fossils are few in the older part of the local succession. Trace fossils low in the Caerfai Group indicate the avalonensis Ichnozone or Teichichnus Interval of the Terreneuvian, while a radiometric date of early C2 (CS3) age has been obtained higher up. Trilobite faunas occur more commonly in the higher parts of the Caerfai Group and in the Porth-y-rhaw Group, and these facilitate international correlation of the C3 (CS5) to Furongian (Paibian) parts of the succession. Trilobites characteristic of the oelandicus Biosuperzone and the gibbus , fissus , parvifrons , punctuosus , pisiformis and Olenus biozones all occur.

Abstract The classic Cambrian succession of SW Wales comprises a succession of clastic rocks some 1250 m thick that make up part of the Dyfed Supergroup. The existing lithostratigraphical framework owes much to the Nineteenth Century researchers, with relatively little detailed work having been published since. We here present a detailed, rationalized and revised lithostratigraphy for the Cambrian part of the Dyfed Supergroup of the area. Where possible and appropriate, we have retained original and well-known names for formations and other units in harmony with current usage. However, the recognition of four lithostratigraphical groups is overly complex and sometimes unworkable, and a two-fold subdivision is proposed instead. The Caerfai and much of the Lower and Middle Solva groups of earlier usage comprise conglomerates, pebbly sandstones and brightly coloured fine- to coarse-grained sandstones: all are here combined into a revised Caerfai Group. By excluding the silt-dominated Upper Solva division, the Caerfai Group is readily divided into lower and upper parts comprising conglomerates and/or pebbly sandstones, with sandstones and siltstones dominant in between. These rocks comprise the Ogof Golchfa (new), St Non's, Caerfai Bay, Caer Bwdy Bay, Newgale (new) and Porth Clais (new) formations. The following members (all new) are recognized within the Newgale Formation: the Trwyncynddeiriog, Pen-y-Cyfrwy and Cwm Mawr members. Ichnofossils from the upper part of the Ogof Golchfa Formation suggest that Cambrian deposition in the area began in Unnamed Cambrian Series 2 (C2) times. Body fossils and radiometric dating show that the Caerfai Bay to Porth Clais formations span the interval from Cambrian Series 2, Unnamed Cambrian Stage 3 (such stages are denoted by CS3, CS4 etc. below), probably to the Ptychagnostus gibbus Biozone (CS5). The former Upper Solva Group, Menevian Group and Lingula Flags comprise the newly erected Porth-y-rhaw Group, a 687 m-thick unit of fine sandstones, siltstones and mudstones, within which a further five formations are recognized. These are the Whitesands Bay, Menevia, Aber Llong (all new), Ogof Velvet (revised) and Treffgarne Bridge formations. The Porth-y-rhaw Group spans the Tomagnostus fissus Biozone (C3, Drumian) to the Olenus cataractes Biosubzone (Furongian, Paibian). The overall two-fold subdivision of the Cambrian part of the Dyfed Supergroup in the area accords broadly with the first lithostratigraphical scheme proposed for the area, and is comparable with the separation of the Harlech Grits and Mawddach groups in northern and central Wales. The oldest part of the Caerfai Group formed in a tectonically active context and records a transition from alluvial fan deposits, through braided stream environments, into transgressive nearshore marine sandstones. These sediments were derived from the west, and as well as locally-sourced material, include lithic clasts and grains derived from a presumed southwestwards extension of the Monian Composite Terrane. Above lie sedimentary deposits formed under a wide range of conditions, ranging from tidally-influenced to turbidites. Further evidence of active tectonism is found in the easterly-derived fan-delta sedimentary deposits of the higher part of the Caerfai Group and lower part of the Porth-y-rhaw Group. Deposition of the latter began with fine-grained turbidites deposited in a mid–outer shelf setting. These pass up first into hemipelagites, then into sedimentary rocks deposited on a storm-dominated shelf, and finally a very extensive shallow subaqueous delta platform formed in a passive margin setting.

