ABSTRACT Carbon stable isotope data from western Canada, in combination with biostratigraphic control and astrochronologic constraints from magnetic susceptibility data, provide insight into the pace and timing of the Frasnian–Famennian (F–F; Late Devonian) biotic crisis. In much of the world, this event is characterized by two organic–rich shales, which display geochemical anomalies that indicate low-oxygen conditions and carbon burial. These events, commonly referred to as the Lower and Upper Kellwasser events (LKE and UKE), have been linked to the expansion of deeply rooted terrestrial forests and associated changes in soil development, chemical weathering, and Late Devonian climate. The δ 13 C data generated from organic matter record a 3 to 4‰ positive excursion during each event. These data and other geochemical proxy data reported elsewhere corroborate hypotheses about enhanced biological productivity, driven by terrigenous input under exceptionally warm climatic conditions. In this hypothesis,a boom in primary production leads to successive development of anoxic bottom water conditions, decreased biotic diversity, and net transfer of carbon from the atmosphere to the ocean floor. Despite the importance of the F–F events, a precise chronology for the events is lacking due to limited biostratigraphic resolution. Each of the F–F events falls within one conodont zone, with durations estimated on the order of 0.5 to 1.0 Myr. The LKE occurs very high in Frasnian Zone (FZ) 12, while the UKE begins within FZ 13B, just below the F–F boundary. A previous analysis of high-resolution magnetic susceptibility data from the studied sections in western Canada identified 16.5 eccentricity cycles, each lasting 405 kyr, within the Frasnian strata and one in the earliest Famennian. The present study reports δ 13 C anomalies associated with the LKE and UKE in the same sections. The LKE and UKE intervals comprise 7 to 8 and 13 to 13.5 m of stratigraphic section, respectively. Based on our analysis, this implies that they represent only one 405-kyr eccentricity cycle or less.We estimate that the duration of the LKE was a bit more than half of a long eccentricity cycle (~200–250 kyr), while the UKE was more protracted, lasting a full long eccentricity cycle (~405 kyr). The onset of both events is separated by one-and-a-half 405-kyr eccentricity cycles, indicating that they occurred about 500 to 600 kyr apart. This work demonstrates the utility of magnetic susceptibility, or other long time-series proxy data, used in conjunction with astronomical calibration to provide insight into the pacing of significant events in geologic time.

Abstract We investigate the Late Devonian Frasnian–Famennian extinction interval in western Alberta and south China to shed light on the palaeoecological and palaeoceanographic conditions that characterize this biotic crisis. Both the Lower and Upper Kellwasser events are documented in western Canada. Only the Upper Kellwasser event has been evaluated in south China. Our multiproxy geochemical approach reveals that these events are characterized by positive δ 13 C and δ 15 N excursions and increasing magnetic susceptibility (Canada/China) and increases in detrital (Al, Si, Ti, Zr), productivity (Cu, Ni, Zn) and redox (Mo, U, V) elemental proxies (Canada). We interpret these trends as part of a systemic palaeoecological shift associated with the development of widespread terrestrial forests and their alteration of chemical–mechanical weathering patterns. Increase in detrital proxies is thus interpreted as resulting from pedogenically driven weathering on the continents that nutrified epeiric and continental margin seas. High biological productivity led to eutrophication and development of suboxic to anoxic conditions during both events and probably euxinic conditions during the Upper Kellwasser event in western Canada. Positive δ 13 C excursions are the telltale signature of excessive carbon burial, while redox proxies and δ 15 N records indicate suboxic–anoxic denitrifying conditions.

