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NARROW
GeoRef Subject
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all geography including DSDP/ODP Sites and Legs
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Africa
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Antarctica
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commodities
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Primary terms
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Africa
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Assessing controls on organic matter enrichments in hemipelagic marls of the Aptian-Lower Albian Blue Marls of the Vocontian Basin (France): an unexpected variability observed from multiple “organic-rich” levels
Re-assessing copper and nickel enrichments as paleo-productivity proxies
Conjugated enrichments in arsenic and antimony in marine deposits used as paleoenvironmental proxies: preliminary results
Poly-phased fluid flow in the giant fossil pockmark of Beauvoisin, SE basin of France
Dip-related changes in stratigraphic architecture and associated sedimentological and geochemical variability in the Upper Cretaceous Eagle Ford Group in south Texas
3D morphology and timing of the giant fossil pockmark of Beauvoisin, SE Basin of France
Paleoenvironmental evolution of the southern Neuquèn basin (Argentina) during the Tithonian-Berriasian (Vaca Muerta and Picún Leufú Formations): a multi-proxy approach
Small-scaled lateral variations of an organic-rich formation in a ramp-type depositional environment (the Late Jurassic of the Boulonnais, France): impact of the clastic supply
On the Lower Cambrian biotic and geochemical record of the Hetang Formation (Yangtze Platform, south China): evidence for biogenic silica and possible presence of Radiolaria
A possible capture of molybdenum during early diagenesis of dysoxic sediments
Abstract Abstract: In the Kimmeridge Clay Formation of the Wessex–Weald Basin, five organic-matter-rich intervals (ORIs), dated from Kimmeridgian–Tithonian times, can be correlated from distal depositional environments in Dorset and Yorkshire (UK) to the proximal environments in Boulonnais, northern France. The ORIs are superimposed on a meter-scale cyclic distribution of organic matter (OM), referred to as primary cyclicity, which is commonly interpreted to result from Milankovitch climate forcing. The present work addresses the distribution of redox-sensitive and/or sulfide-forming trace metals and selected major elements (Si, Al, and Fe) in Kimmeridge Clay shales from the Cleveland Basin (Yorkshire) and the Boulonnais cliffs with two objectives: (1) to determine whether the ORIs formed in similar paleoenvironments, and (2) to identify the mechanism(s) of OM accumulation. High-resolution geochemical data from primary cycles in the Yorkshire boreholes (Marton and Ebberstone boreholes) were studied and the results are then applied with lower-resolution sampling at the ORI scale in the Flixton borehole and Boulonnais cliff. Good correlations are found between total organic carbon (TOC) vs. Cu/Al and Ni/Al, but relationships between TOC and Mo/Al, V/ Al and U/Al are more complex. Cu and Ni enrichment is interpreted to have resulted from passive accumulation with OM in an oxygen-deficient basinal setting, which prevented the subsequent loss of Cu and Ni from the sediment. Mo and V were significantly enriched only in sediments where considerable amounts of OM (TOC > 7%) accumulated, the result of strongly reducing conditions and OM burial. At the scale of the Flixton ORIs, the samples with the highest Mo and V concentrations also show relative Fe enrichment, suggesting pyrite formation in the water column (combination of euxinic conditions and presumably low sedimentation rates). Samples from all ORIs were slightly enriched in Si relative to Al, interpreted as reflecting decreased sediment flux during transgressive and early-highstand systems tracts. The data show that in some ORIs, OM accumulation proceeded while productivity was not particularly high and sediments were not experiencing strong anoxia. In other ORIs, OM accumulation was accompanied by widespread anoxia and possibly euxinic conditions in distal settings. Though somewhat different from each other, all of the ORIs developed during episodes of reduced terrigenous supply (transgressive episodes). The common feature linking these contrasted episodes of enhanced OM storage (ORIs) must be the conjunction of productivity coupled with a decrease in the dilution effect by the land-derived supply, in a depositional environment prone to water stratification and, therefore, favorable to OM preservation and accumulation.