This memoir is the first to review all of Antarctica's volcanism between 200 million years ago and the Present. The region is still volcanically active. The volume is an amalgamation of in-depth syntheses, which are presented within distinctly different tectonic settings. Each is described in terms of (1) the volcanology and eruptive palaeoenvironments; (2) petrology and origin of magma; and (3) active volcanism, including tephrochronology. Important volcanic episodes include: astonishingly voluminous mafic and felsic volcanic deposits associated with the Jurassic break-up of Gondwana; the construction and progressive demise of a major Jurassic to Present continental arc, including back-arc alkaline basalts and volcanism in a young ensialic marginal basin; Miocene to Pleistocene mafic volcanism associated with post-subduction slab-window formation; numerous Neogene alkaline volcanoes, including the massive Erebus volcano and its persistent phonolitic lava lake, that are widely distributed within and adjacent to one of the world's major zones of lithospheric extension (the West Antarctic Rift System); and very young ultrapotassic volcanism erupted subglacially and forming a world-wide type example (Gaussberg).

Abstract The tectonic evolution of Antarctica in the Mesozoic and Cenozoic eras was marked by igneous activity that formed as a result of simultaneous continental rifting and subduction processes acting during the final stages of the southward drift of Gondwana towards the South Pole. For the most part, continental rifting resulted in the progressive disintegration of the Gondwana supercontinent from Middle Jurassic times to the final isolation of Antarctica at the South Pole following the Cenozoic opening of the surrounding ocean basins, and the separation of Antarctica from South America and Australia. The initial rifting into East and West Gondwana was proceeded by emplacement of large igneous provinces preserved in present-day South America, Africa and Antarctica. Continued rifting within Antarctica did not lead to continental separation but to the development of the West Antarctic Rift System, dividing the continent into the East and West Antarctic plates, and uplift of the Transantarctic Mountains. Motion between East and West Antarctica has been accommodated by a series of discrete rifting pulses with a westward shift and concentration of the motion throughout the Cenozoic leading to crustal thinning, subsidence, elevated heat flow conditions and rift-related magmatic activity. Contemporaneous with the disintegration of Gondwana and the isolation of Antarctica, subduction processes were active along the palaeo-Pacific margin of Antarctica recorded by magmatic arcs, accretionary complexes, and forearc and back-arc basin sequences. A low in magmatic activity between 156 and 142 Ma suggests that subduction may have ceased during this time. Today, following the gradual cessation of the Antarctic rifting and surrounding subduction, the Antarctic continent is situated close to the centre of a large Antarctic Plate which, with the exception of an active margin on the northern tip of the Antarctic Peninsula, is surrounded by active spreading ridges.

Abstract Since Jurassic time ( c. 200 Ma), Antarctica has had a greater diversity of volcanism than other southern continents. It includes: (1) voluminous mafic and felsic volcanism associated with the break-up of Gondwana; (2) a long-lived continental margin volcanic arc, including back-arc alkaline volcanism linked to slab rollback; (3) small-volume mafic alkaline volcanism associated with slab-window formation; and (4) one of Earth's major continental rift zones, the West Antarctic Rift System (WARS), with its numerous large alkaline central volcanoes. Several of Antarctica's volcanoes are still active. This chapter is a review of the major volcanic episodes and their principal characteristics, in their tectonic, volcanological and palaeoenvironmental contexts. Jurassic Gondwana break-up was associated with large-scale volcanism that caused global environmental changes and associated mass extinctions. The volcanic arc was a major extensional arc characterized by alternating volcanic flare-ups and lulls. The Neogene rift-related alkaline volcanism is dominated by effusive glaciovolcanic eruptions, overwhelmingly as both pāhoehoe- and ‘a‘ā-sourced lava-fed deltas. The rift is conspicuously poor in pyroclastic rocks due to the advection and removal of tephra erupted during glacial intervals. Volcanological investigations of the Neogene volcanism have also significantly increased our knowledge of the critical parameters and development of the Antarctic Ice Sheet.

