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Mengeite, Ba(Mg, Mn (super 2+) )Mn (super 3+) (sub 4) (PO (sub 4) ) (sub 4) (OH) (sub 4) .4H2 (sub ) O, a new mineral from the Spring Creek Mine, South Australia, Australia

Peter Elliott
Mengeite, Ba(Mg, Mn (super 2+) )Mn (super 3+) (sub 4) (PO (sub 4) ) (sub 4) (OH) (sub 4) .4H2 (sub ) O, a new mineral from the Spring Creek Mine, South Australia, Australia
The Canadian Mineralogist (September 2022) 60 (5): 815-824

Abstract

Mengeite, Ba(Mg,Mn (super 2+) )Mn (super 3+) (sub 4) (PO (sub 4) ) (sub 4) (OH) (sub 4) .4H (sub 2) O, is a new mineral from the Spring Creek copper mine, near Wilmington, South Australia, Australia, where it occurs as dark orange-red masses to 0.8 mm across in a quartz matrix. The streak is pale salmon pink and the luster is vitreous. Mengeite is non-fluorescent and the Mohs hardness is approximately 3. The measured density is 3.40 g/cm (super 3) and the calculated density is 3.43 g/cm (super 3) . Mengeite is biaxial (-) with alpha = 1.757(4), beta = 1.776(4), gamma = 1.781(4) measured in white light. Electron microprobe analyses results give the empirical formula, based on 24 O apfu: Ba (sub 1.09) (Mg (sub 0.58) Mn (super 2+) (sub 0.26) Cu (sub 0.10) Al (sub 0.02) Na (sub 0.01) Ca (sub 0.01) (sub 0.09) ) (sub Sigma 1.07) Mn (super 3+) (sub 3.88) (PO (sub 4) ) (sub 4.07) (OH) (sub 3.52) .4.13H (super 2) O. The idealized formula is Ba(Mg,Mn (super 2+) )Mn (super 3+) (sub 4) (PO (sub 4) ) (sub 4) (OH) (sub 4) .4H (sub 2) O. Mengeite is triclinic, space group P1, with a = 5.4262(11), b = 5.4274(11), c = 16.387(3) Aa, alpha = 87.61(3), beta = 98.97(3), gamma = 110.56(3) degrees , V = 446.28(16) Aa (super 3) , and Z = 1. The crystal structure of mengeite was solved using synchrotron single-crystal X-ray diffraction data and refined to R (sub 1) = 0.0453 for 2115 observed reflections with F (sub 0) > 4sigma (F (sub 0) ). It is based on [(M (sub 2) (OH) (sub 2) (AsO (sub 4) ) (sub 2) ] sheets that are linked in the c-direction alternately by [M (sub 3) (H (sub 2) O) (sub 4) O (sub 2) ] octahedra and by BaO (sub 10) polyhedra.


ISSN: 0008-4476
EISSN: 1499-1276
Coden: CAMIA6
Serial Title: The Canadian Mineralogist
Serial Volume: 60
Serial Issue: 5
Title: Mengeite, Ba(Mg, Mn (super 2+) )Mn (super 3+) (sub 4) (PO (sub 4) ) (sub 4) (OH) (sub 4) .4H2 (sub ) O, a new mineral from the Spring Creek Mine, South Australia, Australia
Author(s): Elliott, Peter
Affiliation: University of Adelaide, Department of Earth Sciences, Adelaide, South Austr., Australia
Pages: 815-824
Published: 202209
Text Language: English
Publisher: Mineralogical Association of Canada, Ottawa, ON, Canada
References: 28
Accession Number: 2023-001669
Categories: Mineralogy of non-silicates
Document Type: Serial
Bibliographic Level: Analytic
Illustration Description: illus. incl. 6 tables
S32°49'60" - S32°40'00", E138°00'00" - E138°10'00"
Country of Publication: Canada
Secondary Affiliation: GeoRef, Copyright 2023, American Geosciences Institute. Abstract, copyright, Mineralogical Association of Canada. Reference includes data from GeoScienceWorld, Alexandria, VA, United States
Update Code: 2023
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