Abstract The IUGS- and UNESCO-funded International Geoscience Programme Project #512 (Neoproterozoic Ice Ages) was conceived to contribute towards a global synthesis of current geological data on the number, duration, extent, causes and consequences of glacial episodes during the Neoproterozoic Era. IGCP 512 attracted more than 200 scientists from over 30 countries, many of whom provided their regional and specialist expertise on Neoproterozoic successions around the world to the realization of this volume. IGCP 512 focused on integrating various aspects of Neoproterozoic geology: geochronology, geochemistry, sedimentary geology, biostratigraphy, palaeomagnetism and economic geology. At its inaugural meeting on 27 August 2005 during the International Association of Sedimentology conference on glacial processes and products in Aberystwyth, Wales, IGCP 512 members decided to produce a volume that summarized existing data sets in a form similar to Earth's Pre-Pleistocene Glacial Record by Hambrey & Harland (1981) . An enormous amount of work has been carried out in the 12 years since the publication of Hoffman et al. 's (1998) paper on the Snowball Earth hypothesis for Neoproterozoic glaciation ( Fairchild & Kennedy 2007 ). The Snowball Earth hypothesis and, more generally, Neoproterozoic climate, have been the topic of numerous special volumes, special sessions, a dedicated conference in Ascona (Switzerland) in 2006 ( Shields 2006 ), and numerous documentaries. Motivated by this intense worldwide interest in the Neoproterozoic glaciations and an exploding body of research into the topic, this volume synthesizes the state-of-the-art in this now highly multidisciplinary research field. It is intended to facilitate

Abstract Neoproterozoic glacial records have been discovered on 23 palaeocontinents, their rate of discovery changing little since 1871. Yet, half of all the resulting publications appeared since 2000. The history of research before 1998 is described in five stages defined by publication spikes; subsequent work is not covered because historical perspective is lacking. In stage 1 (1871–1907), ‘Cambrian’ (now Neoproterozoic) glaciation was recognized successively in Scotland, Australia, India, Norway, Svalbard and China. Criteria for recognition included faceted and striated pebbles in matrix-supported conglomerates resting on ice-worn bedrock pavements. In stage 2 (1908–1940), Neoproterozoic glaciation was shown to have been widespread in Africa, Asia and the Americas. Major textbooks summarized these findings, but the rejection of continental drift (to account for late Palaeozoic glacial dynamics) put a chill on research. In stage 3 (1942–1964), the occurrence of glacial deposits within carbonate successions, as well as nascent palaeomagnetic observations, suggested that Neoproterozoic glaciers reached sea-level at low palaeolatitudes, but the belated recognition of sediment gravity flowage caused glacial interpretations to be prematurely abandoned in key areas. In stage 4 (1965–1981), the extent of Neoproterozoic glaciation was rethought in light of plate tectonics. Distinctive chemical sediments (iron±manganese formations and cap carbonates) were identified. In basic climate models, modest lowering of solar luminosity resulted in global glaciation due to ice-albedo feedback, and deglaciation due to greenhouse forcing resulted from silicate-weathering feedback in the carbon cycle. Neoproterozoic glacial geologists were blind to these ideas. In stage 5 (1982–1997), reliable palaeomagnetic data combined with glacial marine sedimentation models confirmed that Neoproterozoic ice sheets reached sea level close to the palaeoequator.

Abstract This chapter provides an overview and key references of glacial processes and resulting sedimentary products in subglacial, terrestrial proglacial and glaciomarine or glaciolacustrine settings. These settings are characterized by a wide variety of processes ranging from subglacial lodgement and deformation, ice-push and sediment remobilization, which in turn result in a wide range of products such as diamictite, conglomerate, sandstone, siltstone and mudstone. The sedimentary record of proglacial settings exhibits the most lateral and vertical variability due to the dynamic nature of ice margins and the most direct record of climatic fluctuations. Many Neoproterozoic successions, however, preserve glaciomarine deposits that can provide a more continuous and high-resolution (though indirect) record of change. This chapter will enable the reader to identify features that may be used to infer a glacial influence on the formation of ancient deposits. The chapter also outlines some of the important issues that require consideration when evaluating palaeoclimatic models for Neoproterozoic sedimentary successions. These include the equivocal significance of most commonly used proxies such as occurrence of diamictite, outsized clasts in laminated sediments, clast characteristics, lithostratigraphic trends and sequence boundaries. Careful analysis of multiple lines of sedimentary evidence, together with other proxies of climatic changes, can yield meaningful reconstructions and provide a basis for testing palaeoclimate models for this time period. A summary table outlining the characteristics of diamictite with different depositional origins is also included in order to assist with the interpretation of the Neoproterozoic sedimentary record.

