Abstract: High-resolution, time-significant correlations are integral to meaningful stratigraphic frameworks in depositional systems but may be difficult to achieve using traditional sequence stratigraphic or biostratigraphic approaches alone, particularly in geologically complex settings. In steep, reefal carbonate margin-to-slope systems, such correlations are essential to unravel shelf-to-basin transitions, characterize strike variability, and develop predictive sequence stratigraphic models—concepts that are currently poorly understood in these heterogeneous settings. The Canning Basin Chronostratigraphy Project integrates multiple independent data sets (including biostratigraphy, magnetostratigraphy, stable isotope chemostratigraphy, and sequence stratigraphy) extracted from Upper Devonian (Frasnian and Famennian) reefal platform exposures along the Lennard Shelf, Canning Basin, Western Australia. These were used to generate a well-constrained stratigraphic framework and shelf-to-basin composite reconstruction of the carbonate system. The resultant integrated framework allows for unprecedented analysis of carbonate margin-to-slope heterogeneity, depositional architecture, and sequence stratigraphy along the Lennard Shelf. Systems tract architecture, facies partitioning, and stacking patterns of margin to lower-slope environments were assessed for six composite-scale sequences that form part of a transgressive-to-regressive supersequence and span the Frasnian–Famennian (F–F) biotic crisis. Variations are apparent in margin styles, foreslope facies proportions, dominant resedimentation processes, downslope contributing sediment factories, and vertical rock successions, related to hierarchical accommodation signals and ecological changes associated with the F–F boundary. We present these results in the form of carbonate margin-to-basin sequence stratigraphic models and associations that link seismic-scale architecture to fine-scale facies heterogeneity. These models provide a predictive foundation for characterization of steep-sided flanks of reefal carbonate platform systems that is useful for both industry and academia. This study emphasizes the utility of an integrated stratigraphic approach and the insights gained from better-constrained facies and stratal architecture analysis, insights that were not achievable with traditional sequence stratigraphic or biostratigraphic techniques alone.

The redox state of the mid-Proterozoic oceans, lakes, and atmospheres is still debated, but it is vital for understanding the emergence and rise of macroscopic organisms and eukaryotes. The Appekunny Formation, Belt Supergroup, Montana, contains some of these early macrofossils dated between 1.47 Ga and 1.40 Ga and provides a well-preserved record of paleoenvironmental conditions. We analyzed the iron chemistry and mineralogy in samples from Glacier National Park, Montana, by pairing bulk rock magnetic techniques with textural techniques, including light microscopy, scanning electron microscopy, and synchrotron-based X-ray absorption spectroscopy. Field observations of the Appekunny Formation combined with mineralogical information allowed revised correlations of stratigraphic members across the park. However, late diagenetic and/or metasomatic fluids affected primary iron phases, as evidenced by prevalent postdepositional phases including base-metal sulfides. On the west side of the park, pyrrhotite and chlorite rims formed during burial metamorphism in at least two recrystallization events. These complex postdepositional transformations could affect bulk proxies for paleoredox. By pairing bulk and textural techniques, we show primary records of redox chemistry were preserved in early diagenetic and often recrystallized framboidal pyrite, submicron magnetite grains interpreted to be detrital in origin, and red-bed laminae interpreted to record primary detrital oxides. Based on these observations, we hypothesize that the shallow waters of the mid-Proterozoic Belt Basin were similar to those in modern marine and lacustrine waters: fully oxygenated, with detrital reactive iron fluxes that mineralized pyrite during organic diagenesis in suboxic, anoxic, and sulfidic conditions in sedimentary pore waters.

Abstract Two and three axis magnetometers based on RF-driven SQUIDS are now routinely used in the study of palesmagnetism. These magnetometers are both far more sensitive and much faster than any other type of rock magnetometer currently available; consequently they have made it possible to accurately measure the direction and intensity of the natural remanent magnetism in a large variety of otherwise unuseable sedimentary rocks. During the process of progressive demagnetization, however, many samples with an originally weak but apparently stable magnetic remanence become unmeasureable before the various magnetic components present have been resolved. Asimple theoretical analysis shows that the detrital magnetism from either biogenic or inorganic processes could have left geologically meaningful information in these samples, and implies that two or three orders of −14 magnetitude more sensitivity (down to about 10 −14 Joule/Tesla) might be of use. At this level, however, sample contamination from dust and other junk in the environment would become significant, requiring some form of air filtration in the laboratory. Similar facilities would be of use to detect small quantities of ferromagnetic minerals in animal tissue. * Department of Geological and Geophysical Sciences, Princeton University, Princeton, N.J. 08544 U.S.A.