ABSTRACT This study provides new stratigraphic data and identifications for fossil marine mammals from the Monterey Formation in the Capistrano syncline, Orange County, California, showing that there are two distinct marine mammal assemblages. Until now, marine mammals from the Monterey Formation of Orange County have been considered to represent a single assemblage that is 13.0–10.0 Ma in age. By combining data from diatoms with the geographic positions of sites, faunal analysis, and data from the literature, we can assign 59 sites to three main levels: the lower part (ca. 16–13 Ma), the middle part (ca. 13–10 Ma), and the upper part (ca. 10–8 Ma). We assigned 308 marine mammal specimens to 38 taxa, resulting in 97 occurrences (unique record of a taxon for a given site). Of the 38 taxa we identified within the study area, 15 taxa are restricted to the lower part of the Monterey Formation, 15 are restricted to the upper part of the Monterey Formation, eight were found in both, and none has yet been reported from the middle (possibly condensed) section. Six of the eight taxa that occur in both the lower and upper parts of the Monterey Formation are higher-level taxa, which accounts for their broad temporal range. The recognition of two distinct marine mammal assemblages in the Monterey Formation of Orange County is an important step toward a better-calibrated sequence of faunal evolution in the region while improving the utility of marine mammals for regional biostratigraphy.

ABSTRACT The Monterey Formation of Central and Southern California has produced billions of barrels of oil since the early 1900s. The Monterey Formation in the Santa Maria Basin is a tectonically fractured reservoir, meaning that the fractures formed through natural geologic processes; they are not human-generated artifacts. Open natural fractures provide the effective porosity for oil storage and the permeability pathways through which oil flows from rocks to wells. Monterey strata are notable for a diverse range of lithologies characterized by contrasts in texture and composition. Not all Monterey rock types contain natural fractures. Structural geologists applied the concepts of mechanical stratigraphy to the Monterey Formation to explain fracture variability. Hard rocks, including chert, porcelanite, and dolostone, contain extensive open-fracture systems, while softer lithologies like siliceous mudstone and organic-rich mudstone have few or no open fractures. However, the words “hard and soft” or “strong and weak” are inexact and subject to interpretation. This report constrains these qualitative descriptions by using engineering-geology data to associate rock properties with quantitative measurements of rock mechanical strength.

ABSTRACT The late early to middle Miocene period (18–12.7 Ma) was marked by profound environmental change, as Earth entered into the warmest climate phase of the Neogene (Miocene climate optimum) and then transitioned to a much colder mode with development of permanent ice sheets on Antarctica. Integration of high-resolution benthic foraminiferal isotope records in well-preserved sedimentary successions from the Pacific, Southern, and Indian Oceans provides a long-term perspective with which to assess relationships among climate change, ocean circulation, and carbon cycle dynamics during these successive climate reversals. Fundamentally different modes of ocean circulation and carbon cycling prevailed on an almost ice-free Earth during the Miocene climate optimum (ca. 16.9–14.7 Ma). Comparison of δ 13 C profiles revealed a marked decrease in ocean stratification and in the strength of the meridional overturning circulation during the Miocene climate optimum. We speculate that labile polar ice sheets, weaker Southern Hemisphere westerlies, higher sea level, and more acidic, oxygen-depleted oceans promoted shelf-basin partitioning of carbonate deposition and a weaker meridional overturning circulation, reducing the sequestration efficiency of the biological pump. X-ray fluorescence scanning data additionally revealed that 100 k.y. eccentricity-paced transient hyperthermal events coincided with intense episodes of deep-water acidification and deoxygenation. The in-phase coherence of δ 18 O and δ 13 C at the eccentricity band further suggests that orbitally paced processes such as remineralization of organic carbon from the deep-ocean dissolved organic carbon pool and/or weathering-induced carbon and nutrient fluxes from tropical monsoonal regions to the ocean contributed to the high amplitude variability of the marine carbon cycle. Stepwise global cooling and ice-sheet expansion during the middle Miocene climate transition (ca. 14.7–13.8 Ma) were associated with dampening of astronomically driven climate cycles and progressive steepening of the δ 13 C gradient between intermediate and deep waters, indicating intensification and vertical expansion of ocean meridional overturning circulation following the end of the Miocene climate optimum. Together, these results underline the crucial role of the marine carbon cycle and low-latitude processes in driving climate dynamics on an almost ice-free Earth.

