Abstract Orogenic gold systems are open, flow-controlled thermodynamic systems and generally occur in mid- to upper crustal environments where there is strong coupling between fluid flow and dilatant plastic deformation. This paper considers the principles involved in such coupling, with an emphasis on the elastic and plastic volume changes and their influence on the fluid, mechanical and thermodynamic pressures. Some misconceptions regarding the magnitudes of these three distinctly different pressures and their influences on fluid flow and chemical equilibrium are addressed, with examples at both the tens of metres scale and the crustal scale. We show that the mean stress is less than twice the lithostatic stress for Mohr–Coulomb materials with cohesion and the thermodynamic pressure only has meaning under isentropic conditions and hence is less than many previously published estimates based on high mean stresses. At the crustal scale, we also include the role of critical behaviour in influencing the geometry and magnitudes of fluid pressure gradients and fluid flow velocities in open, flow-controlled systems.

Abstract Episodic fluctuations in fluid pressure and temperature are characteristic of the behaviour of orogenic gold systems and are commonly attributed to processes external to the system, such as seismic events and associated adiabatic fault valve or suction pump/piston behaviour; any temperature changes are attributed to the adiabatic nature of the process. Such processes are commonly associated with fluctuations in fluid pressure with little, if any, changes in temperature. We describe aseismic, non-adiabatic processes internal to the hydrothermal system that lead to episodic modes of temperature and fluid pressure behaviour and the deposition of gold. These gold deposition processes are essentially controlled by localized changes in temperature; such temperature-dependent gold deposition processes are normally thought of as inconsequential. We propose that internal episodic behaviour is fundamental in hydrothermal mineralizing systems associated with orogenic gold deposits. Importantly, the time period for these hydrothermal events appears to be small relative to metamorphic systems, with 1–2 myr as an upper limit. This has important ramifications for rates of heat production and for the resultant kinetics of mineral reactions during alteration and mineralization. We explore these systems as non-linear, non-equilibrium dynamic, open flow systems.

Abstract Coupling between the physical processes intrinsic to a hydrothermal system can lead to episodic and chaotic behaviour. Such behaviour includes variations in both space and time of the temperature, fluid pressure and activity of H 2 S, which result in the deposition of alteration mineral assemblages, zoned pyrite and gold; these variations are multifractal. In particular, the coupling of deformation and simultaneous endothermic and exothermic reactions with fluid flow leads to the highly localized deposition of gold. We discuss the physical and chemical mechanisms for such episodic and localization behaviour and explore the non-linear dynamic reasons why such mechanisms are recorded in the multifractal paragenetic sequence and deformation history. The synchronization of intrinsic episodicity as described here and extrinsic forcing induced by episodic seismicity provides another mechanism for enhancing the yield of gold deposition processes and hence the grade of orogenic gold deposits.

Abstract The spatial distributions of mineralization and alteration in hydrothermal systems are complex and are often considered to be cryptic and problematic to quantify. We used wavelet analysis of conventional hyperspectral drillcore logs to demonstrate quantitatively that primary Au mineralization, common vein-hosted mineralogy (calcite and ankerite), host rock alteration mineralogy (sericite and chlorite) and regional-scale metamorphic assemblages (amphibole) organize spatially as multifractals. This documentation of multifractal spatial organization in Au and alteration mineralogy is sufficient to show that they are the result of underlying deterministic dynamic processes as opposed to random stochastic processes. The application of wavelets to three ore bodies (GQ, Vogue and Cosmo East) from the highly endowed Archaean Sunrise Dam hydrothermal Au system of Western Australia shows that the spatial organizations of Au and ankerite are more closely associated in GQ than in Vogue. The spatial organization of Au in Vogue is more strongly associated with calcite. Primary Au mineralization and infill carbonate mineralogy are more complexly organized than sericitic and chloritic host rock alteration. Although demonstrated here for a hydrothermal system, wavelet analysis is readily applicable to downhole or outcrop data from any deposit type.

Abstract The inter-relationships between mineral reactions and deformation are explored with a view to understanding the development of certain mineral foliations and lineations. The following arguments are presented: (i) the processes involved during mineral reactions in deforming metamorphic rocks are described by coupled reaction–diffusion–deformation equations; (ii) these reactions can become unstable producing compositional patterning in both space (metamorphic differentiation) and time (compositional zoning); (iii) the patterns (foliations and mineral lineations) that result from coupled reaction–diffusion–deformation equations are described by surfaces that approximate minimal surfaces (surfaces of zero mean curvature) and an example of such geometry is given; and (iv) the foliations and mineral lineations that form by such processes are controlled by the evolution of the kinematics of the deformation history and not by the finite strain tensor.

Abstract Feedback relations between deformation and metamorphic mineral reactions, derived using the principles of non-equilibrium thermodynamics, indicate that mineral reactions progress to completion in high-strain areas, driven by energy dissipated from inelastic deformation. These processes, in common with other time-dependent geological processes, lead to both strain, and strain-rate, hardening/softening in rate-dependent materials. In particular, strain-rate softening leads to the formation of shear zones, folds and boudins by non-Biot mechanisms. Strain-softening alone does not produce folding or boudinage and results in low-strain shear zones; strain-rate softening is necessary to produce realistic strains and structures. Reaction–mechanical feedback relations operating at the scale of 10–100 m produce structures similar to those that arise from thermal–mechanical feedback relations at coarser (kilometre) scales and reaction–diffusion–mechanical feedback relations at finer (millimetre) scales. The dominance of specific processes at various length scales but the development of similar structures by all coupled processes leads to scale invariance. The concept of non-equilibrium mineral stability diagrams is introduced. In principle, deformation influences the position of mineral stability fields relative to equilibrium stability fields; the effect is negligible for the quartz → coesite reaction but may be important for others. Application of these results to the development of structures and mineral reactions in the Italian Alps is discussed.