Abstract Although the pre-glacial Proterozoic isotopic record is poorly constrained, it is apparent that the chemical and isotopic composition of the oceans began to change during the early to mid-Neoproterozoic and experienced considerable fluctuations alongside climatic instability during much of the subsequent Cryogenian and Ediacaran periods. The earliest known large negative δ 13 C excursion appears to post-date 811 Ma and fluctuations became progressively more extreme, culminating in the late-Ediacaran ‘Shuram–Wonoka’ anomaly. The negative excursions are commonly associated with pre-glacial and post-glacial times, while extremely high δ 13 C values are characteristic of strata between glaciations. The precise causal mechanism for these excursions is subject to debate. Seawater 87 Sr/ 86 Sr rose during the Neoproterozoic, with abrupt increases following deglaciation consistent with enhanced weathering rates. Reported marine sulphate and pyrite δ 34 S data exhibit marked variation through this interval, although the changes are not always consistent within or between sedimentary successions of equivalent age. Iron-speciation studies indicate that much of this variation was caused by fluctuating and low sulphate concentrations in seawater, which at times led to the build-up of ferruginous conditions in the ocean. The application of chemostratigraphy to understanding and correlating the Neoproterozoic glaciations evokes considerable controversy, and many questions persist regarding the reliability and calibration of the δ 13 C, 87 Sr/ 86 Sr and δ 34 S record. Nevertheless, the individual glaciations appear to be characterized by distinct combined chemostratigraphic signatures, in large part due to the generally increasing strontium isotope composition of seawater through the Neoproterozoic Era.

Abstract Orthochemical sediments associated with Neoproterozoic glaciation have prominence beyond their volumetric proportions because of the insights they provide on the nature of glaciation and the records they hold of the environment in which they were precipitated. Synglacial Fe formations are mineralogically simple (haematite jaspilite), and their trace element spectra resemble modern seawater, with a weaker hydrothermal signature than Archaean–Palaeoproterozoic Fe formations. Lithofacies associations implicate subglacial meltwater plumes as the agents of Fe(II) oxidation, and temporal oscillations in the plume flux as the cause of alternating Fe- and Mn-oxide deposits. Most if not all Neoproterozoic examples belong to the older Cryogenian (Sturtian) glaciation. Older and younger Cryogenian (Marinoan) cap carbonates are distinct. Only the younger have well-developed transgressive cap dolostones, which were laid down during the rise in global mean sea level resulting from ice-sheet meltdown. Marinoan cap dolostones have a suite of unusual sedimentary structures, indicating abnormal palaeoenvironmental conditions during their deposition. Assuming the meltdown of ice-sheets was rapid, cap dolostones were deposited from surface waters dominated by buoyant glacial meltwater, within and beneath which microbial activity probably catalysed dolomite nucleation. Former aragonite seafloor cement (crystal fans) found in deeper water limestone above Marinoan cap dolostones indicates carbonate oversaturation at depth, implying extreme concentrations of dissolved inorganic carbon. Barite is associated with a number of Marinoan cap dolostones, either as digitate seafloor cement associated with Fe-dolomite at the top of the cap dolostone, or as early diagenetic void-filling cement associated with tepee or tepee-like breccias. Seafloor barite marks a redoxcline in the water column across which euxinic Ba-rich waters upwelled, causing simultaneous barite titration and Fe(III) reduction. Phosphatic stromatolites, shrub-like structures and coated grains are associated with a glacioisostatically induced exposure surface on a cap dolostone in the NE of the West African craton, but this appears to be a singular occurrence of phosphorite formed during a Neoproterozoic deglaciation.

