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Sn-isotope fractionation as a record of hydrothermal redox reactions
Early Tertiary extensional magmatism in southern Mexico and its relationship to exhumation of the Xolapa complex and detachment of the Chortis block
CO 2 diffusion into pore spaces limits weathering rate of an experimental basalt landscape
CO 2 diffusion into pore spaces limits weathering rate of an experimental basalt landscape
Isotopic evidence for the provenance of turquoise in the southwestern United States
Re-Os AGE OF THE PUEBLO VIEJO EPITHERMAL DEPOSIT, DOMINICAN REPUBLIC
Pressure-temperature-time evolution of high-pressure rocks of the Acatlán Complex (southern Mexico): Implications for the evolution of the Iapetus and Rheic Oceans: Reply
Significance of Provenance Ages from the Chiapas Massif Complex (Southeastern Mexico): Redefining the Paleozoic Basement of the Maya Block and Its Evolution in a Peri-Gondwanan Realm
Geologic origins of salinization in a semi-arid river: The role of sedimentary basin brines
The Society of Economic Geologists Awards for 2006* R. A. F. Penrose Gold Medal for 2006 Citation of Stephen E. Kesler
Pressure-temperature-time evolution of Paleozoic high-pressure rocks of the Acatlán Complex (southern Mexico): Implications for the evolution of the Iapetus and Rheic Oceans
The sustained magmatic activity along the North American Cordillera during late Mesozoic and Paleogene times produced the emplacement of numerous porphyry copper deposits. This activity extended by most of western México, particularly along the northwestern part of the country. This region, along with Arizona and New Mexico in the United States, contains one of the most important centers of copper mineralization on Earth. Most of the Mexican deposits lie in the eastern part of the Laramide magmatic belt (90–40 Ma) and were formed predominantly between 75 and 50 Ma. The largest deposits occur in northeastern Sonora and are represented by Cananea (∼30 Mt Cu) and La Caridad (∼8 Mt Cu). The copper ores are locally accompanied by molybdenum, tungsten, gold, and other metals. However, the metal distribution is apparently coupled with major changes in the basement of emplacement, which can be roughly separated into three domains: a northern domain characterized by Proterozoic crystalline rocks of North American affinity; a central domain composed of Paleozoic deep-marine basin rocks underlain by the Proterozoic North American rocks; and a southern domain, represented by Mesozoic island-arc–related sequences of the Guerrero terrane. Sr and Nd isotopic data from Laramide plutons along these domains suggest that the basement modified the final composition of the Laramide magmas. Also, the basement seems to have partly controlled the metal commodities along the porphyry copper belt, with relatively larger deposits characterized by Cu-Mo-W mineralization in the northern and central domains, and smaller and more Cu-Au dominated systems in the southern (more oceanic) domain.
Geologic evolution of the Xolapa Complex, southern Mexico: Evidence from U-Pb zircon geochronology: Reply
Laramide Porphyry Cu-Mo Mineralization in Northern Mexico: Age Constraints from Re-Os Geochronology in Molybdenite
Abstract Combined isotopic dating indicates five episodes of felsic intrusion within the El Teniente orebody: (1) Sewell stock and other quartz diorite-tonalite intrusions of the eastern part crystallized from 6.46 ± 0.11 to 6.11 ± 0.13 Ma (zircon U-Pb); (2) quartz diorite-tonalite, immediately southeast of the orebody, with biotite 40 Ar/ 39 Ar plateau ages of 5.63 ± 0.12 and 5.47 ± 0.12 Ma—these ages agree with a hydrothermal overprint on zircons from the intrusions of the previous episode at 5.67 ± 0.19 to 5.48 ± 0.19 Ma (U-Pb); (3) Teniente dacite porphyry crystallized at 5.28 ± 0.10 Ma (zircon U-Pb); (4) a dacite ring dike encircling the Braden pipe crystallized at 4.82 ± 0.09 Ma (zircon U-Pb); and (5) minor dacite intrusions and dikes yielded a biotite 40 Ar/ 39 Ar plateau age of 4.58 ± 0.10 Ma, and sericite 40 Ar/ 39 Ar plateau ages of 4.56 ± 0.12 to 4.46 ± 0.10 Ma. All these felsic intrusions were emplaced within country rocks of late Miocene according to an apatite fission-track age of 8.9 ± 2.8 Ma for a mafic sill, in accord with previous K-Ar ages of 12.0 ± 0.7 to 6.6 ± 0.4 Ma for volcanic rocks from the district. Molybdenite Re-Os dating at El Teniente revealed ore deposition at 6.30 ± 0.03, 5.60 ± 0.02, 5.01 to 4.96, 4.89 ± 0.08 to 4.78 ± 0.03, and 4.42 ± 0.02 Ma, concurrent with the five intrusive episodes. The Re-Os system for molybdenite was unaffected by the various hydrothermal episodes. In contrast, the 40 Ar/ 39 Ar system of micas was reset by high-temperature (>350°C) fluid circulation and provides only a partial record of the latest history of development of this supergiant ore-forming system; biotite, sericite, and altered whole-rock samples collected throughout the orebody yielded 40 40 Ar/ 39 Ar plateau ages ranging from 5.06 ± 0.12 to 4.37 ± 0.10 Ma. These ages reveal a period of hydrothermal activity, which extended either continuously or episodically, for at least 0.69 ± 0.22 m.y. (±2σ) and that comprises a succession of three episodes of ore deposition. Separate hydrothermal episodes are thus interpreted to have lasted <0.69 ± 0.22 m.y. The Braden breccia pipe in the center of the deposit was formed as a single synmineralization event, probably related in time to the injection of the dacite ring dikes at 4.82 ± 0.09 Ma (zircon U-Pb). It was followed by quartzsericite alteration within and peripheral to, the pipe from 4.81 ± 0.12 to 4.37 ± 0.10 Ma (sericite 40 Ar/ 39 Ar). The successive intrusions of felsic bodies and their respective crystallization processes were immediately followed by genetically related, short-lived episodes of ore deposition, each associated with hydrothermal alteration. This multistage evolution, inferred from systematic dating, was not apparent from previous geochronologic data and is inferred to have contributed to the enormous volume and richness of the El Teniente. Thermal modeling of apatite fission-track data suggests that the porphyry system cooled very rapidly to temperatures below 105° ± 20°C, most likely before the intrusion of a postore hornblende-rich andesitic dike at 3.85 ± 0.18 Ma (hornblende 40 Ar/ 39 Ar). This dike cuts the southern part of the El Teniente deposit and marks the end of igneous activity in the orebody.