Abstract The Dyfed Supergroup of SW Wales ranges from Terreneuvian to Furongian in age and represents a prolonged and nearly continuous phase of siliciclastic sedimentation on the southern margin of the Cambrian Welsh Basin. The lower 564 m of the Supergroup are included in an extended Caerfai Group (six formations), embracing strata previously assigned to the Solva Group. Predominantly arenaceous, the Caerfai Group has important units of conglomerate and pebbly sandstone at its base, middle and top. The Caerfai Group is overlain by 687 m of mainly argillaceous sedimentary deposits of the Porth-y-rhaw Group (five formations), a newly erected unit that includes strata previously assigned to the ‘Menevian Group’ and ‘Lingula Flags’. This two-fold division of the Dyfed Supergroup is comparable with the distinction of the laterally equivalent Harlech Grits and Mawddach groups exposed around the Harlech Dome in North Wales. High resolution sequence-stratigraphical techniques, constrained by biostratigraphical data wherever possible, are applied to the Dyfed Supergroup across southern Britain: the revised lithostratigraphy is thereby integrated with a slightly modified version of the Avalonian chronostratigraphy initially developed for the western Avalonian successions of maritime Canada. Sequences 1 and 2 are not recognized in the Dyfed supergroup of SW Wales, reflecting the inner platform setting of the area. Those sequences are represented in North Wales however, which was situated on the outer platform. The relative ease with which the Cambrian successions of southern Britain can be incorporated into the general Avalonian framework reflects the shared epeirogenic history, sediment sources and accumulation history of a microcontinent unified by early Cambrian times. The gross lithological similarities that exist between Cambrian successions across Avalonia, and between SW Wales and North Wales in particular, are better understood when basin chronostratigraphy is placed within a sequence stratigraphic framework defined by systems tracts. This is particularly evident during Unnamed Cambrian Series 3 (C3) and Furongian times, when clear systems links are demonstrated between paralic depositional environments in SW Wales and deeper basin turbidites in North Wales. Sequences 3–7 (Terreneuvian–C3) in the Welsh Basin and its hinterland were dominated by siliciclastic deposition on an epeirogenically active platform. An extensional rift-like tectonic regime is proposed, where elongate basins dominated by mudstone deposition have time equivalents formed on areas of apparent uplift that were probably tilt-block highs. Local accumulation history, the development of regional unconformities, the extent of marine onlap, and the secular succession of lithofacies were controlled principally by phases of fault-accommodated subsidence along the NE-trending lineaments that bounded these basins and their intervening horsts or platforms. In southern Britain, movements first along the Menai Straits Fault System then the Welsh Borderlands Fault System, both of which are terrane boundaries, were responsible for the dominantly coarse-grained arenaceous sedimentation of pre-Drumian times. In the Welsh Basin, this is highlighted by a change in sediment source from the Monian Superterrane to the Wrekin Terrane. A rapid switch from marginal to inner platform source areas accompanied a major phase of tectonic reorganization of the Avalonian Superterrane during the development of the boundary between sequences 3 and 4. Although the role of secular variations in eustatic sea level as a control on sequence development and architecture has been dismissed previously, prominent lowstands such as those recorded during the basal Ptychagnostus gibbus Biozone, ‘ Solenopleura ’ brachymetopa Biozone (mid- Paradoxides forchhammeri Biosuperzone), and the upper part of the forchhammeri Biosuperzone also influenced the depositional sequence stratigraphy. The broad subdivision of Cambrian Avalonian stratigraphy into tectonically active and passive phases of sedimentation allows two megasequences to be distinguished. Megasequence 1 (sequences 1–7) represents the transform termination of Avalonian subduction following oblique convergence, and the accretion of island arcs onto the northern periphery of Gondwana. Under transpressional regimes, late Precambrian arc-related basins were inverted and recycled into pull-apart successor basins. Initially, the margins of these were dominated by alluvial fans and coarse-grained fan-deltas built by flood-generated sediment dispersal processes. In the later transform stage of Cadomian–Avalonian orogenesis, there was a switch to sediment supplied from highlands to the east. Sequence 8, represented in Pembrokeshire by the Aber Llong and Ogof Velvet formations, lies at the base of Megasequence 2 (late C3–early Ordovician). Excellent sections occur through these formations and their equivalents in North Wales, and their interpretation significantly improves understanding of younger Cambrian sedimentary basins in Avalonia. These successions reflect passive margin sedimentation and the culmination of the Avalonian–Cadomian orogenic cycle. Deposition occurred in part of a subaqueous delta platform at the mouth of a huge river system that drained a substantial part of West Gondwana, with Avalonia acting as a sink for vast quantities of fine-grained sediment. Secular variations in eustatic sea level and/or sediment supply, rather than active tectonism, were the main mechanisms controlling sequence architecture and depositional environments at this time.

Abstract This Memoir reviews, revises and interprets the biostratigraphy, lithostratigraphy, process sedimentology, palaeoenvironments and sequence stratigraphy of the classic Cambrian succession of SW Wales. This 1250 m thick clastic sedimentary succession, of Terreneuvian to Furongian age, was deposited in environments ranging from alluvial fan to mid–outer shelf. Two lithostratigraphical groups are distinguished, each comprising six formations; where possible and appropriate, original and well-known names are retained in harmony with current usage. High-resolution sequence-stratigraphical techniques, constrained by biostratigraphical data whenever possible, allow the revised lithostratigraphy to be integrated with the western Avalonian chronostratigraphy developed in maritime Canada. A twofold subdivision is recognized. Megasequence 1 (sequences 3–7) spans the Terreneuvian, C2 and much of C3, with deposition occurring in an extensional rift-like regime on an epeirogenically active platform. Sequence 8 lies at the base of Megasequence 2, which extends from late C3 into the early Ordovician, and represents passive margin sedimentation.

