Arsenmarcobaldiite, Pb (sub 12) (As (sub 3.2) Sb (sub 2.8) ) (sub Sigma =6) S (sub 21) , a new N=3.5 jordanite homologue from the Sant'Anna tectonic window, Apuan Alps (Tuscany, Italy)

The new mineral species arsenmarcobaldiite, Pb (sub 12) (As (sub 3.2) Sb (sub 2.8) ) (sub Sigma =6) S (sub 21) , occurs as black anhedral grains, up to 0.5 mm in size, with metallic lustre, associated with pyrite and minor sphalerite, within layers of granoblastic quartz and accessory baryte embedded in pyrite-rich schist from a small baryte+pyrite prospect at Verzalla, Stazzema, Apuan Alps, Tuscany, Italy. Under the ore microscope, arsenmarcobaldiite is white. It is weakly pleochroic in shades of grey. Anisotropy is distinct, both in air and oil, with rotation tints from brownish to bluish-grey. Reflectance percentages for the four COM wavelengths are [R (sub min) , R (sub max) (%) (lambda )]: 32.8, 38.3 (470 nm); 32.2, 37.5 (546 nm); 31.7, 36.9 (589 nm); 31.4, 36.6 (650 nm). Polysynthetic twinning is common and characteristic. Electron microprobe analysis gave (in wt% - average of 19 spot analyses): Ag 0.20(1), Pb 66.34(38), As 6.36(10), Sb 8.93(9), Bi 0.30(5), S 18.00(14), total 100.13(48). On the basis of Sigma Me=18 atoms per formula unit, the chemical formula is Ag (sub 0.07(1)) Pb (sub 11.96(5)) (As (sub 3.17(4)) Sb (sub 2.74(3)) Bi (sub 0.05(1)) ) (sub Sigma 5.96) S (sub 20.97(17)) , ideally Pb (sub 12) (As (sub 3.2) Sb (sub 2.8) ) (sub Sigma =6) S (sub 21) . The main diffraction lines, corresponding to multiple hkl indices, are [d in Aa (relative visual intensity)]: 3.595 (m), 3.429 (m), 3.214 (ms), 3.027 (ms), 2.233 (s), 2.125 (ms), 1.839 (ms). The X-ray diffraction study gave a triclinic unit cell, space group P1, with a=8.9736(9), b=29.334(3), c=8.4925(10) Aa, alpha =98.369(6), beta =118.705(6), gamma =90.874(6) degrees , V=1930.5(4) Aa3, Z=2. The crystal structure was solved and refined to R (sub 1) =0.063 on the basis of 6325 reflections with Fo>4sigma (F (sub o) ) and 364 refined parameters. Arsenmarcobaldiite is a new N=3.5 homologue belonging to the jordanite homologous series and it is the As-dominant isotype of marcobaldiite.