Abstract Petrological investigations over the past 30 years have significantly advanced our knowledge of the origin and evolution of magmas emplaced within and erupted on top of the Antarctic Plate. Over the last 200 myr Antarctica has experienced: (1) several episodes of rifting, leading to the fragmentation of Gondwana and the formation by c. 83 Ma of the current Antarctica Plate; (2) long-lived subduction that shut down progressively eastwards along the Gondwana margin in the Late Cretaceous and is still active at the northernmost tip of the Antarctic Peninsula; and (3) broad extension across West Antarctica that produced one of the Earth's major continental rift systems. The dynamic tectonic history of Antarctica since the Triassic has led to a diversity of volcano types and igneous rock compositions with correspondingly diverse origins. Many intriguing questions remain about the petrology of mantle sources and the mechanisms for melting during each tectonomagmatic phase. For intraplate magmatism, the upwelling of deep mantle plumes is often evoked. Alternatively, subduction-related metasomatized mantle sources and melting by more passive means (e.g. edge-driven flow, translithospheric faulting, slab windows) are proposed. A brief review of these often competing models is provided in this chapter along with recommendations for ongoing petrological research in Antarctica.

Abstract In the last two centuries, demographic expansion and extensive urbanization of volcanic areas have increased the exposure of our society to volcanic hazards. Antarctica is no exception. During the last decades, the permanent settlement and seasonal presence of scientists, technicians, tourists and logistical personnel close to active volcanoes in the south polar region have increased notably. This has led to an escalation in the number of people and the amount of infrastructure exposed to potential eruptions. This requires advancement of our knowledge of the volcanic and magmatic history of Antarctic active volcanoes, significant improvement of the monitoring networks, and development of long-term hazard assessments and vulnerability analyses to carry out the required mitigation actions, and to elaborate on the most appropriate response plans to reduce loss of life and infrastructure during a future volcanic crisis. This chapter provides a brief summary of the active volcanic systems in Antarctica, highlighting their main volcanological features, which monitoring systems are deployed (if any), and recent (i.e. Holocene and/or historical) eruptive activity or unrest episodes. To conclude, some notes about the volcanic hazard assessments carried out so far on south polar volcanoes are also included, along with recommendations for specific actions and ongoing research on active Antarctic volcanism.

Abstract Preserved rocks in the Jurassic Ferrar Large Igneous Province consist mainly of intrusions, and extrusive rocks, the topic of this chapter, comprise the remaining small component. They crop out in a limited number of areas in the Transantarctic Mountains and southeastern Australia. They consist of thick sequences of lavas and sporadic occurrences of volcaniclastic rocks. The latter occur mainly beneath the lavas and represent the initial eruptive activity, but also are present within the lava sequence. The majority are basaltic phreatomagmatic deposits and in at least two locations form immense phreatocauldrons filled with structureless tuff breccias and lapilli tuffs with thicknesses of as much as 400 m. Stratified sequences of tuff breccias, lapilli tuffs and tuffs are up to 200 m thick. Thin tuff beds are sparsely distributed in the lava sequences. Lava successions are mainly 400–500 m thick, and comprise individual lavas ranging from 1 to 230 m thick, although most are in the range of 10–100 m. Well-defined colonnade and entablature are seldom displayed. Lava sequences were confined topographically and locally ponded. Water played a prominent role in eruptive activity, as exhibited by phreatomagmatism, hyaloclastites, pillow lava and quenching of lavas. Vents for lavas have yet to be identified.

Abstract The Lower Jurassic Ferrar Large Igneous Province consists predominantly of intrusive rocks, which crop out over a distance of 3500 km. In comparison, extrusive rocks are more restricted geographically. Geochemically, the province is divided into the Mount Fazio Chemical Type, forming more than 99% of the exposed province, and the Scarab Peak Chemical Type, which in the Ross Sea sector is restricted to the uppermost lava. The former exhibits a range of compositions (SiO 2 = 52–59%; MgO = 9.2–2.6%; Zr = 60–175 ppm; Sr i = 0.7081–0.7138; ε Nd = −6.0 to −3.8), whereas the latter has a restricted composition (SiO 2 = c. 58%; MgO = c. 2.3%; Zr = c. 230 ppm; Sr i = 0.7090–0.7097; ε Nd = −4.4 to −4.1). Both chemical types are characterized by enriched initial isotope compositions of neodymium and strontium, low abundances of high field strength elements, and crust-like trace element patterns. The most basic rocks, olivine-bearing dolerites, indicate that these geochemical characteristics were inherited from a mantle source modified by subduction processes, possibly the incorporation of sediment. In one model, magmas were derived from a linear source having multiple sites of generation each of which evolved to yield, in sum, the province-wide coherent geochemistry. The preferred interpretation is that the remarkably coherent geochemistry and short duration of emplacement demonstrate derivation from a single source inferred to have been located in the proto-Weddell Sea region. The spatial variation in geochemical characteristics of the lavas suggests distinct magma batches erupted at the surface, whereas no clear geographical pattern is evident for intrusive rocks.

