Impacts of volumetric strain on CO (sub 2) sequestration in coals and enhanced CH (sub 4) recovery
Impacts of volumetric strain on CO (sub 2) sequestration in coals and enhanced CH (sub 4) recovery
AAPG Bulletin (January 2008) 92 (1): 15-29
- adsorption
- aliphatic hydrocarbons
- alkanes
- Canada
- carbon dioxide
- carbon sequestration
- chemical properties
- cleats
- climate change
- coal
- coal seams
- coalbed methane
- elastic constants
- equations
- expansive materials
- fabric
- gas injection
- human activity
- hydrocarbons
- Langmuir equation
- matrix
- measurement
- mechanical properties
- methane
- natural gas
- nitrogen
- numerical models
- organic compounds
- permeability
- petroleum
- physical properties
- recovery
- sedimentary rocks
- sorption
- technology
- variations
- vitrinite reflectance
- Western Canada
- Young's modulus
Sequestration of CO (sub 2) into deep, unminable coal seams is an attractive option to reduce atmospheric emissions. However, coal seams commonly have low initial permeability, and CO (sub 2) adsorption causes the coal matrix to swell, which further reduces the permeability and may result in inefficient injection. We investigate numerically the impacts of coal swelling on coal permeability and, thus, CO (sub 2) injection efficiency with constraints determined by experimental adsorption-associated volumetric strain measurements on three western Canadian coals. Our results show that injecting pure CO (sub 2) markedly reduces permeability through time to the extent that it is not a feasible sequestration technology for almost all coals. However, injection of a gas mixture of N (sub 2) and CO (sub 2) (flue gas) markedly improved CO (sub 2) injection efficiency while mildly reducing CO (sub 2) sequestration capacity. The study also suggests that different geological settings and mechanical properties of specific coal seams strongly control coal seam permeability during gas injection and, thus, viability of CO (sub 2) sequestration.