Finding a VOICE in the Southern Hemisphere; a new record of global organic carbon?

Variations in the carbon isotopic composition of carbonate and organic carbon (delta (super 13) C (sub carb) and delta (super 13) C (sub org) ) are generally used to record perturbations in the global carbon cycle, which are in turn closely linked to changes in climate. However, because of climate gradients on Earth, assignment of the "global" signal in ancient records is not straightforward. Here, we report the delta (super 13) C values of organic material in the Upper Jurassic to Lower Cretaceous sedimentary record of the Vaca Muerta Formation, situated in the Neuquen Basin, Argentina, which show similar patterns to those observed in several northern latitude basins. This record of delta (super 13) C values in the organic material differs from those measured in the early Atlantic Ocean, a record previously considered to be representative of the global values of organic carbon. As a result of the global synchronicity observed in the delta (super 13) C values of organic material from both northern and southern latitudes, we suggest that these patterns may represent the global record of delta (super 13) C values in organic material rather than those measured in the proto-Atlantic Ocean. The delta (super 13) C values of the organic components show a slight initial decrease of approximately 2 ppm in the early Tithonian (149-145 Ma) and then another decrease of approximately 2 ppm before reaching a minimum of -30.29 ppm in the late Tithonian (145-143 Ma), followed by a gradual increasing trend throughout the Berriasian (143.1-137.7 Ma). The early Valanginian (137.7-135.5 Ma) was marked by a more substantial increase in delta (super 13) C values up to -23.46 ppm. These changes mirror those seen in Northern Hemisphere locations during the Late Jurassic and Early Cretaceous, where this perturbation has been termed the Volgian isotopic carbon excursion (VOICE). This difference in the Late Jurassic and Early Cretaceous delta (super 13) C values between the early Atlantic Ocean and the Neuquen Basin is interpreted to be the result of the climate gradient at the time, which was characterized by more humid conditions in high latitudes compared to dry conditions in the Atlantic Ocean basin.