Abstract The break-up of Gondwana during the Early–Middle Jurassic was associated with flood basalt volcanism in southern Africa and Antarctica (Karoo–Ferrar provinces), and formed one of the most extensive episodes of continental magmatism of the Phanerozoic. Contemporaneous felsic magmatism along the proto-Pacific margin of Gondwana has been referred to as a silicic large igneous province, and is exposed extensively in Patagonian South America, the Antarctic Peninsula and elsewhere in West Antarctica. Jurassic-age silicic volcanism in Patagonia is defined as the Chon Aike province and forms one of the most voluminous silicic provinces globally. The Chon Aike province is predominantly pyroclastic in origin, and is characterized by crystal tuffs and ignimbrite units of rhyolite composition. Silicic volcanic rocks of the once contiguous Antarctic Peninsula form a southward extension of the Chon Aike province and are also dominated by silicic ignimbrite units, with a total thickness exceeding 1 km. The ignimbrites include high-grade rheomorphic ignimbrites, as well as unwelded, lithic-rich ignimbrites. Rhyolite lava flows, air-fall horizons, debris-flow deposits and epiclastic deposits are volumetrically minor, occurring as interbedded units within the ignimbrite succession.

Abstract Large-volume rhyolitic volcanism along the proto-Pacific margin of Gondwana consists of three major episodes of magmatism or ‘flare-ups’. The initial episode (V1) overlaps with the Karoo–Ferrar large igneous provinces at c. 183 Ma. A second (V2) episode was erupted in the interval 171–167 Ma, and a third episode (V3) was emplaced in the interval 157–153 Ma. The magmatic events of the V1 and V2 episodes of the Antarctic Peninsula are reviewed here describing major and trace elements, and isotopic (Sr, Nd, O) data from rhyolitic volcanic rocks and more minor basaltic magmatism. An isotopically uniform intermediate magma developed as a result of anatexis of hydrous mafic lower crust, which can be linked to earlier, arc-related underplating. The subsequent lower-crust partial melts mixed with fractionated mafic underplate, followed by mid-crust storage and homogenization. Early Jurassic (V1) volcanic rocks of the southern Antarctic Peninsula are derived from the isotopically uniform magma, but they have mixed with melts of upper-crustal paragneiss in high-level magma chambers. The V2 rhyolites from the northern Antarctic Peninsula are the result of assimilation and fractional crystallization of the isotopically uniform magma. This process took place in upper-crust magma reservoirs involving crustal assimilants with an isotopic composition akin to that of the magma. A continental margin-arc setting was critical in allowing the development of an hydrous, fusible lower crust. Lower-crustal anatexis was in response to mafic underplating associated with the mantle plume thought to be responsible for the contemporaneous Karoo magmatic province and rifting associated with the initial break-up of Gondwana.

Abstract The Jurassic igneous rocks of Dronning Maud Land represent Karoo flood basalt magmatism in Antarctica. Fifty years of research has documented systematic differences between magmas associated with the Karoo rift-zone (Vestfjella and Ahlmannryggen) and the rift-shoulder (Sembberget, Kirwanveggen) settings. The 189–182 Ma rift-zone tholeiites were chemically diverse and mainly formed compound-braided flow fields which record several magnetic polarity reversals. In contrast, the c. 181 Ma rift-shoulder tholeiites were chemically uniform and formed thick tabular sheet lavas within a single normal polarity period. The volcanic architecture records a long initial phase of slow eruptions from shield volcanoes in the initial rift and a brief phase of voluminous fissure eruptions flooding the rift shoulder. All of the major magma types in the rift-zone and rift-shoulder settings belong to a Nb-depleted category of Karoo flood basalts and were mainly derived from depleted convective upper mantle by magmatic differentiation. Pyroxenite-rich mantle components may have been significant sources for the most enriched magma types. Geochemical fingerprints of recycled crustal material imply that the Nb-depleted Karoo tholeiites may have been derived from mildly subduction-modified parts of the same overall upper-mantle reservoir which has been associated with the Ferrar tholeiites.

