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Organic anions in layered double hydroxides; an experimental investigation of citrate hydrotalcite

Qiang Li and R. James Kirkpatrick
Organic anions in layered double hydroxides; an experimental investigation of citrate hydrotalcite (in Microbeam cathodoluminescence, Ian M. Coulson (prefacer), Paul R. Edwards (prefacer) and Martin R. Lee (prefacer))
American Mineralogist (February 2007) 92 (2-3): 397-402


The nature of the chemical interactions between organic species and mineral surfaces and inter-layers has significant implications for many geochemical processes and for medical and materials applications, but the molecular-scale characteristics of such interactions are poorly understood. Here we describe an experimental investigation of citrate-hydrotalcite (HT) that is designed to investigate the structural environments and dynamical behavior of carboxylic species interacting with the protonated surfaces of positively charged materials such as layered double hydroxides (LDHs). X-ray diffraction, compositional analysis, and thermal analysis confirm successful intercalation of trivalent citrate anions into the interlayers of the Mg/Al hydrotalcite using an ion-exchange method. The basal spacing changes from 8.9 Aa at relative humidity (R.H.) = 0% to 11.3 Aa at R.H. = 75%, to 18.9 Aa at 100% R.H., consistent with reorientation of the citrate from parallel to the hydroxide layers at low water contents to perpendicular to them at higher water contents. At the largest water contents, the citrate may lose contact with one of the hydroxide layers, in contrast to the behavior of LDHs containing small, inorganic species. The similarity of the (super 13) C nuclear magnetic resonance (NMR) chemical shifts for citrate-HT and sodium citrate solution demonstrates the absence of grafting (covalent bond formation) between the citrate molecules and the metal hydroxide layers, and the dominance of Coulombic and H-bond interactions in stabilizing the structure. Decreasing (super 13) C NMR peak widths, decreasing signal/noise ratios in the (super 1) H- (super 13) C CPMAS NMR spectra, and increasing basal spacing with increasing R.H. are consistent with increasing dynamical disorder of the interlayer citrate sites in a progressively more water-rich interlayer.

ISSN: 0003-004X
EISSN: 1945-3027
Serial Title: American Mineralogist
Serial Volume: 92
Serial Issue: 2-3
Title: Organic anions in layered double hydroxides; an experimental investigation of citrate hydrotalcite
Title: Microbeam cathodoluminescence
Author(s): Li, QiangKirkpatrick, R. James
Author(s): Coulson, Ian M.prefacer
Author(s): Edwards, Paul R.prefacer
Author(s): Lee, Martin R.prefacer
Affiliation: University of Illinois at Urbana-Champaign, Department of Geology, Urbana, IL, United States
Affiliation: University of Regina, Department of Geology, Regina, SK, Canada
Pages: 397-402
Published: 200702
Text Language: English
Publisher: Mineralogical Society of America, Washington, DC, United States
References: 45
Accession Number: 2007-039041
Categories: Mineralogy of non-silicates
Document Type: Serial
Bibliographic Level: Analytic
Illustration Description: illus.
Secondary Affiliation: University of Strathclyde, GBR, United KingdomUniversity of Glasgow, GBR, United Kingdom
Country of Publication: United States
Secondary Affiliation: GeoRef, Copyright 2017, American Geosciences Institute. Abstract, copyright, Mineralogical Society of America. Reference includes data from GeoScienceWorld, Alexandria, VA, United States
Update Code: 200721
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