Abstract We use volatiles in melt inclusions and nominally anhydrous phenocrysts, with volcanic gas flux and composition, and textural analysis of mafic inclusions to estimate the mass of exsolved vapour prior to eruption at Soufrière Hills Volcano (SHV). Pre-eruptive andesite coexists with exsolved vapour comprising 1.6–2.4 wt% of the bulk magma. The water content of orthopyroxenes indicates a zone of magma storage at pressures of approximately 200–300 MPa, whereas melt inclusions have equilibrated at shallower pressures. Inclusions containing >3 wt% H 2 O are enriched in CO 2 , suggesting flushing with CO 2 -rich gases. Intruding mafic magma contains >8 wt% H 2 O at 200–300 MPa. Rapid quenching is accompanied by crystallization and vesiculation. Upon entrainment into the andesite, mafic inclusions may undergo disaggregation, where expansion of volatiles in the interior overcomes the strength of the crystal frameworks, thereby recharging the vapour content of the andesite. Exsolved vapour may amount to 4.3–8.2 vol% at 300 MPa, with implications for eruption longevity and volume; we estimate the magma reservoir volume to be 60–200 km 3 . Exsolved vapour may account for the small volume change at depth during eruptions from geodetic models, and has implications for magma flow: exsolution is likely to be in equilibrium during rapid magma ascent, with little nucleation of new bubbles.

Abstract The andesite lava erupted at the Soufrière Hills Volcano (SHV) is crystal-rich with 33–63% phenocrysts of plagioclase (65%), amphibole (28%), orthopyroxene (7%), and minor Fe–Ti oxide and clinopyroxene microphenocrysts. The andesite hosts mafic enclaves that have similar mineral phases to the andesite. The enclaves are generally crystal-poor but can have up to 27% of inherited phenocrysts from the andesite, the majority of which are plagioclase. The eruption is defined by discrete periods of extrusion called phases, separated by pauses. The enclaves exhibit bulk geochemical trends that are consistent with fractionation. We infer that the intruded mafic liquids of Phases I and II interacted and assimilated plutonic residue remaining from the multiple prior mafic intrusions, while the basaltic liquids from Phases III and V assimilated relatively little material. We also infer a change in the basaltic composition coming from depth. The bulk Fe contents of both magma types are coupled and they both show a systematic interphase variation in Fe content. We interpret the coupled Fe variation to be due to contamination of the andesite from the intruding basalt via diffusion and advection processes, resulting in the erupted andesite products bearing the geochemical imprint of the syn-eruptive enclaves.

Abstract Lavas from the current eruption of the Soufrière Hills Volcano (SHV), Montserrat exhibit evidence for magma mingling, related to the intrusion of mafic magma at depth. We present detailed field, petrological, textural and geochemical descriptions of mafic enclaves in andesite erupted during 2009–2010, and subdivide the enclaves into three distinct types: type A are mafic, glassy with chilled margins and few inherited phenocrysts; type B are more evolved with high inherited phenocryst content and little glass, and are interpreted as significantly hybridized; type C are composite, with a mafic interior (type A) and a hybrid exterior (type B). All enclaves define tight linear compositional trends, interpreted as mixing between a mafic end member (type A) and host andesite. Enclave glasses are rhyolitic, owing to extensive crystallization during quenching. Type A quench crystallization is driven by rapid thermal equilibration during injection into the andesite. Conversely, type B enclaves form in a hybridized melt layer, which ponded near the base of the chamber and cooled more slowly. Vesiculation near the mafic–silicic interface resulted in disruption of the hybridized layer and the formation of the type B enclaves. The composite enclaves represent an interface between types A and B, suggesting multiple episodes of mafic injection.