ABSTRACT A 3 ton (2.7 metric tonnes [t]), granitoid lonestone with Appalachian provenance was found in situ in offshore Devonian black shale in northeastern Kentucky, United States, and is denoted herein as the Robinson boulder, or lonestone, after its discoverer, Michael J. Robinson. This large boulder appears to have been displaced nearly 500 km from its source on the opposite margin of the Acadian/Neoacadian Appalachian foreland basin. While previous identifications of possible lonestones have been attributed to Pleistocene glacial events, scrutiny of this lonestone’s origin suggests that the boulder, which was embedded in the Upper Devonian Cleveland Shale Member of the Ohio Shale in northeastern Kentucky, is most likely a Devonian ice-rafted glacial dropstone. Notably, palynologic correlation with reported glacial diamictites elsewhere in the basin indicates such a source. Together, the dropstone and diamictites, separated by ~500 km, provide evidence for alpine glaciation in the ancient Acadian/Neoacadian orogen and for tidewater glaciers in the adjacent, eastern margin of the foreland basin. The latest Devonian marine transgression and Neoacadian foreland subsidence are interpreted to have been associated with tidewater glacial connections to the open sea. Importantly, the existence of this dropstone and its likely glacial precursor events require new considerations about contemporary black-shale sedimentation and the influence of tectonics on the delivery of glacial sediments to foreland basins.

Abstract Each year an estimated 56,000 metric tons (t) of rare earth elements (REEs), including 23,000 t of heavy REEs (HREEs), are mined, beneficiated, and put into solution, but not recovered, by operations associated with the global phosphate fertilizer industry. Importantly, the REEs in sedimentary phosphorites are nearly 100% extractable, using technologies currently employed to meet global phosphate fertilizer needs. Our evaluation suggests that by-product REE production from these phosphate mines could meet global REE requirements. For example, the calculated REE flux accompanying phosphate production in the United States is approximately 40% of the world’s total and, alone, could supply 65% of global HREEs needs. Moreover, recognition that the tonnages and HREE concentrations of some unmined phosphorite deposits dwarf the world’s richest REE deposits suggests that these deposits might constitute stand-alone REE deposits. The hypothesized genesis of these REE-rich occurrences strongly supports the long-debated suggestion that oceanic REE contents vary in a secular fashion and that associated high-grade REE abundances reflect oceanic redox state transitions during specific time periods. Here, we use this new process-based model, based on observed variations in global-secular REE abundances, to identify phosphorite horizons deposited during periods favorable for highgrade REE accumulation.