Gold enrichment mechanism in mid-ocean ridge hydrothermal systems; an example from the Longqi hydrothermal field on the ultraslow-spreading Southwest Indian Ridge

In mid-ocean ridge (MOR) hydrothermal systems, the gold grade of sea-floor massive sulfides (SMSs) is negatively correlated with the spreading rate of the ridge. Previous investigations have addressed the distribution of gold in sulfides from hydrothermal fields hosted by ultramafic rocks. In contrast, the gold enrichment mechanisms in sulfides from hydrothermal fields hosted by mafic rocks in ultraslow-spreading ridge environments are less well constrained. The basalt-hosted Longqi hydrothermal field, located on the classic ultraslow-spreading Southwest Indian Ridge, provides an opportunity to examine gold enrichment mechanisms in such an environment. Two ore-forming stages are identified in chimney fragments: anhydrite + barite + colloidal/porous pyrite (Py1) + marcasite + fine-grained sphalerite (stage 1); euhedral-subhedral pyrite (Py2) + coarse-grained sphalerite + chalcopyrite + isocubanite (stage 2). Py1 is usually overgrown by marcasite, which is in turn enclosed by Py2. Py2 coexists with coarse-grained sphalerite and chalcopyrite. Abundant native gold nanoparticles occur in Py1 or at the transition zone between Py1 and Py2. Laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) analysis suggests that Py1 contains higher Mo, V, Sn, and Pb and lower As, Co/Ni, and Se/Tl values compared to Py2. In situ LA-multicollector (MC)-ICP-MS analyses show that Py1 has a higher mean delta (super 34) S (+7.1 per mille) value than Py2 (+6.6 per mille). Sulfur primarily derives from MORB and seawater sulfate, of which the proportion of sulfur from seawater sulfate is between 20.5 and 47.6%. Textures, mineral assemblages, and trace element contents of sulfides indicate that the degree of mixing between hydrothermal fluids and seawater decreases as the chimney grows and is accompanied by a gradual increase in temperature. Based on data compiled from 41 hydrothermal fields hosted by basalt, the large range of sulfide delta (super 34) S from slow- and ultraslow-spreading MORs may be attributed to the wide range of sulfur sources (e.g., leaching from MOR basalt, thermochemical reduction of seawater sulfate, magma degassing, and bacterial activity), fluid-basalt interaction, and redox state (CH (sub 4) /CO (sub 2) ratios). Prolonged fluid-basalt interaction and the type of chimneys, such as beehive chimneys, may lead to higher gold grades in hydrothermal fields. Moreover, low H (sub 2) S content may be an important contributor to gold enrichment in basalt-hosted SMS deposits in ultraslow-spreading MOR environments.