ABSTRACT Sequence stratigraphy has proven to be an invaluable tool for the analysis of coarse-clastic depositional systems and the integration of observations across scales from reflection seismic to scanning electron microscope. Applications to mudstone-dominated depositional sequences have been more limited, despite the fact that mudstones make up more than 60% of the global sedimentary volume and generally provide the most complete record of sedimentation in a basin. During the late 1970s and through the 1980s, Bob Garrison and his students at the University of California–Santa Cruz conducted numerous studies that revealed the basic sedimentary and stratigraphic framework of the Monterey Formation in California, advancing our understanding of the sedimentary processes at work in these deep-margin basins. We expanded on that framework using direct observations from outcrops and cores that have been integrated with other subsurface data, as well as a wide variety of information derived from paleontologic, chronostratigraphic, geochemical, and compositional analyses to illustrate a sequence-stratigraphic approach to interpreting fine-grained rocks and their associated depositional systems in these settings. These were some of the earliest investigations of mudstone sequence stratigraphy focused on slope and basinal environments. In this study, observations from outcrops in the Pismo Basin, California, provided the basis for developing a detailed sequence-stratigraphic framework for the Monterey Formation, expanding on the broad-scale characterization of Garrison and his colleagues. These outcrops represent deposition during different phases of basin evolution and in different borderland-type basin settings (slope and basin depocenters). Comparison of coeval strata from different depositional settings and locations documented variation at both the sequence and parasequence scale. Variation of parasequence character, in particular, provided a valuable tool for enhanced understanding of deposition and diagenesis in these margin basins. Extrapolation to the subsurface using gamma-ray logs greatly enhanced basinwide application compared to limited, partial-stratigraphic-section outcrops, and it facilitated the lateral characterization of mudstone depositional sequences. These elements served as the building blocks for improved models of deposition in margin-basin settings.

ABSTRACT Application of updated diatom biochronology to the Monterey Formation and related biosiliceous rocks reveals the imprint of both global paleoclimatic/paleoceanographic and regional tectonic events. A rise in global sea level combined with regional tectonic deepening associated with the development of the transform California margin resulted in the abrupt onset of deposition of fine-grained Monterey sediments that were relatively free from clastic debris between 18 and 16 Ma. The base of the Monterey Formation does not mark a silica shift in diatom deposition from the North Atlantic to the North Pacific Ocean. Rather, a North Atlantic Ocean decline of diatoms after ca. 13 Ma and increasing divergence in nutrient levels between the North Atlantic and North Pacific Oceans between ca. 13 and 11 Ma coincided with a major enhancement of diatom deposition in the Monterey Formation. A stratigraphically condensed interval of phosphate-rich sediments between 13 and 10 Ma in coastal southern California appears to have resulted from sediment starvation in offshore basins during a period of higher sea level, as inland sections such as those in the San Joaquin Valley commonly contain thick sequences of diatomaceous sediment. Increasing latitudinal thermal gradients in the latest Miocene, which triggered a biogenic bloom in the equatorial Pacific Ocean at 8 Ma, also led to enhanced diatom deposition in the uppermost Monterey Formation and overlying biosiliceous rocks. Uplift of the California coastal ranges after ca. 5.2 Ma resulted in an increasing detrital contribution that obscured the presence of diatoms in onshore sediments. Major reduction in coastal upwelling in the early Pliocene ca. 4.6 Ma then caused a drastic reduction of diatoms in sediments offshore southern California.

ABSTRACT Rock properties play a critical role in dictating styles of deformation at all spatial scales, yet the effect of changes across and within diagenetic transition zones has been little studied, despite profound impact on resulting mechanical stratigraphy. Our analysis of the variation of fold strain at map scale and outcrop scale of the highly siliceous Monterey and Sisquoc Formations in the southern Santa Maria Basin, California, provides insight into the interplay among deformation, diagenesis, and rock composition. Diagenetic modification of these rocks has created intervals with high interstratal and interformational contrasts in competence. Map-scale analysis showed large variation in fold strain within the same area, with shortening values ranging from 5.5% to 21.1% between siliceous formations of different diagenetic grade and competence. Apparent shortening in the competent, diagenetically altered, thinly bedded Monterey Formation is twice as high as that in the overlying highly porous, diatomaceous, more massive Sisquoc Formation. The large difference in measurable apparent shortening suggests that the same amount of actual strain was chiefly accommodated by folding in the Monterey Formation versus horizontal compaction in the Sisquoc Formation, since there is no evidence of a detachment between the units. Strain analysis at outcrop scale provided insight into the ways in which both units express such different shortening ratios without having an unconformity or detachment fault between them.

