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NARROW
GeoRef Subject
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all geography including DSDP/ODP Sites and Legs
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Atlantic Ocean
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North Atlantic (1)
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Europe
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Western Europe
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France
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Pas-de-Calais France
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Boulonnais (2)
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United Kingdom
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Great Britain
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England
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Yorkshire England (1)
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Wales
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Pembrokeshire Wales (1)
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commodities
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petroleum (1)
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elements, isotopes
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carbon
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C-13/C-12 (1)
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chemical ratios (1)
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isotope ratios (1)
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isotopes
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stable isotopes
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C-13/C-12 (1)
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O-18/O-16 (1)
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metals (1)
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oxygen
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O-18/O-16 (1)
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trace metals (2)
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geochronology methods
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geologic age
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Cenozoic
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Quaternary
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Pleistocene (1)
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Mesozoic
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Jurassic
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Upper Jurassic
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Kimmeridge Clay (1)
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Kimmeridgian (1)
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Tithonian (1)
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Paleozoic
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Carboniferous
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Mississippian
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Upper Mississippian (1)
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minerals
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silicates
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sheet silicates
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clay minerals
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smectite (1)
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Primary terms
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Atlantic Ocean
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North Atlantic (1)
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carbon
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C-13/C-12 (1)
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Cenozoic
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Quaternary
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Pleistocene (1)
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diagenesis (1)
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Europe
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Western Europe
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France
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Pas-de-Calais France
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Boulonnais (2)
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United Kingdom
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Great Britain
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England
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Yorkshire England (1)
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Wales
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Pembrokeshire Wales (1)
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geochemistry (1)
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isotopes
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stable isotopes
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C-13/C-12 (1)
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O-18/O-16 (1)
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Mesozoic
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Jurassic
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Upper Jurassic
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Kimmeridge Clay (1)
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Kimmeridgian (1)
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Tithonian (1)
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metals (1)
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oxygen
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O-18/O-16 (1)
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paleoecology (1)
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paleomagnetism (1)
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Paleozoic
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Carboniferous
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Mississippian
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petroleum (1)
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sea-level changes (1)
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sedimentary rocks
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carbonate rocks
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limestone (1)
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chemically precipitated rocks
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sedimentary structures
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planar bedding structures
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sediments
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marine sediments (1)
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weathering (1)
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sedimentary rocks
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calcrete (1)
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sedimentary rocks
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carbonate rocks
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limestone (1)
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chemically precipitated rocks
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evaporites (1)
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clastic rocks
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shale (1)
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sedimentary structures
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sedimentary structures
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planar bedding structures
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laminations (1)
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sediments
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sediments
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carbonate sediments (1)
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marine sediments (1)
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Late Mississippian limestone sedimentary environment in southern Pembrokeshire (Bullslaughter Bay, Wales): evidence of meteoric diagenesis and hypersaline features
Small-scaled lateral variations of an organic-rich formation in a ramp-type depositional environment (the Late Jurassic of the Boulonnais, France): impact of the clastic supply
Abstract Abstract: In the Kimmeridge Clay Formation of the Wessex–Weald Basin, five organic-matter-rich intervals (ORIs), dated from Kimmeridgian–Tithonian times, can be correlated from distal depositional environments in Dorset and Yorkshire (UK) to the proximal environments in Boulonnais, northern France. The ORIs are superimposed on a meter-scale cyclic distribution of organic matter (OM), referred to as primary cyclicity, which is commonly interpreted to result from Milankovitch climate forcing. The present work addresses the distribution of redox-sensitive and/or sulfide-forming trace metals and selected major elements (Si, Al, and Fe) in Kimmeridge Clay shales from the Cleveland Basin (Yorkshire) and the Boulonnais cliffs with two objectives: (1) to determine whether the ORIs formed in similar paleoenvironments, and (2) to identify the mechanism(s) of OM accumulation. High-resolution geochemical data from primary cycles in the Yorkshire boreholes (Marton and Ebberstone boreholes) were studied and the results are then applied with lower-resolution sampling at the ORI scale in the Flixton borehole and Boulonnais cliff. Good correlations are found between total organic carbon (TOC) vs. Cu/Al and Ni/Al, but relationships between TOC and Mo/Al, V/ Al and U/Al are more complex. Cu and Ni enrichment is interpreted to have resulted from passive accumulation with OM in an oxygen-deficient basinal setting, which prevented the subsequent loss of Cu and Ni from the sediment. Mo and V were significantly enriched only in sediments where considerable amounts of OM (TOC > 7%) accumulated, the result of strongly reducing conditions and OM burial. At the scale of the Flixton ORIs, the samples with the highest Mo and V concentrations also show relative Fe enrichment, suggesting pyrite formation in the water column (combination of euxinic conditions and presumably low sedimentation rates). Samples from all ORIs were slightly enriched in Si relative to Al, interpreted as reflecting decreased sediment flux during transgressive and early-highstand systems tracts. The data show that in some ORIs, OM accumulation proceeded while productivity was not particularly high and sediments were not experiencing strong anoxia. In other ORIs, OM accumulation was accompanied by widespread anoxia and possibly euxinic conditions in distal settings. Though somewhat different from each other, all of the ORIs developed during episodes of reduced terrigenous supply (transgressive episodes). The common feature linking these contrasted episodes of enhanced OM storage (ORIs) must be the conjunction of productivity coupled with a decrease in the dilution effect by the land-derived supply, in a depositional environment prone to water stratification and, therefore, favorable to OM preservation and accumulation.