Torrecillasite, Na(As,Sb) (sub 4) , a new mineral from the Torrecillas Mine, Iquique Province, Chile; description and crystal structure
Torrecillasite, Na(As,Sb) (sub 4) , a new mineral from the Torrecillas Mine, Iquique Province, Chile; description and crystal structure
Mineralogical Magazine (June 2014) 78 (3): 747-755
- abandoned mines
- alteration
- anhydrite
- antimonides
- arsenates
- arsenic ores
- arsenides
- arsenites
- Atacama Chile
- Atacama Desert
- chemical composition
- Chile
- chlorides
- cinnabar
- coexisting minerals
- crystal chemistry
- crystal structure
- electron probe data
- formula
- framework silicates
- gypsum
- halides
- halite
- intergrowths
- lattice parameters
- marcasite
- metal ores
- mines
- new minerals
- physical properties
- pyrite
- quartz
- scorodite
- secondary minerals
- silica minerals
- silicates
- South America
- space groups
- sulfates
- sulfides
- unit cell
- X-ray diffraction data
- lavendulan
- wendwilsonite
- Iquique Chile
- magnesiokoritnigite
- Torrecillas Mine
- torrecillasite
The new mineral torrecillasite (IMA2013-112), Na(as,Sb) (super 3+) (sub 4) , was found at the Torrecillas mine, Iquique Province, Chile, where it occurs as a secondary alteration phase in association with anhydrite, cinnabar, gypsum, halite, lavendulan, magnesiokoritnigite, marcasite, quartz, pyrite, scorodite, wendwilsonite and other potentially new As-bearing minerals. Torrecillasite occurs as thin colourless prisms up to 0.4 mm long in jack-straw aggregates, as very thin fibres in puff balls and as massive intergrowths of needles. Prisms are elongated on [100] with diamond-shaped cross-section and irregular terminations. Crystals are transparent, with adamantine lustre and white streak. The Mohs hardness is 2 1/2, tenacity is brittle and fracture is irregular. Cleavage on (001) is likely. The calculated density is 4.056 g cm (super -3) . Optically, torrecillasite is biaxial (-) with alpha = 1.800(5), beta = 1.96(1), gamma = 2.03(calc.) (measured in white light). The measured 2V is 62.1(5) degrees , no dispersion or pleochroism were observed, the optical orientation is X = c, Y = b, Z = a. The mineral is very slowly soluble in H (sub 2) O, slowly soluble in dilute HCl and rapidly soluble in concentrated HCl. The empirical formula, determined from electron-microprobe analyses, is (Na (sub 1.03) Mg (sub 0.02) ) (sub Sigma 1.05) (As (sub 3.39) Sb (sub 0.62) ) (sub Sigma 4.01) O (sub 6.07) Cl (sub 0.93) . Torrecillasite is orthorhombic, Pmcn, a = 5.2580(9), b = 8.0620(13), c = 18.654(3) Aa, V = 790.7(2) Aa (super 3) and Z = 4. The eight strongest X-ray powder diffraction lines are [d (sub obs) Aa(I)(hkl)]: 4.298(33)(111), 4.031(78)(014,020), 3.035(100)(024,122), 2.853(39)(115,123), 2.642(84)(124,200), 2.426(34)(125), 1.8963(32)(225) and 1.8026(29)(0.1.10,233). The structure, refined to R (sub 1) = 4.06% for 814 F (sub o) >4sigma F reflections, contains a neutral, wavy As (sub 2) O (sub 3) layer parallel to (001) consisting of As (super 3+) O (sub 3) pyramids that share O atoms to form six-membered rings. Successive layers are flipped relative to one another and successive interlayer regions contain alternately either Na or Cl atoms. Torrecillasite is isostructural with synthetic orthorhombic NaAs (sub 4) O (sub 6) Br.