Abstract In 2010, Gunung Merapi (Central Java, Indonesia) generated two violent eruption sequences on 26 October and 5 November culminating in widespread pyroclastic density currents (PDCs) associated with the destruction of lava domes. Tephra from PDC deposits were analysed to examine pre-dome collapse volatile behaviour and evidence of carbonate assimilation. Secondary-ion mass spectroscopy (SIMS) depth profiles of plagioclase phenocrysts reveal that the 7 Li/ 30 Si ratios in 26 October products are higher in the glass compared to the crystal, indicating a build-up of Li in the groundmass not observed in the 5 November samples. Higher Li in the groundmass suggests gas accumulation and rapid development of conduit overpressure in the shallow plumbing system prior to the initial 26 October explosion, which was only captured through the behaviour of quickly diffusing Li and not H 2 O. Following the explosion-induced decompression, juvenile magma rapidly ascended in great volume to generate extremely destructive PDCs following subsequent dome collapses, particularly on 5 November. Additionally, 26 October tephras contain carbonate grains in the ash component and abundant CO 2 within the lava lapilli groundmass glass, which supports previous studies indicating assimilation of calc-silicate lithologies by the Merapi magma at depth in the plumbing system prior to the onset of 2010 activity. supplementary material: Feldspar microlite compositions and SIMS volatile data for the glass measurements are available at http://www.geolsoc.org.uk/SUP18762 .

Abstract The andesite lava erupted at the Soufrière Hills Volcano (SHV) is crystal-rich with 33–63% phenocrysts of plagioclase (65%), amphibole (28%), orthopyroxene (7%), and minor Fe–Ti oxide and clinopyroxene microphenocrysts. The andesite hosts mafic enclaves that have similar mineral phases to the andesite. The enclaves are generally crystal-poor but can have up to 27% of inherited phenocrysts from the andesite, the majority of which are plagioclase. The eruption is defined by discrete periods of extrusion called phases, separated by pauses. The enclaves exhibit bulk geochemical trends that are consistent with fractionation. We infer that the intruded mafic liquids of Phases I and II interacted and assimilated plutonic residue remaining from the multiple prior mafic intrusions, while the basaltic liquids from Phases III and V assimilated relatively little material. We also infer a change in the basaltic composition coming from depth. The bulk Fe contents of both magma types are coupled and they both show a systematic interphase variation in Fe content. We interpret the coupled Fe variation to be due to contamination of the andesite from the intruding basalt via diffusion and advection processes, resulting in the erupted andesite products bearing the geochemical imprint of the syn-eruptive enclaves.