Abstract Organic-rich shale contains significant amounts of gas held within fractures and micropores and adsorbed onto organic matter. In the USA shale gas extracted from regionally extensive units such as the Barnett Shale currently accounts for 6% of gas production and is likely to reach 30% by 2015. Shale gas prospectivity is controlled by the amount and type of organic matter held in the shale, its thermal maturity, burial history, microporosity and fracture spacing and orientation. Potential targets range in age from Cambrian to the late Jurassic, within the main UK organic-rich black shales: younger shales have been excluded because they have not reached the gas window, but they may possess a biogenic gas play. A geographic information system, showing the distribution of potential reservoir units, has been created combining information on hydrocarbon shows, thermal maturity, fracture orientation, gas composition, and isotope data to identify potentially prospective areas for shale gas. Some of these data are shown as graphs and maps, but crucial data is lacking because earlier exploration concentrated on conventional reservoirs. The prospects include Lower Palaeozoic shale basins on the Midland Microcraton (a high risk because no conventional gas has been proved in this play), Mississippian shales in the Pennine Basin (the best prospect associated with conventional fields and high maturity), Pennsylvanian shales in the Stainmore and Northumberland Basin system (high risk because no conventional gas discoveries exist) and Jurassic shales in Wessex and Weald basins (small conventional fields signify potential here).

Abstract Large tracts of the NW European continental shelf and Atlantic margin have experienced kilometre-scale exhumation during the Cenozoic, the timing and causes of which are debated. There is particular uncertainty about the exhumation history of the Irish Sea basin system, Western UK, which has been suggested to be a focal point of Cenozoic exhumation across the NW European continental shelf. Many studies have attributed the exhumation of this region to processes associated with the early Palaeogene initiation of the Iceland Plume, whilst the magnitude and causes of Neogene exhumation have attracted little attention. However, the sedimentary basins of the southern Irish Sea contain a mid–late Cenozoic sedimentary succession up to 1.5 km in thickness, the analysis of which should permit the contributions of Palaeogene and Neogene events to the Cenozoic exhumation of this region to be separated. In this paper, an analysis of the palaeothermal, mechanical and structural properties of the Cenozoic succession is presented with the aim of quantifying the timing and magnitude of Neogene exhumation, and identifying its ultimate causes. Synthesis of an extensive apatite fission-track analysis (AFTA), vitrinite reflectance (VR) and compaction (sonic velocity and density log-derived porosities) database shows that the preserved Cenozoic sediments in the southern Irish Sea were more deeply buried by up to 1.5 km of additional section prior to exhumation which began between 20 and 15 Ma. Maximum burial depths of the preserved sedimentary succession in the St George’s Channel Basin were reached during mid–late Cenozoic times meaning that no evidence for early Palaeogene exhumation is preserved whereas AFTA data from the Mochras borehole (onshore NW Wales) show that early Palaeogene cooling (i.e. exhumation) at this location was not significant. Seismic reflection data indicate that compressional shortening was the principal driving mechanism for the Neogene exhumation of the southern Irish Sea. Coeval Neogene shortening and exhumation is observed in several sedimentary basins around the British Isles, including those along the UK Atlantic margin. This suggests that the forces responsible for the deformation and exhumation of the margin may also be responsible for the generation of kilometre-scale exhumation in an intraplate sedimentary basin system located >1000 km from the most proximal plate boundary. The results presented here show that compressional deformation has made an important contribution to the Neogene exhumation of the NW European continental shelf.

Abstract Uranium-series isotopes provide important constraints on the timescale of magma differentiation and this can be used to identify where in the crust and silicic magmas acquire their geochemical characteristics. Timescales of differentiation can be inferred from the observed co-variations of U-series disequilibria with differentiation indexes. When crustal assimilation of secular equilibrium material is involved, inferred timescales will generally decrease. In turn, they will increase if periodical recharge (>20 wt% relative volume) of the magma body occurs. If crustal assimilation and magma recharge occur concurrently, inferred timescales for differentiation can be similar to that of closed system differentiation. We illustrate the approach with data from Mount St Helens which suggest that dacitic compositions are produced in c . 2000 years. Combining this with recent evidence for an important role for amphibole fractionation suggests that differentiation of a c . 10 km 3 magma body at this volcanic centre occurs at 8–10 km depth in the crust.