Abstract The Chemical Index of Alteration (CIA) is the most accepted of available weathering indices. Past conditions of physical and chemical weathering can be reliably inferred if application of the CIA is combined with a comprehensive facies analysis. When applied to the reconstruction of climate conditions during Neoproterozoic times, CIA data provide crucial insights into the changes in the relative contributions of chemical and physical weathering in the production of sedimentary detritus. CIA data are thus instrumental not only in documenting changes between icehouse and greenhouse climates, but also in recognizing shorter-term climate oscillations between glacial and warm–humid conditions. Concerning the Neoproterozoic glacial periods, sedimentological and CIA data sets give strong evidence of a functioning hydrological cycle, operative sediment routing systems, and variable climate conditions oscillating between dry–cool and glacial, and warm–humid and interglacial. These findings are incompatible with the hypothesis of a totally ice-covered Snowball Earth.

Abstract New stratigraphic, geochronological and palaeomagnetic constraints allow updates to be made to a synthesis of Neoproterozoic glacial palaeolatitudes, including modifications to some reliability estimates. The overall pattern of a Neoproterozoic climatic paradox persists: there is an abundance of tropical palaeolatitudes and near to complete absence of glaciogenic deposits demonstrably laid down between latitudes of 60° and 90°. In addition to 12 units with palaeolatitude estimates that are somewhat reliable, estimates with moderate to high reliability now include Konnarock (less than 10° from the palaeo-equator), Elatina, Rapitan, Mechum River, Grand Conglomerat (10–20°), Upper Tindir, Puga (20–30°), Nantuo, Gaskiers (30–40°) and Walsh (40–50°). Among these, Elatina, Upper Tindir and Nantuo are considered to have the highest reliability, all with estimates of low to moderate palaeolatitude. The Elatina result stems from sedimentary rocks with quantitative correction of inclination-shallowing effects, and the Upper Tindir result stems from data collected from igneous rocks that are precisely coeval with the glacial deposits. Despite continuing debate on the global character of Neoproterozoic ice ages, their pan-glacial extent (ice extending to low latitude in a low-obliquity world) is well demonstrated.

Abstract Cryogenian correlation in Australia is based on an extensive data set from the Centralian Superbasin and Adelaide Rift Complex and integrates biostratigraphy and isotope chemostratigraphy to provide a three-dimensional interpretation based on outcrop and drill holes. Studies are ongoing, but newer data are consistent with the distributions discussed here. From the chemostratigraphic and biostratigraphic viewpoint, the first appearance of the acritarch Cerebrosphaera buickii , coupled with a large negative isotope excursion at c. 800 Ma, supported by the first appearance of the stromatolite Baicalia burra , seems to have potential for boundary placement. It is widely recognized across Australia and seems to have potential globally.

Abstract Geochronology is essential for understanding Neoproterozoic Earth history. Here we review the types of rocks and minerals that are used to date geologic events and the analytical protocols for the different radio-isotopic decay systems employed. We discuss the limitations and potential of these methodologies for dating Neoproterozoic stratigraphy, highlighting the major sources and magnitudes of uncertainties and the assumptions that often underpin them.

Abstract We review most of the modelling studies performed to date to understand the initiation and melting of a Snowball Earth, as well as to describe the glacial environment during the glaciation itself. All the described scenarios explaining the onset of glaciation rely on a sufficient decrease in the concentrations of atmospheric greenhouse gases (GHGs), typically resulting from the equatorial palaeogeography of the late Proterozoic. It is still heavily debated whether or not the oceanic ice cover was thick during the glaciation itself. However, a consensus has arisen that the most climatically stable scenarios imply the existence of a globally frozen ocean, with a thick ice cover caused by the flowing of high-latitude sea-ice glaciers towards the equator. Depending on the characteristics of the ice, a thin ice layer may have persisted along the equator, but this numerical solution is rather fragile. During the snowball event itself, model results suggest the existence of wet-based continental glaciers. Some parts of the continents may have remained ice-free. From the modelling perspective, the most significant problem in the snowball hypothesis, particularly in its ‘hard snowball’ version (the most stable numerically), is the melting phase. With improved modelling, the CO 2 threshold required to melt the snowball is much higher than initially thought, significantly above 0.29 bar. Indeed, because of the very cold conditions prevailing at the surface of the Earth during the glacial event, the atmosphere becomes vertically isothermal, strongly limiting the efficiency of the greenhouse effect. This melting problem is further highlighted by geochemical modelling studies that show that weathering of the oceanic crust might be an active sink of CO 2 during the glacial event, limiting the rise in atmospheric CO 2 . The solution might be found by considering the input of dark dust from catastrophic volcanic eruptions that would efficiently decrease the albedo of the ice. Finally, modelling studies also explore the aftermath of the glaciation. The world might have been drier than initially anticipated, resulting in the persistence of the supergreenhouse effect for at least one million years after the melting phase.