Abstract The Lisburne Group (Carboniferous-Permian) consists of a carbonate platform that extends for >1000 km across northern Alaska, and diverse margin, slope, and basin facies that contain world-class deposits of Zn and Ba, notable phosphorites, and petroleum source rocks. Lithologic, paleontologic, isotopic, geochemical, and seismic data gathered from outcrop and subsurface studies during the past 20 years allow us to delineate the distribution, composition, and age of the off-platform facies, and to better understand the physical and chemical conditions under which they formed. The southern edge of the Lisburne platform changed from a gently sloping, homoclinal ramp in the east to a tectonically complex, distally steepened margin in the west that was partly bisected by the extensional Kuna Basin (~200 by 600 km). Carbonate turbidites, black mudrocks, and radiolarian chert accumulated in this basin; turbidites were generated mainly during times of eustatic rise in the late Early and middle Late Mississippian. Interbedded black mudrocks (up to 20 wt% total organic carbon), granular and nodular phosphorite (up to 37 wt% P 2 O 5 ), and fine-grained limestone rich in radiolarians and sponge spicules formed along basin margins during the middle Late Mississippian in response to a nutrient-rich, upwelling regime. Detrital zircons from a turbidite sample in the western Kuna Basin have mainly Neoproterozoic through early Paleozoic U-Pb ages (~900-400 Ma), with subordinate populations of Mesoproterozoic and late Paleoproterozoic grains. This age distribution is similar to that found in slightly older rocks along the northern and western margins of the basin. It also resembles age distributions reported from Carboniferous and older strata elsewhere in northwestern Alaska and on Wrangel Island. Geochemical and isotopic data indicate that suboxic, denitrifying conditions prevailed in the Kuna Basin and along its margins. High V/Mo, Cr/Mo, and Re/Mo ratios (all marine fractions [MF]) and low MnO contents (<0.01 wt%) characterize Lisburne black mudrocks. Low Qmf/Vmf ratios (mostly 0.8-4.0) suggest moderately to strongly denitrifying conditions in suboxic bottom waters during siliciclastic and phosphorite sedimentation. Elevated to high Mo contents (31-135 ppm) in some samples are consistent with seasonal to intermittent sulfidic conditions in bottom waters, developed mainly along the basin margin. High d 15 N values (6-120) imply that the waters supplying nutrients to primary producers in the photic zone had a history of denitrification either in the water column or in underlying sediments. Demise of the Lisburne platform was diachronous and reflects tectonic, eustatic, and environmental drivers. Southwestern, south-central, and northwestern parts of the platform drowned during the Late Mississippian, coincident with Zn and Ba metallogenesis within the Kuna Basin and phosphogenesis along basin margins. This drowning was temporary (except in the southwest) and likely due to eutrophication associated with upwelling and sea-level rise enhanced by regional extension, which allowed suboxic, denitrifying waters to form on platform margins. Final drowning in the southcentral area occurred in the Early Pennsylvanian and also may have been linked to regional extension. In the northwest, platform sedimentation persisted into the Permian; its demise there appears to have been due to increased siliciclastic input. Climatic cooling may have produced additional stress on parts of the Lisburne platform biota during Pennsylvanian and Permian times.