ABSTRACT We present here a comprehensive record of Miocene terrestrial ecosystems from exposures of the Monterey Formation along the Naples coastal bluffs, west of Santa Barbara, California. Constrained by an updated chronology, pollen analyses of 28 samples deposited between 18 and 6 Ma reflect the demise of mesophytic taxa that grew in a warm, wet environment during the late early and early middle Miocene and the development of a summer-dry/winter-wet Mediterranean climate during the late Miocene. Broadleaf tree pollen from mesophytic woodlands and forests now found in the southeastern United States and China ( Liquidambar , Tilia , Ulmus , Carya ) characterized the Miocene climatic optimum (16.9–14.7 Ma), the middle Miocene climate transition (14.7–13.8 Ma), and the interval up to ca. 13.0 Ma. Subsequently, during the late middle to early late Miocene, between 13.3 and 9.0 Ma, oak woodlands and herbs (Asteraceae, Amaranthaceae, Poaceae) from beach scrub and chaparral increased as ocean temperatures cooled and the climate became drier. Between ca. 8.9 and 7.6 Ma, pine increased mostly at the expense of oak ( Quercus ) and herbs, suggesting a period of increasing precipitation. During the latest Miocene (7.5–6.0 Ma), an increase of herb-dominated ecosystems (chaparral, coastal scrub) at the expense of pine reflects the full development of a summer-dry/winter-wet climate in coastal southern California.

ABSTRACT The Monterey Formation and related formations in California have long been the subject of field and laboratory studies on silica diagenesis. Biogenic or amorphous silica (opal-A) alters to a more-ordered opal-CT and eventually to the crystalline end member, quartz, with increasing burial depth and temperature. Low-pressure nitrogen sorption serves as an indicator of silica alteration by detecting the nanometer-scale pore structures associated with opal-CT while excluding contributions from larger pores. To apply this method, calibrations with known compositions are not required, sample preparation and measurements are straightforward, hazardous waste is not generated (as with mercury porosimetry), and subtle changes in silica phase are readily detected. Nitrogen desorption isotherms, collected on mini cores (~0.8 cm diameter × 1 cm) after outgassing at 50 °C and processed using the Barrett-Joyner-Halenda method, provide nanometer-scale pore throat size distributions (nPSD), pore volumes (nPV), and surface areas (nSA). A scatter plot of nPV and nSA reveals two distinct trends. Samples with more nSA per unit volume contain opal-CT, either in transition from opal-A or completely converted. The other nSA trend consists of opal-A and quartz samples in the small nSA and nPV range, whereas samples with small nSA and large nPV also contain opal-CT and are in transition to quartz. These distinct trends are also apparent in the nPSD. Samples with more nSA exhibit a peak between 4 and 10 nm, whereas samples with less nSA have a broad peak between 10 and 100 nm if they contain opal-CT. Images collected via scanning electron microscopy reveal that opal-CT morphologies account for these differences.