Abstract The Taoudéni Basin covers over 1 000 000 km 2 of the West African Craton, bounded by Pan-African orogenic belts. Four supergroups separated by craton-scale unconformities are recognized, with Neoproterozoic glaciogenic deposits occurring at the base of Supergroup 2. The Jbéliat Group occurs along a continuous, 1300-km-long, narrow belt from the Adrar region of Mauritania to the eastern limit of the Hank in Algeria and comprises thin glacial drift capped widely by periglacial polygonal structures, with more complex glacial sequences preserved in palaeo-depressions. A thicker, variously marine and continental glaciogenic succession can be found in southern parts, while fully marine, glacially influenced successions are only known from the extreme SW of the basin. The ‘triad’ sequence of diamictites overlain by barite-bearing ‘cap’ dolostones and then by green shales and/or bedded cherts (silexites) is ubiquitous and has long been used to correlate the Supergroup 1/2 boundary across the basin and into the surrounding orogenic belts. The bedded cherts commonly show a volcanic influence and are cemented by early marine calcite at their base at Adrar, Mauritania. Although fossil-based age constraints are scarce and ambiguous, regional tectonic events indicate that ‘triad’ deposition occurred between the Bassaride (665–655 Ma) and Dahomeyide (610–580 Ma) orogens. Recent U–Pb zircon studies of ignimbrite tuffs provide a minimum age for the glaciation of c. 600 Ma. Correlation of supergroup 2 glacial deposits with the c. 635 Ma end-Cryogenian (‘Marinoan’) glaciation is likely and is supported by limited carbon and strontium isotope data. Barite is commonly found within the cap carbonate and may relate to methane seepage and/or unusual oceanographic conditions after deglaciation. Several studies have attributed sequence complexity within the post-glacial succession to isostatic reequilibration. The Taoudéni Basin represents a rare Neoproterozoic example of terrestrial tillites and associated periglacial facies.

Abstract Glaciogenic sediments of the Katanga Supergroup are represented by two units. The syn-rift Grand Conglomerat Formation (<765±5 Ma to >735±5 Ma) occurs within the Nguba Group, and the Petit Conglomerat Formation defines the base of the Kundelungu Group deposited in the earliest foreland basin of the Lufilian orogenic belt located between the Congo and Kalahari cratons. Their glacial origin is inferred on the basis of the following features: the common and widespread occurrence of thick polymictic conglomerates and diamictites with faceted and striated clasts, massive structure, abundant poorly sorted fine-grained matrix, and the presence of planar-laminated shales (laminites) with dropstones. Glaciomarine facies associations prevail over most of the geographic extent of both units, but at the northern periphery of the depository, continental glacial facies are present. The glaciomarine units are succeeded by carbonates: the Kakontwe Limestone and ‘Calcaire Rose’ respectively. The clasts in the glaciogenic units are of extrabasinal and intrabasinal provenance. Lower boundaries, conformable in the basin centre, evolve to unconformities in the marginal areas to the N and S. The palaeomagnetic evidence suggests deposition in low latitudes.

Abstract The focus of this chapter is the West Congo Supergroup in the West Congo Belt (WCB), which extends along the western margin of the Congo Craton from Gabon in the north to northern Angola in the south, and the Lindi/Ubangi Supergroup of the Lindian and Fouroumbala – Bakouma Basins exposed on the northern margin of the craton. In both regions, up to two distinct diamictite horizons have been recognized, the younger of which is often associated with carbonate rocks. Geochronological constraints are generally rather poor, many of the deposits lack modern sedimentological analysis, and the glacial versus non-glacial genesis of the diamictites is a matter of debate in the literature. However, recent studies suggest a periglacial influence of diamictite deposition, particularly for the sequences in the WCB. The stratigraphy of the various basins is described, available geochemical and geochronological information collated, and recent work regarding the periglacial nature of the diamictites discussed. Finally, an updated chronostratigraphic correlation between the basins is presented. However, much more work is required, particularly in the Neoproterozoic basins on the northern margin of the Congo Craton, and more accurate geochronological constraints are required before the Neoproterozoic palaeogeography and depositional environments of the western and northern Congo Craton can be fully understood.