Abstract Stratigraphic analysis of the Yaxcopoil-1 core (Yax-1) and seismic analysis of offshore two-dimensional (2D) seismic data provide insight into the Paleogene history of the Chicxulub impact basin and Yucatàn platform development. Ten facies were identified based on core and petrographic analysis. Slope sediments include redeposited and background facies. The former are carbonate supportstones and finer-grained facies with evidence of soft sediment deformation deposited as gravity flows. Background facies are shales and mud-wackestone interpreted as sub-storm wave base suspension deposits. Depositional setting ranged from a steep bathyal slope inside the crater rim to neritic outer carbonate platform environments of the seaward prograding Yucatàn platform. Through sequence stratigraphic analysis of Yax-1, we documented five sequences based on identification of transgressive and maximum flooding surfaces and facies stacking patterns. Biostratigraphic ages are equivocal, but they imply that sequences 1 and 2 are Early Paleocene, sequences 3 and 4 are Early Eocene, and sequence 5 is Middle Eocene. Coarse-grained redeposited carbonates in lower sequences 1 to 4 indicate slope gravity flow processes. Upper sequence 3 records the first evidence of fine-grained turbidites, indicating progradation of the Yucatàn platform. By the top of sequence 4, facies indicate that the platform margin had prograded over the position of Yax-1. Seismic analysis identified six units, the lower five of which appear to correlate with cored Yax-1 sequences. The geometry and distribution of seismic units A and B indicate deposition confined to the western and central parts of the basin. Unit C, with two sets of clinoforms, records a major progradational event in the eastern part of the basin likely related to Yax-1 sequence 3 turbidites. Mainly parallel reflectors in seismic units D and E indicate relatively level bottom conditions similar to the environments of facies in upper sequence 4 and 5. The tops of units D and E, in proximal settings, are erosionally truncated. This unconformity marks the base of unit F, which is characterized by discontinuous reflectors and is restricted to the northeastern portion of the basin. Stratal patterns in seismic units C to E are more controlled by relative sea-level change, as suggested by the development of clinoforms and regional unconformities. If Chicxulub and others like the Chesapeake Bay structure are representative, large marine impacts in tectonically quiescent regions may dominate local depositional environments for millions to tens of millions of years postimpact before returning control to eustasy.

The Upper Triassic (Carnian–Norian) Martin Bridge Formation of northeastern Oregon, southeastern Washington, and western Idaho is characterized by rapidly shifting depositional processes within a tropical volcanic island arc setting. Martin Bridge sequences in the Hells Canyon and northern Wallowa Mountains document shallow-water peritidal evaporitic sediments that are succeeded by deeper and predominantly subtidal deposits. This indicates drowning of the carbonate platform and a transition to deeper-water turbiditic sedimentation before a late Triassic transition into the overlying mid-Norian to Jurassic Hurwal Formation. At the type locality in the southern Wallowa Mountains, dysaerobic shales, carbonate debris sheets, and turbiditic sediments indicate distal slope and basinal environments while other facies at other sites in the Wallowa Mountains and Hells Canyon areas indicate reef and shallow-water platform settings. In this paper we formally recognize the name Martin Bridge Formation and reinstate the type locality in the southern Wallowa Mountains as the principal unit strato-type. An additional reference section is given at Hurricane Creek in the northern Wallowa Mountains. The Martin Bridge is formally divided into four members: the Eagle Creek and Summit Point Members are introduced and formally proposed herein and the BC Creek and Scotch Creek Members also are elevated to formal status. A partial reconstruction of the Wallowa terrane during deposition of the Martin Bridge Formation suggests a north-south (or northeast-southwest) trending platform margin facing a forearc basin situated to the east (or southeast). The lithofacies and paleontological characteristics of the Martin Bridge can be put into the framework of a depositional and a tectonic model to help better explain many of the stratigraphic and paleontologic problems previously encountered. We believe that the Wallowa terrane provides one of the best and most complete examples yet known for shallow-water carbonate depositional patterns in an oceanic island arc setting.

