Abstract The Late Palaeozoic deposits in Croatia were derived from the Palaeotethyan shelf areas along the northern Gondwana passive continental margin and consist of mixed carbonate–clastic facies. These sedimentary rocks accumulated in the equatorial area along northern Gondwana under a dominantly hot climate and laid the foundations for the future Adriatic Carbonate Platform (AdCP). Detailed classification and geochemical studies of the Permian and Permian–Triassic deposits in most parts of Croatia are still in progress, especially concerning palaeoclimate and regional palaeogeography. The best preserved Permian outcrops can be found in the Velebit mountain area, including continuous Permian–Triassic sections. Stable isotopes of carbon and oxygen from carbonates, with characteristic positive δ 13 C carb excursion during the Late Permian and negative δ 13 C carb excursion at the Permian–Triassic transition combined with palaeontological and sedimentological data, helped in palaeoclimate estimations and the positioning of the chemostratigraphical Permian–Triassic Boundary (PTB). Sedimentological, palaeontological and geochemical data indicate that deposition in the Permian took place mainly in shallow-water tropical areas under oligotrophic conditions. High carbon isotope ratios in Capitanian carbonate rocks (+4 to +6‰ VPDB) mark the ‘Kamura event’ characterized by temporary cooling, high productivity and burial rate. Evaporites in the central part of the Karst Dinarides and red beds of the ‘Gröden type’ indicate a warm and mostly arid climate. Calculations based on the oxygen isotopic compositions of whole-rock carbonate and fossil samples estimate latest Permian temperatures up to 26 °C.