ABSTRACT The Shublik Formation (Middle and Upper Triassic) is a mixed siliciclastic-carbonate-phosphatic unit in northern Alaska. It generated oil found in Prudhoe Bay and other accumulations and is a prospective self-sourced resource play on Alaska’s North Slope. Its distal, deeper-water equivalent—the Otuk Formation—consists largely of radiolarian chert, mudstone, and limestone and contains potential gas accumulations in the Brooks Range foothills to the south. New petrographic, fossil, geochemical, spectral gamma-ray, and zircon U-Pb data yield insights into facies changes in these units, which were deposited across a shallowly dipping shelf margin in a high-latitude setting. Samples come from four localities along a transect that extends ~410 km from present-day northeast (proximal) to southwest (distal) in northwest Alaska. Proximal Shublik facies (Brontosaurus 1 well) contain abundant siliciclastic detritus and local phosphate. Shublik-Otuk transitional facies occur in the probable onshore extension of the Hanna Trough (Surprise Creek); new zircon U-Pb data indicate an early Norian age for a bentonite bed in this section. Distal Otuk facies (Red Dog district, Cape Lisburne) are fine grained, biosiliceous, and organic rich. New detrital zircon U-Pb data from a distinctive sandstone member in the Otuk Formation at Cape Lisburne reinforce previous interpretations of a provenance to the present-day northwest and indicate a protracted history of Triassic magmatism for this source area. Triassic facies patterns in northwestern Alaska were shaped by sea-level change, climate, and regional tectonism. Organic-rich facies developed best at times (Ladinian–middle Norian) and/or in settings (distal shelf, Hanna Trough) with minimal dilution of organic matter by other detritus.

ABSTRACT The Monterey Formation, consisting of siliceous and calcareous biogenic sediments, was deposited during the transition from a relatively warm greenhouse climate in the early Miocene to the cooler temperatures of icehouse climatic conditions during the early middle to late Miocene. This cooling event was associated with global paleoclimatic and oceanic changes assumed to be related to the deposition of organic carbon–rich sediments into the marginal basins of California. This chapter introduces an age model for the Miocene strata at Naples Beach based on a composite stratigraphic section and standardized data set, providing the framework for the integration of biostratigraphic zones with a series of astronomically tuned siliceous and calcareous microfossil bioevents, an updated strontium isotope stratigraphy, new tephrochronology ages, and ages from specific magnetostratigraphic units. This multidisciplinary approach, utilizing the integration of microfossil disciplines with independent age controls, is critical to obtaining an age resolution of ~200 k.y. for the majority of the Monterey Formation section. This chronostratigraphic framework improves the age control of the boundaries between the California benthic foraminiferal stages and provides more age refinement for the possible hiatus and condensed interval within the Carbonaceous Marl member of the Monterey Formation. The recalibrated ages for the tops of the Miocene benthic foraminiferal stages are Saucesian (ca. 17.4 Ma), Relizian (15.9 Ma), Luisian (13.1 Ma), and Mohnian (7.7 Ma). Also, the time missing in the hiatus between the Luisian and Mohnian is <200 k.y., and the duration of the condensed interval is from 13.0 to 11 Ma. This refined age model provides a correlation of the organic carbon–rich intervals occurring in the Luisian and lower Mohnian stages within the Naples Beach strata to the deep-sea δ 13 C maxima events CM5 (ca. 14.7 Ma) and CM6 (ca. 13.6 Ma), suggesting episodic increases in organic carbon deposition along the continental margins coincided with the Miocene carbon isotope excursion found in deep-sea cores. The transition from the Miocene climatic optimum to the icehouse world consisted of four climatic and oceanic phases (from ca. 17.5 to ca. 7 Ma), which are represented in the onshore section by variations in the organic carbon and phosphate contents, the occurrence of calcareous and siliceous lithologic facies, and the distribution of microfossils, especially changes in the benthic foraminiferal assemblages.

ABSTRACT Tuff beds (volcanic ash beds and tuffs) have been known in the Miocene Monterey and Modelo Formations since they were initially described nearly 100 yr ago. Yet, these tephra layers have remained largely ignored. The ages and correlation of the Monterey and Modelo Formations are predominantly based on associated biostratigraphy. Here, we combined tephrochronology and biostratigraphy to provide more precise numerical age control for eight sedimentary sequences of the Monterey and Modelo Formations from Monterey County to Orange County in California. We correlated 38 tephra beds in the Monterey and Modelo Formations to 26 different dated tephra layers found mainly in nonmarine sequences in Nevada, Idaho, and New Mexico. We also present geochemical data for an additional 19 tephra layers in the Monterey and Modelo Formations, for which there are no known correlative tephra layers, and geochemical data for another 11 previously uncharacterized tephra layers in other areas of western North America. Correlated tephra layers range in age from 16 to 7 Ma; 31 tephra layers erupted from volcanic centers of the Snake River Plain, northern Nevada to eastern Idaho; 13 other tephra layers erupted from the Southern Nevada volcanic field; and the eruptive source is unknown for 12 other tephra layers. These tephra layers provide new time-stratigraphic markers for the Monterey and Modelo Formations and for other marine and nonmarine sequences in western North America. We identified tephra deposits of four supereruptions as much as 1200 km from the eruptive sources: Rainier Mesa (Southern Nevada volcanic field) and Cougar Point Tuff XI, Cougar Point Tuff XIII, and McMullen Creek (all Snake River Plain).

