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NARROW
GeoRef Subject
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all geography including DSDP/ODP Sites and Legs
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Australasia
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Australia
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Canada
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Australia
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Nunavut (1)
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Queen Elizabeth Islands
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Western Canada
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Northwest Territories (1)
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carbon
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A 22 m series of cores from a continuously laminated sequence of postglacial sediment was recovered from 29.6 m of water from the deepest part of Elk Lake, Clearwater County, Minnesota, by piston and freeze-coring methods during the winters of 1978 and 1982. A varve time series constructed and used as a basis for subsampling the cores and samples, based on the varve chronology, allows precise determination of fluxes of geochemical and biological sediment components. Chronological and petrographic studies have shown that the laminations are varves and their measurement and enumeration has produced a 10,400 year time series that estimates the rates and timing of paleolimnologic and paleoenvironmental changes in Elk Lake and its drainage. A radiocarbon date from surface sediment is 850 years. The difference between radiocarbon and varve dates continues down core; varve dates are older than radiocarbon dates, probably because of systematic incorporation of dead carbon (as bicarbonate) in organic matter in the sediment. Varve-dated boundaries of pollen zones in the Elk Lake cores compare closely with the ages of the same zones in cores from nearby lakes that have been radiocarbon dated.
Variations in the ratios of 18 O: 16 O and 13 C: 12 C in calcite throughout the Holocene in Elk Lake, Minnesota, are recorded in three varve-calibrated carbonate cores. Marl in a varved deep-basin (29.6 m) core consists mainly of calcite precipitated from surface waters during the summer and probably provides the least complicated isotope record. Marl in a sublittoral (10 m) core consists of calcite contributed from several inorganic and organic sources and probably is the most complicated of the three isotope records. Calcite from shells of the ostracod Candona ohioensis in the sublittoral core provides a record of shallow-water conditions in Elk Lake for the period between 10,500 and 5500 varve yr. Variations in the 13 C: 12 C ratio of organic carbon deposited in Elk Lake during the Holocene are recorded in organic matter in the deep-basin core. All three oxygen isotope records show that, in general, the 18 O: 16 O ratio in carbonate was enriched in 18 O by several parts per mil during the mid-Holocene relative to the past few thousand years. This pattern of oxygen isotope variation is similar to that observed for carbonate materials from other lakes in the northeastern and north-central United States. Oxygen isotope records from these other lakes also show that the 18 O: 16 O ratio during the early Holocene was lower than during the mid-Holocene, and this pattern has been interpreted as representing a response to a generally warmer and drier climate during the mid-Holocene beginning about 8000 varve yr (the so-called hypsithermal). Ostracod and diatom assemblages from Elk Lake cores show, however, that the lake was colder and more saline than at present until at least 6700 varve yr, with conditions similar to those that exist today in cold prairie lakes of Canada. It may be more appropriate, therefore, to refer to the mid-Holocene in northwestern Minnesota as the “prairie period” rather than the hypsithermal, indicating that the climate was drier, but with no connotation regarding temperature. The oxygen isotope data from the three Elk Lake records for this period are somewhat equivocal. Values of δ 18 O in the marl from the sublittoral core and shells of Candona increase from 10,000 to about 6800 varve yr. However, values of δ 18 O in the marl that accumulated in the deepest part of the lake over the same interval (10,000–6800 varve yr) are more or less constant and enriched in 18 O; this probably reflects the cold, saline prairie-lake conditions predicted from the ostracod and diatom assemblage data. All three oxygen isotope records show decreases in 18 O: 16 O ratios after about 6800 varve yr in response to an increase in temperature and decrease in salinity of the lake. The 13 C: 12 C ratios in carbonates from all three Elk Lake records show a distinct pattern; the ratio increased gradually from 10,000 to 8000 varve yr going into the mid-Holocene prairie period and then decreased gradually coming out of the prairie period between about 5500 and 2500 varve yr. These changes in the 13 C: 12 C ratio could have been related to temperature through its effect on solubility of carbon dioxide; however, this interpretation is not supported by the oxygen isotope data. Another possibility is that changes in the 13 C: 12 C ratio are related to organic productivity that removes 13 C-depleted organic carbon and results in 13 C-enriched surface waters. This interpretation implies that organic productivity was higher in Elk Lake during the mid-Holocene prairie period. Support for the high-productivity, 13 C-enriched surface-water model for the mid-Holocene prairie period in Elk Lake is provided by changes in the 13 C: 12 C ratio of organic carbon in the deep-basin core. These changes parallel almost exactly those in the 13 C: 12 C ratio of carbonate carbon, but are about 2% larger (about 6% as opposed to about 4% for carbonate carbon). The difference of about 2% may represent 13 C depletion due to CO 2 limitation. The percentage of organic carbon in the sediment did not increase during the prairie period because it was diluted by an increased flux of detrital clastic material. The ultimate burial rate of organic carbon increased considerably, however, indicating that organic productivity was higher and/or the degree of preservation increased. Diatom assemblages and plant-pigment concentrations indicate that productivity was higher during the prairie period. Pyrolysis hydrogen and oxygen indices show that the 13 C-enriched organic matter that accumulated during the prairie period was hydrogen rich and oxygen poor relative to organic matter that accumulated before and after. These two indices demonstrate that the organic matter that accumulated during the prairie period was much better preserved.
Dating methods applicable to the Quaternary
Abstract A wide variety of dating methods are used in Quaternary research, and each method has many applications and limitations. Because of this variety, we cannot discuss the applications and limitations of all methods here. The more versatile and widely used methods, including 14 C, K/Ar, fission-track, U-series, paleomagnetism, thermoluminescence, and amino acid dating are treated more comprehensively in this chapter than other methods that are shown on the summary chart. The summary chart is provided here to give an overview of dating work and research for the Quaternary. This summary consists mainly of a table (Plate 2) that is modified and updated from Colman and Pierce (1977, Plate 1, ref. 66). The table is intended as an overview and concise guide to Quaternary dating methods. It contains many subjective judgments and should not be considered definitive; the entries for applicability, age range, and optimum resolution are particularly interpretive. Details concerning assumptions, analytical techniques, uncertainties, and interpretations should be obtained from specialized references using the key references in Plate 2 as a guide. The dating methods described range from well-known and established techniques to experimental procedures whose results are subject to considerable interpretation. Key references included on Plate 2 are intended as an entry into the vast literature on dating methods; space prohibits a more complete listing. We have emphasized recent review papers and notable examples of applications as sources of additional references and information. Dating methods discussed in other sections of this chapter are indicated by asterisks in.