Abstract This study applies high-resolution sequence stratigraphy, biostratigraphy, and magnetic susceptibility (MS) stratigraphy to better constrain correlation of upper Middle and Upper Devonian strata and geologic events in western Alberta, Canada. We also explore the potential of MS stratigraphy as a long-range correlation tool and paleoclimatic or oxygen isotope proxy. High-resolution MS data from slope and basin deposits near the isolated Miette and Ancient Wall platforms provide insight into patterns of carbonate- platform development and infilling of the Devonian Alberta basin. Our MS data, combined with conodont and brachiopod biostrati-graphic data and sequence stratigraphy, provides additional control on the relative timing of five major and fifteen higher-frequency MS excursions and nine depositional sequences. Sea-level events that initiated deposition of seven of nine late Givetian-early Famennian third order depositional sequences in western Alberta coincide with Devonian transgressive-regressive (T-R) cycles IIa-2 to IIe. Eight of these form the main sequence stratigraphic architectural units of the isolated Miette and Ancient Wall platforms. Sea- level events were identified based on significant sequence stratigraphic horizons, including exposure and marine flooding surfaces, and were biochronologically calibrated using combined conodont and brachiopod biostratigraphy. Identification of sequence boundaries and differentiation of highstand and lowstand slope and basinal deposits was based on the geometry, mineralogy, and clast content of redeposited carbonate units. The magnetic-susceptibility signature of slope and basin facies is also shown to vary systematically within the sequence stratigraphic framework. Spikes in the MS record coincide with events associated with lowstand or initial transgression. The MS stratigraphy displays a consistent pattern across the Alberta basin, with generally higher MS values toward the east. The MS signature is generally low in the late Givetian and early Frasnian (through MN Zone 9) but displays a major bimodal MS increase in the middle to late Frasnian (MN zones 10-11). MS values return to generally lower levels during the late Frasnian (MN zones 12-13) and early Famennian. This general pattern of increasing followed by decreasing MS is interpreted to indicate variations in delivery of magnetically susceptible terrigenous material. The highest MS values correlate directly to the lithologic change associated with an influx of fine-grained siliciclastics in the Mount Hawk Formation. The generally consistent pattern of MS change across the Alberta basin points toward the utility of MS stratigraphy as a regional correlation tool. Several other positive MS excursions documented here are also associated with increased detrital input and are coeval with decreasing or low oxygen isotope values (increasing or high paleotemperatures) reported from both Laurasia and Gondwana. This relationship implies a paleoclimatic linkage with increasing temperatures and weathering rates resulting in higher detrital input and higher MS values. Published oxygen isotope data are too coarse to conduct high-resolution comparison with our MS data, but the parallel trends noted here suggest that further research on the use of MS as an oxygen isotope or paleoclimate proxy is warranted. The MS signature of coeval Devonian rocks from highly condensed sections in Morocco displays a shape structure similar to our data and reinforces arguments that MS stratigraphy has potential as a long-range correlation tool.

Abstract The Shublik Formation (Triassic, North Slope, Alaska) is an organic-, phosphate-, and glauconite-rich unit with abundant fossils of marine vertebrates and mollusks. Five lithofacies, generalized around significant chemical constituents or lack thereof, are identified in the Shublik Formation: nonglauconitic sandstone - thin- to medium-bedded, fine, quartzose, calcareous to noncalcareous sandstone or silty to muddy sandstone, fossiliferous in places; glauconitic - thin- to medium-bedded, fine, quartzose sandstone, muddy sandstone, or siltstone containing 10% to > 50% glauconite grains phosphatic - thin- to medium-bedded siltstone or sandstone or laminated, black silty limestone or limestone containing phosphate nodules; and organic-rich - laminated, black limestone, marl, and mudstone nonphosphatic, nonorganic-rich limestone - bioclastic wackestone, or argillaceous grainstone and packstone or graded grainstone and packstone. Ichnofabrics provide evidence of fluctuating oxygen levels within the facies, especially the nonglauconitic sandstone and glauconitic facies. The organic-rich facies and, to a lesser extent, the phosphatic facies contain abundant, pristine, disarticulated shells of the clam Halobia . The lithofacies, ichnofabrics, and taphonomy are interpreted to be related to onshore-offshore gradients in biologic productivity and redox conditions. The Shublik Formation is interpreted as an upwelling-zone deposit formed on a shallow shelf. The Shublik Formation in the Prudhoe Bay region is interpreted to comprise three sequences; these have been extended to outcrop but not to cores in the National Petroleum Reserve. Facies stacking patterns indicate that siliclastic facies are most common during lowstand and transgression, organic-rich facies are characteristic of transgression, and carbonate-rich facies are more prevalent during highstand. Phosphatic facies occur along transgressive and maximum flooding surfaces and are thus integral to subdividing sequences into systems tracts.