ABSTRACT The Eocene Kreyenhagen Formation is a widespread siliceous, organic-rich mudstone within the San Joaquin Basin, but it is less studied than the Monterey Formation. This study characterizes the Kreyenhagen Formation in the Kettleman area to define its vertical and lateral variability on the basis redox conditions (Mo, U, Cr), paleoproductivity (biogenic SiO 2 , P, Ba), and detrital input (Al 2 O 3 , TiO 2 ) to determine the dominant environmental conditions during deposition. The Kreyenhagen Formation was correlated across 72 wells over a 4600 km 2 (1776 mi 2 ) area, which revealed an eastward thinning from 335 m (1100 ft) to less than 183 m (600 ft). We identified three informal members on the basis of log response and bulk/trace geochemistry: a lower calcareous silty mudstone, a middle organic-rich clayey mudstone, and an upper siliceous silty mudstone. Spatially, the greatest enrichment of total organic carbon, redox proxies, and biogenic silica occurs along Kettleman North Dome. These properties decrease eastward as clay volume, titanium, and aluminum increase. We interpret the Kreyenhagen Formation to record one transgressive-regressive cycle with contemporaneous climatic cooling: a transgression with initial suboxia and calcareous plankton productivity, a highstand with anoxic-euxinic benthic conditions and clastic starvation, and regression with elevated biogenic silica input. The upward transition from a calcareous to siliceous composition may reflect known cooling and upwelling intensification on the middle Eocene California margin. Mo/U and Th/U patterns suggest variable redox conditions across space and time. Lateral compositional trends indicate that eastern areas were proximal to a Sierran clastic sediment source, while western areas were distal and more anoxic.

ABSTRACT Multisensor track measurements are a nondestructive method to produce continuously measured high-resolution physical property data sets that are a great asset to a wide range of research, including geotechnical studies and paleoceanography. Interpretation of these physical property data can be challenging because they are typically influenced by multiple variables. This paper specifically focuses on the interpretation of gamma-ray attenuation (GRA) data (a proxy for sediment bulk density) in biosiliceous sediments. The Bering Sea is a basin dominated by biosiliceous sediment, and the late Pleistocene to present core record of Sites U1340 and U1339, drilled during Integrated Ocean Drilling Program (IODP) Expedition 323, has subtle meter-scale changes in the concentration of fine-grained siliciclastic sediment that produce lithologic alternations between diatom ooze and diatom mud. We produced a detailed sedimentologic data set that combined smear slide petrography, scanning electron microscopy, and grain-size analysis for both Sites U1340 and U1339 and correlated it to shipboard GRA bulk density measurements. Results show that bulk density is negatively correlated with diatom abundance and positively correlated with the fragmentation of diatom valves. This study argues that diatom abundance and fragmentation influence sediment packing and drive down-core variability in GRA bulk density. Therefore, denser diatom mud is a result of tightly packed, highly fragmented diatom valves, and diatom ooze is a less dense sediment dominated by whole and less fragmented diatom valves. We suggest that GRA data can be used as a proxy for diatom abundance and an indicator of diatom fragmentation. We include a discussion of how these results may impact the interpretation of ancient bedded siliceous rocks.

The Monterey Formation is a Miocene marine unit that occurs extensively in the Coast Ranges and in the continental margins of California, and analogous biosiliceous deposits are found around the Pacific Rim and elsewhere in the world. Classic studies on the diatomaceous deposits that characterize the hemipelagic/pelagic facies of the Monterey Formation have been key to understanding the oceanographic and tectonic conditions that lead to the preservation of large volumes of organic-rich hemipelagic biosiliceous sediments, and the properties of these sedimentary deposits once they convert into rocks. This volume presents a collection of recent studies on the Monterey and other similar biosiliceous deposits that offer modern and updated interpretations of this classic unit and its analogues. The volume is dedicated to the memory of Professor Bob Garrison.