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NARROW
GeoRef Subject
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all geography including DSDP/ODP Sites and Legs
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Africa
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Primary terms
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Africa
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Southern Africa
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South Africa
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Witwatersrand (1)
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Asia
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Far East
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China
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Guizhou China (1)
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Philippine Islands (1)
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Kyrgyzstan (1)
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Siberia (1)
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Atlantic Ocean
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Australasia
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Australia
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Victoria Australia
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Western Australia
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Canada
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stable isotopes
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Pb-207/Pb-204 (1)
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lead-zinc deposits (1)
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silver ores (1)
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metals
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cobalt (1)
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hafnium (1)
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lead
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Pb-206/Pb-204 (1)
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Pb-207/Pb-204 (1)
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Precambrian
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upper Precambrian
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Proterozoic
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Dengying Formation (1)
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sulfur
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sedimentary rocks
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clastic rocks
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black shale (1)
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volcaniclastics (1)
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sediments
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volcaniclastics (1)
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Germanium distribution in Mississippi Valley-Type systems from sulfide deposition to oxidative weathering: A perspective from Fule Pb-Zn(-Ge) deposit, South China
Comparison of lithium borate fusion and four-acid digestions for the determination of whole-rock chemistry – implications for lithogeochemistry and mineral exploration
Trace elements in sulfides from the Maozu Pb-Zn deposit, Yunnan Province, China: Implications for trace-element incorporation mechanisms and ore genesis
Using Mineral Chemistry to Aid Exploration: A Case Study from the Resolution Porphyry Cu-Mo Deposit, Arizona
Recent advances in the application of mineral chemistry to exploration for porphyry copper–gold–molybdenum deposits: detecting the geochemical fingerprints and footprints of hypogene mineralization and alteration
Gold- and Silver-Rich Massive Sulfides from the Semenov-2 Hydrothermal Field, 13°31.13'N, Mid-Atlantic Ridge: A Case of Magmatic Contribution?
Trace Element Content of Pyrite from the Kapai Slate, St. Ives Gold District, Western Australia
Trace Element Content of Sedimentary Pyrite in Black Shales
Abstract Propylitic alteration halos to porphyry deposits are characterized by low- to moderate-intensity replacements of primary feldspars and mafic minerals by epidote, chlorite, calcite ± actinolite, pyrite, prehnite, and zeolites. The pyrite halo that surrounds porphyry deposits typically extends part way through the propylitic halo and provides strong responses to conventional geochemical and geophysical exploration techniques. When exploring outside of the pyrite halo, porphyry deposits have proven to be difficult to detect based simply on the presence of weak epidote-chlorite alteration. Laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) analyses of epidote from propylitic alteration zones around porphyry and skarn deposits in the central Baguio district, Philippines, have shown that low-level hypogene geochemical dispersion halos can be detected at considerably greater distances than can be achieved by conventional rock chip sampling of altered rocks. Epidote chemistry can provide vectoring information to the deposit center and potentially provides insights into the potential metal endowment of the porphyry system, providing explorers with both vectoring and fertility assessment tools. Epidote chemistry varies with respect to distance from porphyry deposit centers, with the highest concentrations of proximal pathfinder elements (e.g., Cu, Mo, Au, Sn) detected in epidote from close to the potassic alteration zone. Distal pathfinder elements (e.g., As, Sb, Pb, Zn, Mn) are most enriched in epidote more than 1.5 km from the deposit center. Rare earth elements and Zr are most enriched in epidote from the edge of the pyrite halo. The lateral zonation in epidote chemistry implies that at Baguio the geochemical dispersion patterns were produced by lateral outflow of spent fluids from the porphyry center, rather than from ingress of peripheral, nonmagmatic waters.