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The validity of plagioclase-melt geothermometry for degassing-driven magma crystallization

Madeleine C. S. Humphreys, Marie Edmonds and Marthe S. Kloecking
The validity of plagioclase-melt geothermometry for degassing-driven magma crystallization
American Mineralogist (April 2016) 101 (4): 769-779


Any quantitative interpretation of the formation conditions of igneous rocks requires methods for determining crystallization temperature. Accurate application of such thermobarometers relies on the attainment of equilibrium in the system to be studied. This may be particularly difficult in silicic magmas, where diffusivities are low and crystallization kinetics sluggish. Moreover, progressive degassing of volatile-rich magmas during ascent can result in continuous changes in effective undercooling, causing particular problems in achieving equilibrium between melt and crystals that grow in response to decompression. We consider these problems in the context of plagioclase-melt equilibria for magmas undergoing decompression and degassing-driven crystallization, using two published thermometers. The two thermometers show similar trends with key parameters but absolute temperatures can vary significantly. Analysis of decompression experiments conducted at constant temperature shows systematic variations in calculated temperature and equilibrium constant with varying decompression rate and quench pressure. This indicates that an unrecognized lack of equilibration could result in significant temperature overestimates and potentially spurious results. This highlights the need to assess for equilibrium, and we discuss problems associated with some commonly used indicators of equilibration. Finally, retrospective analysis of published plagioclase-hosted melt inclusion suites from five subduction zone volcanoes shows systematic increases in calculated temperature and decreases in equilibrium constant with decreasing H (sub 2) O concentration. While this could represent the signature of latent heat of crystallization, we suggest that such patterns should be treated with caution unless there is clear evidence of sustained equilibrium between plagioclase and melt during decompression.

ISSN: 0003-004X
EISSN: 1945-3027
Serial Title: American Mineralogist
Serial Volume: 101
Serial Issue: 4
Title: The validity of plagioclase-melt geothermometry for degassing-driven magma crystallization
Affiliation: Durham University, Department of Earth Sciences, Durham, United Kingdom
Pages: 769-779
Published: 201604
Text Language: English
Publisher: Mineralogical Society of America, Washington, DC, United States
References: 52
Accession Number: 2016-040340
Categories: Igneous and metamorphic petrology
Document Type: Serial
Bibliographic Level: Analytic
Illustration Description: illus. incl. 1 table
Secondary Affiliation: University of Cambridge, GBR, United Kingdom
Country of Publication: United States
Secondary Affiliation: GeoRef, Copyright 2017, American Geosciences Institute. Abstract, copyright, Mineralogical Society of America. Reference includes data from GeoScienceWorld, Alexandria, VA, United States
Update Code: 201620
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