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Slow changes in lava chemistry at Kama‘ehuakanaloa linked to sluggish mantle upwelling on the margin of the Hawaiian plume
CO 2 content beneath northern Iceland and the variability of mantle carbon
New SIMS reference materials for measuring water in upper mantle minerals
Subducted lithosphere controls halogen enrichments in the Iceland mantle plume source
Crystal/melt partitioning of water and other volatiles during the near-solidus melting of mantle peridotite: Comparisons with non-volatile incompatible elements and implications for the generation of intraplate magmatism
Experimental investigation of F, Cl, and OH partitioning between apatite and Fe-rich basaltic melt at 1.0–1.2 GPa and 950–1000 °C
Quantification of water in majoritic garnet
Bubbles matter: An assessment of the contribution of vapor bubbles to melt inclusion volatile budgets
Volatile abundances of coexisting merrillite and apatite in the martian meteorite Shergotty: Implications for merrillite in hydrous magmas
Pre-eruptive vapour and its role in controlling eruption style and longevity at Soufrière Hills Volcano
Abstract We use volatiles in melt inclusions and nominally anhydrous phenocrysts, with volcanic gas flux and composition, and textural analysis of mafic inclusions to estimate the mass of exsolved vapour prior to eruption at Soufrière Hills Volcano (SHV). Pre-eruptive andesite coexists with exsolved vapour comprising 1.6–2.4 wt% of the bulk magma. The water content of orthopyroxenes indicates a zone of magma storage at pressures of approximately 200–300 MPa, whereas melt inclusions have equilibrated at shallower pressures. Inclusions containing >3 wt% H 2 O are enriched in CO 2 , suggesting flushing with CO 2 -rich gases. Intruding mafic magma contains >8 wt% H 2 O at 200–300 MPa. Rapid quenching is accompanied by crystallization and vesiculation. Upon entrainment into the andesite, mafic inclusions may undergo disaggregation, where expansion of volatiles in the interior overcomes the strength of the crystal frameworks, thereby recharging the vapour content of the andesite. Exsolved vapour may amount to 4.3–8.2 vol% at 300 MPa, with implications for eruption longevity and volume; we estimate the magma reservoir volume to be 60–200 km 3 . Exsolved vapour may account for the small volume change at depth during eruptions from geodetic models, and has implications for magma flow: exsolution is likely to be in equilibrium during rapid magma ascent, with little nucleation of new bubbles.