Abstract The voluminous continental margin volcanic arc of the Antarctic Peninsula is one of the major tectonic features of West Antarctica. It extends from the Trinity Peninsula and the South Shetland Islands in the north to Alexander Island and Palmer Land in the south, a distance of c. 1300 km, and was related to east-directed subduction beneath the continental margin. Thicknesses of exposed volcanic rocks are up to c. 1.5 km, and the terrain is highly dissected by erosion and heavily glacierized. The arc was active from Late Jurassic or Early Cretaceous times until the Early Miocene, a period of climate cooling from subtropical to glacial. The migration of the volcanic axis was towards the trench over time along most of the length of the arc. Early volcanism was commonly submarine but most of the volcanism was subaerial. Basaltic–andesitic stratocones and large silicic composite volcanoes with calderas can be identified. Other rock associations include volcaniclastic fans, distal tuff accumulations, coastal wetlands and glacio-marine eruptions. Other groups of volcanic rocks of Jurassic age in Alexander Island comprise accreted oceanic basalts within an accretionary complex and volcanic rocks erupted within a rift basin along the continental margin that apparently predate subduction.

Abstract The Antarctic Peninsula contains a record of continental-margin volcanism extending from Jurassic to Recent times. Subduction of the Pacific oceanic lithosphere beneath the continental margin developed after Late Jurassic volcanism in Alexander Island that was related to extension of the continental margin. Mesozoic ocean-floor basalts emplaced within the Alexander Island accretionary complex have compositions derived from Pacific mantle. The Antarctic Peninsula volcanic arc was active from about Early Cretaceous times until the Early Miocene. It was affected by hydrothermal alteration, and by regional and contact metamorphism generally of zeolite to prehnite–pumpellyite facies. Distinct geochemical groups recognized within the volcanic rocks suggest varied magma generation processes related to changes in subduction dynamics. The four groups are: calc-alkaline, high-Mg andesitic, adakitic and high-Zr, the last two being described in this arc for the first time. The dominant calc-alkaline group ranges from primitive mafic magmas to rhyolite, and from low- to high-K in composition, and was generated from a mantle wedge with variable depletion. The high-Mg and adakitic rocks indicate periods of melting of the subducting slab and variable equilibration of the melts with mantle. The high-Zr group is interpreted as peralkaline and may have been related to extension of the arc.

Abstract Following more than 25 years of exploration and research since the last regional appraisal, the number of known subaerially exposed volcanoes in the northern Antarctic Peninsula region has more than trebled, from less than 15 to more than 50, and that total must be increased at least three-fold if seamounts in Bransfield Strait are included. Several volcanoes remain unvisited and there are relatively few detailed studies. The region includes Deception Island, the most prolific active volcano in Antarctica, and Mount Haddington, the largest volcano in Antarctica. The tectonic environment of the volcanism is more variable than elsewhere in Antarctica. Most of the volcanism is related to subduction. It includes very young ensialic marginal basin volcanism (Bransfield Strait), back-arc alkaline volcanism (James Ross Island Volcanic Group) and slab-window-related volcanism (seamount offshore of Anvers Island), as well as volcanism of uncertain origin (Anvers and Brabant islands; small volcanic centres on Livingston and Greenwich islands). Only ‘normal’ arc volcanism is not clearly represented, possibly because active subduction virtually ceased at c. 4 Ma. The eruptive environment for the volcanism varied between subglacial, marine and subaerial but a subglacial setting is prominent, particularly in the James Ross Island Volcanic Group.

Abstract Young volcanic centres of the Bransfield Strait and James Ross Island occur along back-arc extensional structures parallel to the South Shetland island arc. Back-arc extension was caused by slab rollback at the South Shetland Trench during the past 4 myr. The variability of lava compositions along the Bransfield Strait results from varying degrees of mantle depletion and input of a slab component. The mantle underneath the Bransfield Strait is heterogeneous on a scale of approximately tens of kilometres with portions in the mantle wedge not affected by slab fluids. Lavas from James Ross Island east of the Antarctic Peninsula differ in composition from those of the Bransfield Strait in that they are alkaline without evidence for a component from a subducted slab. Alkaline lavas from the volcanic centres east of the Antarctic Peninsula imply variably low degrees of partial melting in the presence of residual garnet, suggesting variable thinning of the lithosphere by extension. Magmas in the Bransfield Strait form by relatively high degrees of melting in the shallow mantle, whereas the magmas some 150 km further east form by low degrees of melting deeper in the mantle, reflecting the diversity of mantle geodynamic processes related to subduction along the South Shetland Trench.

Abstract The Antarctic Peninsula is distinguished by late Neogene volcanic activity related to a series of northerly younging ridge crest–trench collisions and the progressive opening of ‘slab windows’ in the subjacent mantle. The outcrops were amongst the last to be discovered in the region, with many occurrences not visited until the 1970s and 1980s. The volcanism consists of several monogenetic volcanic fields and small isolated centres. It is sodic alkaline to tholeiitic in composition, and ranges in age between 7.7 Ma and present. No eruptions have been observed (with the possible, but dubious, exception of Seal Nunataks in 1893) but very young isotopic ages for some outcrops suggest that future eruptions are a possibility. The eruptions were overwhelmingly glaciovolcanic and the outcrops have been a major source of information on glaciovolcano construction. They have also been highly influential in advancing our understanding of the configuration of the Plio-Pleistocene Antarctic Peninsula Ice Sheet. However, our knowledge is hindered by a paucity of modern, precise isotopic ages. In particular, there is no obvious relationship between the age of ridge crest–trench collisions and the timing of slab-window volcanism, a puzzle that may only be resolved by new dating.

Abstract Scattered occurrences of Miocene–Recent volcanic rocks of the alkaline intraplate association represent one of the last expressions of magmatism along the Antarctic Peninsula. The volcanic rocks were erupted after the cessation of subduction which stopped following a series of northward-younging ridge crest–trench collisions. Volcanism has been linked to the development of a growing slab window beneath the extinct convergent margin. Geochemically, lavas range from olivine tholeiite through to basanite and tephrite. Previous studies have emphasized the slab-window tectonic setting as key to allowing melting of peridotite in the asthenospheric void caused by the passage of the slab beneath the locus of volcanism. This hypothesis is revisited in the light of more recent petrological research, and an origin from melting of subducted slab-hosted pyroxenite is considered here to be a more viable alternative for their petrogenesis. Because of the simple geometry of ridge subduction, and the well-established chronology of ridge crest–trench collisions, the Antarctic Peninsula remains a key region for understanding the transition from active to passive margin resulting from cessation of subduction. However, there are still some key issues relating to their tectonomagmatic association, and, principally, the poor geochronological control on the volcanic rocks requires urgent attention.

Abstract Neogene volcanism is widespread in northern Victoria Land, and is part of the McMurdo Volcanic Group. It is characterized by multiple coalesced shield volcanoes but includes a few relatively small stratovolcanoes. Two volcanic provinces are defined (Hallett and Melbourne), with nine constituent volcanic fields. Multitudes of tiny monogenetic volcanic centres (mainly scoria cones) are also scattered across the region and are called the Northern Local Suite. The volcanism extends in age between middle Miocene ( c. 15 Ma) and present but most is <10 Ma. Two centres may still be active (Mount Melbourne and Mount Rittmann). It is alkaline, varying between basalt (basanite) and trachyte/rhyolite. There are also associated, geographically restricted, alkaline gabbro to granite plutons and dykes (Meander Intrusive Group) with mainly Eocene–Oligocene ages (52–18 Ma). The isotopic compositions of the plutons have been used to infer overall cooling of climate during the Eocene–Oligocene. The volcanic sequences are overwhelmingly glaciovolcanic and are dominated by ‘a‘ā lava-fed deltas, the first to be described anywhere. They have been a major source of information on Mio-Pliocene glacial conditions and were used to establish that the thermal regime during glacial periods was polythermal, thus necessitating a change in the prevailing paradigm for ice-sheet evolution.